Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Euless Plant
10950 S. Pipeline Rd
Euless TX 76040
08/28/2007
Revised:
PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
Preparer:
1-800-424-9300
CHEMTREC
Sealant
Chemical Family/Use:
Mixture
Formula:
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Harmful if swallowed, inhaled, or absorbed through the skin. Irritating to eyes, respiratory
system and skin. May cause allergic skin reaction. May cause adverse liver, kidney, and CNS effects. May
cause adverse cardiac effects. Adverse reproductive effects reported in animals.
Form: Solid Color: White Odor: Ammonia
POTENTIAL HEALTH EFFECTS
INGESTION
Harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. May
cause central nervous system effects. May cause tingling and numbness in the hands and feet. May
cause pneumonitis as a result of aspiration. Liver and kidney injuries may occur. May cause
cardiopulmonary effects and possible hemorrhaging. May cause reproductive effects based on results
of animal studies.
SKIN
Harmful if absorbed through the skin. May be absorbed through the skin and contribute to the
symptoms listed under "Ingestion". Causes skin irritation. May cause skin defatting with prolonged
exposure. May cause allergic skin reaction.
INHALATION
Harmful if inhaled. Causes irritation of the mouth, nose, and throat. Symptoms of overexposure may
be headache, dizziness, tiredness, nausea and vomiting. May cause central nervous system effects.
May affect the heart and cardiovascular system. May also cause other effects as listed under
"Ingestion".
EYES
Irritation with redness, swelling, pain, and tearing.
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
MEDICAL CONDITIONS AGGRAVATED
Respiratory disorder Central nervous system disorders. Skin disorders. Cardiovascular disorders.
Pre-existing liver or kidney disorders.
SUBCHRONIC (TARGET ORGAN )
Skin; Liver; Kidney; Central nervous system; Heart effects.; Bone marrow and hematopoietic
(blood forming) system
CHRONIC EFFECTS / CARCINOGENICITY
This product contains stoddard solvent or mineral spirits. Chronic and repeated overexposure
may result in adverse liver and kidney effects, bone marrow hyperplasia, and intracerebral
hemorrhage.
ROUTES OF EXPOSURE
Dermal; Inhalation; Ingestion
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS
STODDARD SOLVENT 8052-41-3 1-5%
Diisoheptyl phthalate 71888-89-6 5 - 10 %
B. NON-HAZARDOUS
Limestone 471-34-1 30 - 60 %
Water 7732-18-5 10 - 30 %
2-propenoic acid, polymer 52640-81-0 10 - 30 %
2-Propenoic acid, Butyl ester,- 25067-01-0 1-5%
Polymer with Ethenyl Acetate
4. FIRST AID MEASURES
INGESTION
Do NOT induce vomiting. To avoid aspiration should vomiting occur, have the person lean
forward. Immediate medical attention is required. If victim is conscious, give 2-4 glasses of water.
Never induce vomiting unless specifically directed by qualified medical personnel. Never give
anything by mouth to an unconscious person.
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
SKIN
Flush skin with large amounts of water for at least 15 minutes until no evidence of chemical
remains. Wash with soap and water. Get medical attention if irritation or symptoms from Section
3 develop.
INHALATION
Move to fresh air. If not breathing, begin artificial respiration using a barrier device. Because of
chemical properties, do not use mouth-to-mouth contact.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
Not applicable
FLASH POINT:
Not applicable
IGNITION TEMPERATURE:
Not applicable
FLAMMABLE LIMITS IN AIR - LOWER (%):
Not applicable
FLAMMABLE LIMITS IN AIR - UPPER (%):
No
SENSITIVITY TO MECHANICAL IMPACT:
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.none
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressureself-contained breathing
apparatus with full face mask and fullprotective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Use only in well-ventilated areas. Avoid accidental ingestion of this
material. Wash hands and face before eating, drinking, smoking, using toilet facilities, or applying
cosmetics. Keep container closed when not in use. Keep away from children.
STORAGE
Store away from heat, sources of ignition, and incompatibles.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Showers; Eyewash stations; Ventilation and other forms of engineering controls are preferred for
controlling exposures. Respiratory protection may be needed for non-routine or emergency situations.
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Neoprene
EYE AND FACE PROTECTION
Monogoggles.; Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
STODDARD 8052-41-3 ACGIH, TWA 100 ppm
SOLVENT
STODDARD 8052-41-3 OSHA Z1, PEL 500 ppm; 2,900 mg/m3
SOLVENT
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
9. PHYSICAL AND CHEMICAL PROPERTIES
Not applicable
BOILING POINT - C & F:
Not applicable
VAPOR PRESSURE (20 C) (MM HG):
Not applicable
VAPOR DENSITY (AIR=1):
Not applicable
FREEZING POINT:
Not applicable
MELTING POINT:
Solid
PHYSICAL STATE:
Ammonia
ODOR:
White
COLOR:
Unknown
SPECIFIC GRAVITY (WATER=1):
Unknown
DENSITY:
Not applicable
ACID / ALKALINITY (MEQ/G):
Unknown
pH:
31.10 %(m)
VOLATILE ORGANIC CONTENT (VOL):
Unknown
SOLUBILITY IN WATER (20 C):
Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE
SOLVENT):
64.60
VOC EXCL. H2O & EXEMPTS (G/L):
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Oxides of nitrogen.; Toxic monomer fumes.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
Unknown
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
ACUTE INHALATION
Remarks: Unknown
OTHER
None.
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
This product contains butyl benzyl phthalate. Adverse reproductive effects have been reported in
animals exposed to butyl benzyl phthalate through chronic feeding studies. Additionally, chronically
fed rats exhibited leukemia and lymphomas, including Hodgkin's disease.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
Ecotoxicological data for this product is not available.
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
This product is not regarded as dangerous goods according to the
Further Information:
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Philippines Inventory of n (Negative listing)
Chemicals and Chemical
Substances (PICCS)
Canada NDSL Inventory n (Negative listing)
EU list of existing chemical n (Negative listing)
substances
Australia Inventory of Chemical n (Negative listing)
Substances (AICS)
Canada DSL Inventory y (Positive listing)
Korea Existing Chemicals n (Negative listing)
Inventory (KECI)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
71888-89-6, Diisoheptyl phthalate
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS
Other
3214.10 Mastic Based on Rubber
SCHDLE B/HTSUS:
EAR99
ECCN:
CALIFORNIA PROPOSITION 65
THIS PRODUCT CONTAINS CALIFORNIA PROPOSITION 65 CHEMICALS WHICH ARE LISTED
BELOW:
50-00-0, Formaldehyde. 140-88-5, Ethyl Acrylate. 75-07-0, Acetaldehyde. 79-06-1, 2-Propenamide.
107-13-1, . 123-91-1, 1,4-Dioxane. 75-21-8, Ethylene Oxide. 7440-38-2, Arsenic. 7439-92-1, Lead.
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Material Safety Data Sheet
Version: 1.6
08/28/2007
GE22566 12C-Crtrg(1.1LBS-0.499KG)
ACRYLIC CAULK
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
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