MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 409 SUPER BONDER庐 INDUSTRIAL GRADE GEL INSTANT ADHESIVE
SYNONYMS: N/A
PRODUCT CODES: 72570-09
MANUFACTURER: ELECTRON MICROSCOPY SCIENCES
DIVISION: 1560 INDUSTRY ROAD/P.O. BOX 550
ADDRESS: HATFIELD, PA 19440
EMERGENCY PHONE: 215-412-8400
CHEMTREC PHONE: 800-424 -4300
FAX PHONE: 215-412-8450
CHEMICAL NAME: N/A
CHEMICAL FAMILY: N/A
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT:
ETHYL CYANOACRYLATE
CAS NO. % WT % VOL SARA 313 REPORTABLE
7085-85-0 N/A 60-100
ppm mg/m3
OSHA PEL-TWA: N/A N/A
OSHA PEL STEL : N/A N/A
OSHA PEL CEILING: N/A N/A
ACGIH TLV-TWA: 0.2 N/A
ACGIH TLV STEL: N/A N/A
ACGIH TLV CEILING: N/A N/A
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
ROUTES OF ENTRY: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS
EYES: IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND.
SKIN: BONDS TO SKIN IN SECONS. MAY CAUSE SKIN IRRITATION. CYANOACRYLATES HAVE BEEN REPORTED TO CAUSE
ALLERGIC REACTION BUT DUE TO RAPID POLYMERIZATION AT THE SKIN SURFACE. AN ALLERGIC RESPONSE IS RARE.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES) AND BONDS IN MOUTH.
IT IS ALMOST IMPOSSIBLE TO SWALLOW.
INHALATION: EXPOSURE TO VAPORS ABOVE THE ESTABLISHED EXPOSURE LIMIT RESULTS IN RESPIRATORY IRRITATION
WHICH MAY LEAD TO DIFFICULTY IN BREATHING AND TIGHTNESS IN THE CHEST
ACUTE HEALTH HAZARDS: N/A
CHRONIC HEALTH HAZARDS: N/A
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: EYE, SKIN, AND RESPIRATORY DISORDERS
CARCINOGENICITY
OSHA: NO ACGIH: N/A NTP: NO IARC: NO
OTHER: N/A
PAGE 1 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
SECTION 4: FIRST AID MEASURES
EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF EYELIDS ARE BONDED CLOSED, RELEASE EYELASHES WITH WARM
WATER BY COVERING WITH A WET PAD. DO NOT FORCE EYE OPEN. CYANOACRYLATE WILL BOND TO EYE PROTIEN AND WILL
CAUSE A LACHRYMATORY EFFECT WHICH WILL HELP TO DEPOND THE ADHESIVE. KEP EYE COVERED UNTIL DEBONDING IS
COMPLETE, USUALLY WITHIN 1-3 DAYS. MEDICAL ATTENTION SHOULD BE SOUGHT IN CASE SOLID PARTICLES OF
POLYMERIZED CYANOACRYLATE TRAPPED BEHIND THE EYELID CAUSED ABRASIVE DAMAGE
SKIN: DO NO PULL BONDED SKIN APART. SOAK IN WARM SOAPY WATER. GENTLY PEEL APART USING A BLUNT INSTRUMENT.
IF SKIN IS BURNED DUE TO THE RAPID GENERATION OF HEAT BY A LARGE DROP, SEEK MEDICAL ATTENTION. IF LIPS ARE
BONDED, APPLY WARM WATER TO THE LIPS AND ENCOURAGE WETTING AND PRESSURE FROM SALIVA IN MOUTH. PEEL OR
ROLL LIPS APART. DO NOT PULL LIPS APART WITH DIRECT OPPOSING FORCE.
INGESTION: ENSURE BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL POLYMERIZE RAPIDLY AND BOND
TO THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW. SALICA WILL SEPARATE ANY SOLIDIFIED PRODUCT IN
SEVERAL HOURS. PREVENT THE PATIENT FROM SWALLOWING ANY SEPERATED MASS.
INHALATION: REMOVE TO FRESH AIR. IF DISCOMFORT PERSISTS SEEK MEDICAL ATTENTION
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED
TISSUES. EXPIRIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE, NON-SURGICAL FIRST AID. IF
RAPID CURING HAS CAUSED THERMAL BURNS THEY SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS
REMOVED.
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, UPPER: N/A
(% BY VOLUME) LOWER: N/A
FLASH POINT:
F: 176-200 DEG
C: 80-93.4 DEG
METHOD USED:
AUTOIGNITION TEMPERATURE:
F: 905 DEG
C: 485 DEG
NFPA HAZARD CLASSIFICATION
HEALTH: N/A FLAMMABILITY: N/A REACTIVITY: N/A
OTHER: N/A
HMIS HAZARD CLASSIFICATION
HEALTH: N/A FLAMMABILITY: N/A REACTIVITY: N/A
PROTECTION: N/A
EXTINGUISHING MEDIA: WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS (SCBA).
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
HAZARDOUS DECOMPOSITION PRODUCTS: TRACE AMOUNTS OF TOXIC FUMES MAY BE RELEASED ON INCINERATION AND THE
USE OF BREATHING APPARATUS IS RECOMMENDED.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: VENTILATE AREA. DO NOT SUE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO
COMPLETE POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE DISPOSED OF AS NON-HAZARDOUS
WASTE.
PAGE 2 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID BREATHING VAPOR AND MIST. WASH
THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH FABRIC OR PAPER GOODS. CONTACT WITH THESE MATERIALS MAY
CAUSE RAPID POLYMERIZATION WHICH CAN GENERATE SMOKE AND STRONG IRRITATING VAPORS, AND CAUSE THERMAL
BURNS.
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS, AND OPEN FLAME. KEEP CONTAINER TIGHTLY
CLOSED UNTIL READY FOR USE.
OTHER PRECAUTIONS: N/A
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: USE POSIIVE DOWN-DRAFT EXHAUST VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO
MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
VENTILATION: N/A
RESPIRATORY PROTECTION: USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE LIMITS.
EYE PROTECTION: CHEMICAL SPLASH GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS
SKIN PROTECTION: USE NITRILE GLOVES AND APRONS AS NECESSARY TO PREVENT CONTACT. DO NOT USE PVC, NYLON OR
COTTON.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: N/A
WORK HYGIENIC PRACTICES: N/A
EXPOSURE GUIDELINES: N/A
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: CLEAR COLORLESS
ODOR: SHARP, IRRITATING
PHYSICAL STATE: LIQUID
pH AS SUPPLIED: N/A
pH (Other): N/A
BOILING POINT:
F: > 300 DEG
C > 149
MELTING POINT: N/A
F: N/A
C: N/A
FREEZING POINT: N/A
F: N/A
C: N/A
VAPOR PRESSURE (mmHg): < 0.5 MM HG
@
F: 77 DEG
C: 25 DEG
VAPOR DENSITY (AIR = 1): APPROXIMATELY 3
@
F: N/A
C: N/A
@
F: N/A
C: N/A
PAGE 3 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
EVAPORATION RATE: N/A
BASIS (=1): N/A
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (con鈥檛)
SOLUBILITY IN WATER: POLYMERIZES IN PRESENCE OF WATER
PERCENT SOLIDS BY WEIGHT:
PERCENT VOLATILE: N/A
BY WT/ BY VOL @
F: N/A
C: N/A
VOLATILE ORGANIC COMPOUNDS (VOC):
WITH WATER: < 20 LBS/GAL
WITHOUT WATER: N/A LBS/GAL
MOLECULAR WEIGHT: N/A
VISCOSITY: N/A
@
F: N/A
C: N/A
SECTION 10: STABILITY AND REACTIVITY
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS
CONDITIONS TO AVOID (STABILITY): N/A
INCOMPATIBILITY (MATERIAL TO AVOID): WATER, AMINES, ALKALIS AND ALCOHOLS
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: NONE
HAZARDOUS POLYMERIZATION: RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER, AMINES,
ALKALIS AND ALCOHOLS
CONDITIONS TO AVOID (POLYMERIZATION): SPONTANEOUS POLYMERIZATION
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
ACUTE ORAL LD50 >5000 MG/KG (RAT)(ESTIMATED).
ACUTE ORAL LD50 > 2000 MG/KG (RABBIT)(ESTIMATED).
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: N/A
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: COMPLY WITH FEDERAL, STATE, LOCAL REGULATIONS.
RCRA HAZARD CLASS: NOT A RCRA HAZARDOUS WASTE
PAGE 4 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
SECTION 13: DISPOSAL CONSIDERATIONS (con鈥檛)
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME: COMBUSTIBLE LIQUIDS, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS: COMBUSTIBLE LIQUID
ID NUMBER: NA 1993
PACKING GROUP: NONE
LABEL STATEMENT: N/A
WATER TRANSPORTATION
PROPER SHIPPING NAME: UNRESTRICTED
HAZARD CLASS: N/A
ID NUMBER: N/A
PACKING GROUP: N/A
LABEL STATEMENTS: N/A
AIR TRANSPORTATION
PROPER SHIPPING NAME: AVIATION REGULATED LIQUIDS, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS: 9
ID NUMBER: UN 3334
PACKING GROUP: NONE
LABEL STATEMENTS: N/A
OTHER AGENCIES: N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT): ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): N/A
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HAZARD CATEGORIES: IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD, FIRE REACTIVE.
313 REPORTABLE INGREDIENTS: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986
(40 CFR 372) NONE.
STATE REGULATIONS: N/A
INTERNATIONAL REGULATIONS:
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS: ALLCOMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE DOMESTIC SUBSTANCES
LIST.
SECTION 16: OTHER INFORMATION
OTHER INFORMATION: N/A
PREPARATION INFORMATION: N/A
DISCLAIMER: IN COMPLIANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD, 2.9 C.F.R
PAGE 5 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/07/07
1910. 1200, WE ARE PROVIDING YOU WITH A MSDS FOR THE HAZARDOUS MATERIAL YOU ARE
PURCHASING.
IT IS YOUR RESPONSIBILITY TO EDUCATE YOUR EMPLOYEES ON THE SAFE USE OF THE HAZARDOUS
MATERIAL.
ELECTRON MICROSCOPY SCIENCES MAKES NO PRESENTATION AS TO THE ACCURACY OF THE
INFORMATION IN THE MSDS. THE INFORMATION IS BELIEVED TO BE CORRECT; HOWEVER, YOU
(THE CUSTOMER), SHOULD PERFORM YOUR OWN INVESTIGATION AND INDEPENDENT
VERIFICATION. IF YOU RESELL THE PRODUCT, YOU ARE RESPONSIBLE TO FORWARD THE
INFORMATION IN THE MSDS TO YOUR CUSTOMER.
PAGE 6 OF 6
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