Heavy Duty Diesel 15W-40
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SUPROTEK ADVANTAGE DIESEL ENGINE OIL
SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.
PRODUCT CODE: Prefix 22
PRODUCT USE: For lubricating diesel engines. If these products are used in combination with other products, refer to
the Material Safety Data Sheet for those products.
This number is for emergency use only. If you 24-HOUR EMERGENCY PHONE NUMBER
desire non-Emergency product information, MEDICAL AND TRANSPORTATION (SPILL):
please call a phone number listed below.
CHEMTREC: (800) 424-9300
SUPPLIER: Dixie Gas & Oil Corporation
229 Lee Highway
Verona, VA 24482
www.dixiegas.com
800-403-4943
TECHNICAL
INFORMATION: 540-248-6273
MSDS FORM NUMBER: 82506 ISSUE: February 5, 2004
ORIGINAL ISSUE: June 15, 1989 SUPERSEDES: October 17, 2003
PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force
Page 1 of 8
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL** ACGIH TLV庐
WT%* NAME SYNONYM CAS NO. TWA STEL TWA STEL LDa LCb
mg/m3 mg/m3 mg/m3
Hydrotreated 64742-58-1 5c N.Av. 5c 10c N.Av. N.Av.
Lubricating oils,
paraffinic base oil (>2000)d
petroleum,
35-95
hydrotreated spent
Bright stock 64742-62-7 5c N.Av. 5c 10c >10000 N.Av.
Residual oils
(>2000)d
0-55 (petroleum), solvent
dewaxed
Bright stock 64742-57-0 5c N.Av. 5c 10c N.Av. N.Av.
Residual oils
0-55 (petroleum),
hydrtreated
Bright stock 72623-83-7 5c N.Av. 5c 10c >5000 N.Av.
Lubricating oils
(>3000)d
(petroleum), C>25,
0-55
hydrotreated bright
stock
Bright stock 64742-01-4 5c N.Av. 5c 10c N.Av. N.Av.
Residual oils
0-55* (Patroleum) Solvent
Refined
N. Av. 64742-54-7 5c N.Av. 5c 10c N.Av. N.Av.
Petroleum distillates,
0-36 hydrotreated heavy
paraffinic
N.Av. 72623-86-0 5c N.Av. N.Av. N.Av. N.Av. N.Av.
Lubricating oils,
petroleum, C15-30,
0-11
hydrotreated neutral
oil-based
Polyolefin N.Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
0-10
N. Av. 64742-65-0 5c N.Av. 5c 10c N.Av. N.Av.
Distillates (petroleum),
0-6 solvent dewaxed
heavy paraffinic
N. Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
Polyolefin amide
0-6
alkeneamine
Calcium sulfonate N. Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
0-2.25
Alkylamin N. Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
0-2
Alkylated phenol N. Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
0-2
Calcium phenate N. Av. *** N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
0-1.5
Benzenamine, N- Diphenylamine, 68411-46-1 N. Av. N.Av. N.Av. N.Av. >5000 N.Av.
phneyl-reaction diisobutylene
0-1.5 products with2,4,4- reaction product
trimethylpentene
Phosphorodithioic Dialkyl (C1-C14) 68649-42-3 N. Av. N.Av. N.Av. N.Av. N.Av. N.Av.
acid, O,O-di-C1-14- dithiophosphoric
0-1.5
alkyl esters, zinc salts acid, zinc salt
**OSHA Final PEL value (enforceable). Some States have adopted more stringent values.
N. Av. = Not Available ***Supplier advises that this is a trade secret c Based on Oil mist, mineral
a Oral-Rat LD50 b Inhalationl-Rat LC50 d Skin-Rabbit LD50 (mg/kg)
*Even though the concentration range does not fall under the ranges prescribed by EHMIS, this is the actual range which varies with each
batch of the product.
Page 2 of 8
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
APPEARANCE
Amber, liquid, petroleum odor.
CAUTION!
HEALTH HAZARDS
May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin. May be harmful or fatal if swallowed.
POTENTIAL HEALTH EFFECTS
INHALATION
(BREATHING): These products are not likely to present an inhalation hazard at normal temperatures and
pressures. However, when aerosolizing, misting, or heating these products, high
concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and lungs).
EYES: May cause irritation.
SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful amounts.
SECTION 4: FIRST AID MEASURES
INHALATION
(BREATHING): Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
may be administered by qualified personnel. Someone should stay with victim. Get medical
attention if breathing difficulty persists.
EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air. Upon
contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes.
Get medical attention.
SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical attention
if irritation or pain develops or persists. If product is injected under pressure into or under the skin, or
into any part of the body, regardless of the appearance of the wound or its size, a physician should
immediately evaluate the individual as a medical emergency.
INGESTION
(SWALLOWING): Do NOT induce vomiting. Immediately get medical attention. Call 800-424-9300 for additional
information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product into
the lungs. Never give anything by mouth to an unconscious person.
NOTE TO
PHYSICIANS: Treat symptomatically and supportively. Treatment may vary with condition of victim and specifics of
incident. Call 800-424-9300 for additional information.
Page 3 of 8
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: 392潞F (200潞C) (minimum) Cleveland Open Cup
FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available
AUTOIGNITION
TEMPERATURE: Not available
HAZARDOUS COMBUSTION
PRODUCTS: Decomposition and combustion materials may be toxic. Burning may produce aldehydes, hydrogen
sulfide, alkyl mercaptans, sulfides, boron oxides, calcium oxides, magnesium oxides, molybdenum
oxides, phosphorus oxides, nitrogen oxides, zinc oxides, sulfur oxides, carbon monoxide, and
other unidentified organic compounds.
CONDITIONS OF
FLAMMABILITY: Sparks or flame. Product may burn, but does not ignite readily.
EXTINGUISHING
MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may cause
frothing.
NFPA 704
HAZARD
IDENTIFICATION: This information is intended solely for the use by individuals trained in this system.
FIRE FIGHTING
INSTRUCTIONS: Keep storage containers cool with water spray. A positive-pressure, self-contained breathing
apparatus (SCBA) and full-body protective equipment are required for fire emergencies.
FIRE AND EXPLOSION
HAZARDS: Heated containers may rupture. "Empty" containers may retain residue and can be dangerous.
Products are not sensitive to mechanical impact or static discharge.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective
equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION.
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist.
Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean tool into a sealable
container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.
SECTION 7: HANDLING AND STORAGE
HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for such
locations should be used. Use clean tools. These products have a low vapor pressure and are not
expected to present an inhalation hazard under normal temperatures and pressures. However, when
aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well ventilated
area. Avoid contact with eyes, skin, clothing, and shoes.
SHIPPING AND
STORING: Keep container tightly closed when not in use and during transport. Store containers in a cool, dry
place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from
heat, flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain
productresidue and can be dangerous.
Page 4 of 8
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING
CONTROLS: Provide general ventilation needed to maintain concentration of vapor or mist below applicable
exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels below applicable exposure
limits.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY
PROTECTION: No respiratory protection is normally required. Use NIOSH-certified P- or R- series particulate filter
and organic vapor cartridges when concentration of vapor or mist exceeds applicable exposure limits.
Protection provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and
use of respiratory protective equipment should be in accordance in the USA with OSHA General
Industry Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4.
EYE
PROTECTION: Wearing chemical goggles is recommended. Contact lens use is not recommended without eye
protection.
SKIN
PROTECTION: No skin protection is normally required. Where skin contact is likely, wear neoprene, nitrile (4 mil
minimum), PVC (polyvinyl chloride), or equivalent protective gloves; use of natural rubber or
equivalent gloves is not recommended. When products are heated and skin contact is likely, wear heat-
resistant gloves, boots, and other protective clothing. To avoid prolonged or repeated contact where
spills and splashes are likely, wear appropriate chemical-resistant faceshield, boots, apron, coveralls,
long sleeve shirts, or other protective clothing.
PERSONAL
HYGIENE: Use good personal hygiene. Wash thoroughly with soap and water after handling product and
before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective
equipment before reuse. Discard leather articles, such as shoes, saturated with these products.
OTHER
PROTECTIVE
EQUIPMENT: Where spills and splashes are likely, facilities storing or using these products should be equipped
with an emergency eyewash and shower, both equipped with clean water, in the immediate work
area.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE,
APPEARANCE, AND ODOR: Liquid, amber, petroleum odor.
ODOR THRESHOLD: Not available
MOLECULAR WEIGHT: Not applicable
SPECIFIC GRAVITY: 0.88 (water = 1) (approximately)
DENSITY: 7.3 LB/US gal (880 g/l) (approximately)
VAPOR DENSITY: Not available
VAPOR PRESSURE: less than 0.1 mmHg at 68潞F (20潞C)
BOILING POINT: 475潞F (246潞C) (minimum)
FREEZING/MELTING
POINT: Not available [pour point 16潞F (-9潞C) (maximum)]
pH: Not applicable
Page 5 of 8
EVAPORATION RATE: Not available
SOLUBILITY IN WATER: Insoluble
FLASH POINT: 392潞F (200潞C) Cleveland Open Cup
FLAMMABLE
LIMITS IN AIR: LOWER: Not available UPPER: Not available
AUTOIGNITION
TEMPERATURE: Not available
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal temperatures and pressures. Avoid heat, sparks, or flame.
INCOMPATIBILITY: Avoid oxidizing agents, acids and reactive halogens.
REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive
with water.
HAZARDOUS
DECOMPOSITION
PRODUCTS: None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS
COMBUSTION PRODUCTS.
SECTION 11: TOXICOLOGICAL INFORMATION
SENSITIZATION: Based on best current information, there is no known human sensitization associated with these
products.
MUTAGENICITY: Experimental evidence suggests that these products do not cause mutagenesis.
CARCINOGENICITY: Based on best current information, there is no known carcinogenicity as categorized by ACGIH
A1 or A2 substances; as categorized by IARC Group 1, Group 2A, or Group 2B agents; or as
listed by NTP as either known carcinogens or substances for which there is limited evidence of
carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals.
Also see SECTION 15: CALIFORNIA.
REPRODUCTIVE
TOXICITY: Based on best current information, there is no known reproductive toxicity associated with these
products. Also see SECTION 15: CALIFORNIA.
TERATOGENICITY: Based on best current information, there is no known teratogenicity associated with these products.
TOXICOLOGICALLY
SYNERGISTIC
PRODUCT(S): Based on best current information, there are no known toxicologically synergistic products
associated with these products.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY: Not available
OCTANOL/WATER
PARTITION COEFFICIENT: Not available
VOLATILE ORGANIC COMPOUNDS: 100 WT%; 7.3 LB/US gal; 880 g/l (approximately) As per 40 CFR Part 51.100(s).
Page 6 of 8
SECTION 13: DISPOSAL CONSIDERATIONS
DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply
to empty ontainers. The responsibility for proper waste disposal lies with the owner of the waste.
Contact Dixie Gas And Oil Corporation regarding proper recycling or disposal.
USEPA
WASTE
CODE(S): These products, if discarded, are not expected to be a characteristic or listed hazardous waste. If
recycled in the USA, they must be managed in accordance with 40 CFR Part 279. Processing, use, or
contamination by the user may change the waste code(s) applicable to the disposal of these products.
SECTION 14: TRANSPORT INFORMATION
DOT: Shipping Name: Not regulated.
TDG: Shipping Name: NOT REGULATED.
EMERGENCY RESPONSE GUIDE
NUMBER: Not applicable.Reference North American Emergency Response Guidebook
SECTION 15: REGULATORY INFORMATION
USA REGULATIONS
SARA SECTIONS 302
AND 304: Based on the ingredient listed in SECTION 2, these products do not contain any "extremely
hazardous substances" listed pursuant to Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part
355, Appendix A and B.
SARA SECTIONS 311
AND 312: This product poses the following health hazards as defined in 40 CFR Part 370 and is subject to
the requirements of sections 311 and 312 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Delayed (Chronic) Health
Hazard
SARA SECTION 313: These products contain a "toxic" chemical subject to the requirements of section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372.
Material CAS Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, 68649-42-3 zinc salts (under the zinc
compounds category)
CERCLA: Based on the ingredients listed in SECTION 2, these products do not contain any "hazardous
substances" listed pursuant to the Comprehensive Environmental Response, Compensation and
Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.
TSCA: All the components of these products are listed on, or are automatically included as "naturally
occurring chemical substances" on, or are exempted from the requirement to be listed on, the
TSCA Inventory.
CALIFORNIA: These products may contain detectable amounts of acetaldehyde CAS 75-07-0, arsenic CAS
7440-38-2, benzene CAS 71-43-2, 1,3-butadiene CAS 106-99-0, cadmium CAS 7440-43-9 and
lead CAS 7439-92-1 from additives. These products may contain a detectable amount of
benzo(a)anthracene CAS 56-55-3, benzo(b)fluoranthene CAS 205-99-2, benzo(k)fluoranthene
CAS 207-08-9, benzo(a)pyrene CAS 50-32-8, chrysene CAS 218-01-9, dibenz(a,h)anthracene
CAS 53-70-3 and indeno(1,2,3-cd)pyrene CAS 193-39-5. WARNING: These chemicals are
known to the State of California to cause cancer. Our testing of these products indicates that
these chemicals are not always detectable. These products may contain a detectable amount of arsenic
CAS 7440-38-2, benzene CAS 71-43-2, cadmium CAS 7440-43-9 and lead CAS 7439-92-1from
additives. WARNING: These chemicals are known to the State of California to cause birth defects or
other reproductive harm.
Page 7 of 8
CANADIAN REGULATIONS
These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all information required by the CPR.
WHMIS: Not regulated.
CANADIAN ENVIRONMENTAL PROTECTION
ACT (CEPA): All the components of these products are listed on, or are automatically included as "substance
occurring in nature" on, or are exempted from the requirements to be listed on, the
Canadian Domestic Substances List (DSL).
SECTION 16. OTHER INFORMATION
REVISION
INFORMATION: This MSDS has been revised in the following sections: Section 1: Product Name
LABEL/OTHER
INFORMATION: Not available
User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein
is accurate. However, Dixie Gas And Oil Corporation assumes no liability whatsoever for the accuracy or completeness of the
information contained herein. No representations or warranties, either express or implied, or merchantability, fitness for a particular
purpose or of any other nature are made hereunder with respect to information or the product to which information refers. The data
contained on this sheet apply to the product(s) as supplied to the user.
.
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