Passenger Car Engine Oils (API SM)
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SUPROTEK ADVANTAGE ENGINE OIL
Includes grades 5W-30, 10W-30, 10W-40, 15W-40, 20W-20, 20W-50, 10W, 20W, 30 AND
40.
SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.
PRODUCT CODE: Prefix 21
For lubricating passenger car motors.
PRODUCT USE: If these products are used in combination with other products, refer to the Material
Safety Data Sheet for those products.
This number is for emergency use only. If 24-HOUR EMERGENCY PHONE NUMBER
you desire non-Emergency product MEDICAL AND TRANSPORTATION (SPILL):
information, please call a phone number
listed below. CHEMTREC: (800) 424-9300
SUPPLIER: Dixie Gas & Oil Corporation
229 Lee Highway
Verona, VA 24482
www.dixiegas.com
800-403-4943
TECHNICAL
INFORMATION: 540-248-6273
MSDS FORM NUMBER: 82479 ISSUE: March 4, 2005
ORIGINAL ISSUE: October 31, 1998 SUPERSEDES: April 4, 2003
PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force
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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL** ACGIH TLV庐
WT%* NAME SYNONYM CAS NO. TWA STEL TWA STEL LDa LCb
Mg/m3 Mg/m3 Mg/m3 G/kg
Lubricating oils,
petroleum, Hydrotreated c c c
35-93 64742-58-1 N. Av. N. Av. N. Av.
5 5 10
hydrotreated paraffinic base oil
spent
Lubricating oils,
petroleum, C20- c c c
0-60 N. Av. 72623-87-1 N. Av. N. Av. N. Av.
5 5 10
50, hydrotreated
neutral oil-based
Petroleum
>15 g/kg
distillates, c c c
4-42 N. Av. 64742-54-7 N. Av. N. Av.
5 5 10 d
hydrotreated (>5 g/kg)
heavy paraffinic
Lubricating oils
(petroleum), >5 g/kg
c c c
0-30 Bright stock 72623-83-7 N. Av. N. Av.
C>25, 5 5 10 d
(>3 g/kg)
hydrotreated
bright stock
Residual oils
c c c
0-30 (petroleum), Bright stock 64742-62-7 N. Av. N. Av. N. Av.
5 5 10
solvent dewaxed
Residual oils
c c c
0-30 Bright stock 64742-57-0 N. Av. N. Av. N. Av.
(petroleum), 5 5 10
hydrotreated
Lubricating oils,
petroleum, C15- c c c
0-30 N. Av. 72623-86-0 N. Av. N. Av. N. Av.
5 5 10
30, hydrotreated
neutral oil-based
0-12 Polyolefin *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
Polyolefin amide
1-10 *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
alkeneamine
c c c
0-9 Mineral oil *** *** N. Av. N. Av. N. Av.
5 5 10
Petroleum
distillates, solvent- c c c
0-7 N. Av. 64741-88-4 N. Av. N. Av. N. Av.
5 5 10
refined heavy
paraffinic
Phosphorodithioic
Dialkyl (C1-C14)
acid, O,O-di-C1-
0.5-6 dithiophosphoric 68649-42-3 N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
14-alkyl esters,
acid, zinc salt
zinc salts
0.5-4 Calcium sulfonate *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0.5-2 Alkylamine *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0-2 Polyolefin ester *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0.5-3 Alkylated phenol *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0-2 Calcium phenate *** *** N. Av N. Av N. Av N. Av N. Av N. Av
**OSHA Final PEL value (enforceable). Some States have adopted more stringent values.
N. Av. = Not Available ***Supplier advises that this is a trade secret c
Based on Oil mist, mineral
a d
Oral-Rat LD50 Skin-Rabbit LD50
* Even though the concentration range does not fall under the ranges prescribed by b
Inhalation-Rat LC50
WHMIS, this is the actual range which varies with each batch of the product.
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SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
APPEARANCE
Liquid, amber, petroleum odor.
CAUTION!
HEALTH HAZARDS
May be harmful if swallowed.
May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin.
POTENTIAL HEALTH EFFECTS
These products are not likely to present an inhalation hazard at normal temperatures and
INHALATION pressures. However, when aerosolizing, misting, or heating these products, high
(BREATHING): concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and
lungs).
EYES: May cause irritation.
SKIN: May cause irritation. Not likely to be absorbed through the skin in harmful amounts.
May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.
INGESTION
Breathing product into the lungs during ingestion or vomiting may cause lung injury and
(SWALLOWING):
possible death.
MEDICAL CONDITIONS
Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin
AGGRAVATED BY
disorders may have increased susceptibility to the effects of exposure.
EXPOSURE:
Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue
inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause
CHRONIC: inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis).
Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or
swelling (dermatitis).
CANCER No known carcinogenicity. For more information, see SECTION 11: CARCINOGENICITY.
INFORMATION: Also see SECTION 15: CALIFORNIA.
POTENTIAL ENVIRONMENTAL EFFECTS
Not available. Also see SECTION 12: ECOLOGICAL INFORMATION.
SECTION 4: FIRST AID MEASURES
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
INHALATION
oxygen. Oxygen should only be administered by qualified personnel. Someone should stay
(BREATHING):
with victim. Get medical attention if breathing difficulty persists.
If irritation or redness from exposure to vapor develops, move away from exposure into fresh
EYES: air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart,
for 15 minutes. Get medical attention.
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Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical
attention if irritation or pain develops or persists. If product is injected under pressure into or
SKIN:
under the skin, or into any part of the body, regardless of the appearance of the wound or its
size, a physician should immediately evaluate the individual as a medical emergency.
Do NOT induce vomiting. Immediately get medical attention. Call 1-800-752-7869 for
INGESTION
additional information. If spontaneous vomiting occurs, keep head below hips to avoid
(SWALLOWING):
breathing the product into the lungs. Never give anything by mouth to an unconscious person.
NOTE TO Treat symptomatically and supportively. Treatment may vary with condition of victim and
PHYSICIANS: specifics of incident. Call 800-424-9300 for additional information.
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: 383潞F (195潞C) (minimum) Cleveland Open Cup
FLAMMABLE LIMITS
LOWER: Not available UPPER: Not available
IN AIR:
AUTOIGNITION
Not available
TEMPERATURE:
HAZARDOUS Decomposition and combustion materials may be toxic. Burning may produce aldehydes,
COMBUSTION hydrogen sulfide, alkyl mercaptans, sulfides, carbon monoxide, oxides of sulfur, calcium and
PRODUCTS: zinc and other unidentified organic compounds.
CONDITIONS OF Heat, sparks, or flame. Product may burn, but does not ignite readily.
FLAMMABILITY:
EXTINGUISHING Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may
MEDIA: cause frothing.
NFPA 704
HAZARD This information is intended solely for the use by individuals trained in this system.
IDENTIFICATION:
Health Hazard (Blue) 1 Fire Hazard (Red) 1
Specific Hazard (White) Reactivity (Yellow) 0
FIRE FIGHTING Keep storage containers cool with water spray. A positive-pressure, self-contained breathing
INSTRUCTIONS: apparatus (SCBA) and full-body protective equipment are required for fire emergencies.
FIRE AND EXPLOSION Heated containers may rupture. "Empty" containers may retain residue and can be dangerous.
HAZARDS: Products are not sensitive to mechanical impact or static discharge.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear
protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid
breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid for possible recovery,
or sorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable container for disposal.
Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.
Page 4 of 8
SECTION 7: HANDLING AND STORAGE
Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe
for such locations should be used. Use clean tools. When transferring large volumes of product,
metal containers, including trucks and tank cars, should be grounded and bonded. These
products have a low vapor pressure and are not expected to present an inhalation hazard under
HANDLING:
normal temperatures and pressures. However, when aerosolizing, misting, or heating these
products, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes,
skin, clothing, and shoes.
Keep container tightly closed when not in use and during transport. Store containers in a cool,
SHIPPING AND dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers
STORING: away from flame, sparks, static electricity, or other sources of ignition. Empty product containers
may retain product residue and can be dangerous.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING Provide general ventilation needed to maintain concentration of vapor or mist below applicable
CONTROLS: exposure limits. Where adequate general ventilation is unavailable, use process enclosures,
local exhaust ventilation, or other engineering controls to control airborne levels below
applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY No respiratory protection is normally required. Use NIOSH-certified P- or R- series particulate
PROTECTION: filter and organic vapor cartridges when concentration of vapor or mist exceeds applicable
exposure limits. Protection provided by air purifying respirators is limited. Do not use N-rated
respirators. Selection and use of respiratory protective equipment should be in accordance in
the USA with OSHA General Industry Standard 29 CFR 1910.134; or in Canada with CSA
Standard Z94.4.
EYE PROTECTION: Where eye contact is likely, wear safety glasses; contact lens use is not recommended.
SKIN PROTECTION: Where skin contact is likely, wear neoprene, nitrile, or equivalent protective gloves; use of
natural rubber or equivalent gloves is not recommended. When products are heated and skin
contact is likely, wear heat-resistant gloves, boots, and other protective clothing. To avoid
prolonged or repeated contact where spills and splashes are likely, wear appropriate chemical-
resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other protective clothing.
PERSONAL Use good personal hygiene. Wash thoroughly with soap and water after handling product and
HYGIENE: before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and
protective equipment before reuse. Discard leather articles, such as shoes, saturated with these
products.
OTHER PROTECTIVE Where spills and splashes are likely, facilities storing or using these products should be
EQUIPMENT: equipped with an emergency eyewash and shower, both equipped with clean water, in the
immediate work area.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE, Liquid, amber, petroleum odor.
APPEARANCE, AND ODOR:
ODOR THRESHOLD: Not available
MOLECULAR WEIGHT: Not applicable
SPECIFIC GRAVITY: 0.88 (water = 1) (approximately)
DENSITY: 7.3 LB/US gal (880 g/l) (approximately)
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VAPOR DENSITY: Not available
VAPOR PRESSURE: less than 0.1 mmHg at 68潞F (20潞C)
BOILING POINT: 475潞F (246潞C) (minimum)
FREEZING/MELTING POINT: Not available [pour point 0潞F (-18潞C) (maximum)].
pH: Not applicable
EVAPORATION RATE: Not available
SOLUBILITY IN WATER: Insoluble
FLASH POINT: 383潞F (195潞C) minimum Cleveland Open Cup
FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available
AUTOIGNITION TEMPERATURE: Not available
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal temperatures and pressures. Avoid sparks or flame when not in use.
INCOMPATIBILITY: Avoid oxidizing agents, acids and reactive halogens.
REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive
with water.
HAZARDOUS None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS
DECOMPOSITION COMBUSTION PRODUCTS.
PRODUCTS:
SECTION 11: TOXICOLOGICAL INFORMATION
Based on best current information, there is no known human sensitization associated with
SENSITIZATION:
these products.
MUTAGENICITY: Experimental evidence suggests that these products do not cause mutagenesis.
Based on best current information, there is no known carcinogenicity as categorized by ACGIH
A1 or A2 substances; as categorized by IARC Group 1, Group 2A, or Group 2B agents; or as
CARCINOGENICITY: listed by NTP as either known carcinogens or substances for which there is limited evidence of
carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals.
Also see SECTION 15: CALIFORNIA.
REPRODUCTIVE Based on best current information, there is no known reproductive toxicity associated with
TOXICITY: these products. Also see SECTION 15: CALIFORNIA.
Based on best current information, there is no known teratogenicity associated with these
TERATOGENICITY:
products.
TOXICOLOGICALLY
Based on best current information, there are no known toxicologically synergistic products
SYNERGISTIC
associated with these products.
PRODUCT(S):
SECTION 12: ECOLOGICAL INFORMATION
Page 6 of 8
ECOTOXICITY: Not available.
OCTANOL/WATER
Not available
PARTITION
COEFFICIENT:
VOLATILE
100 WT%; 7.3 LB/US gal; 880 g/l (approximately)
ORGANIC
As per 40 CFR Part 51.100(s).
COMPOUNDS:
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose in accordance with federal, state, provincial, and local regulations. Regulations may
DISPOSAL: also apply to empty containers. The responsibility for proper waste disposal lies with the owner
of the waste. Contact Dixie Gas And Oil Corporation regarding proper recycling or disposal.
These products, if discarded, are not expected to be a characteristic or listed hazardous waste.
USEPA WASTE If recycled in the USA, they must be managed in accordance with 40 CFR Part 279. Processing,
CODE(S): use, or contamination by the user may change the waste code(s) applicable to the disposal of
these products.
SECTION 14: TRANSPORT INFORMATION
DOT: Not regulated
TDG: Not regulated
Not applicable.
EMERGENCY RESPONSE GUIDE NUMBER:
Reference North American Emergency Response Guidebook
SECTION 15: REGULATORY INFORMATION
USA REGULATIONS
Based on the ingredient(s) listed in SECTION 2, these products do not contain any "extremely
SARA SECTIONS hazardous substances" listed pursuant to Title III of the Superfund Amendments and
302 AND 304: Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part
355, Appendix A and B.
These products pose the following health hazard(s) as defined in 40 CFR Part 370 and are
subject to the requirements of sections 311 and 312 of Title III of the Superfund Amendments
SARA SECTIONS
and Reauthorization Act of 1986 (SARA):
311 AND 312:
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
These products contain "toxic" chemical(s) subject to the requirements of section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372.
SARA SECTION 313: Material CAS
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, 68649-42-3
zinc salts (related to zinc compounds)
Based on the ingredient(s) listed in SECTION 2, this product does not contain any "hazardous
CERCLA: substances" listed under the Comprehensive Environmental Response, Compensation and
Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.
All the components of these products are listed on, or are automatically included as "naturally
TSCA: occurring chemical substances" on, or are exempted from the requirement to be listed on, the
TSCA Inventory.
Page 7 of 8
These products may contain a detectable amount of arsenic CAS 7440-38-2, benzene CAS 71-
43-2, cadmium CAS 7440-43-9 and lead CAS 7439-92-1 from additives. These products may
contain a detectable amount of benzo(a)anthracene CAS 56-55-3, benzo(b)fluoranthene CAS
205-99-2, benzo(k)fluoranthene CAS 207-08-9, benzo(a)pyrene CAS 50-32-8, chrysene CAS
CALIFORNIA:
218-01-9, dibenz(a,h)anthracene CAS 53-70-3 and indeno(1,2,3-cd)pyrene CAS 193-39-5.
WARNING: These chemicals are known to the State of California to cause cancer. Our testing
of these products indicates that these chemicals are not always detectable.
These products may contain a detectable amount of arsenic CAS 7440-38-2, benzene CAS 71-43-2, cadmium CAS
7440-43-9 and lead CAS 7439-92-1from additives. WARNING: These chemicals are known to the State of California to
cause birth defects or other reproductive harm.
CANADIAN REGULATIONS
These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)
and the MSDS contains all information required by the CPR.
WHMIS: Not regulated
CANADIAN
All the components of these products are listed on, or are automatically included as "substance
ENVIRONMENTAL
occurring in nature" on, or are exempted from the requirements to be listed on, the Canadian
PROTECTION ACT
Domestic Substances List (DSL).
(CEPA):
SECTION 16. OTHER INFORMATION
REVISION INFORMATION: New formulation
LABEL/OTHER INFORMATION: Not available
User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information
contained herein is accurate. However, Dixie Gas And Oil Corporation assumes no liability whatsoever for the accuracy or
completeness of the information contained herein. No representations or warranties, either express or implied, or
merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or
the product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user.
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