MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: KODAK DEVELOPER SYSTEM CLEANER AND NEUTRALIZER, NEUTRALIZER
SYNONYMS: KAN 965714; PCD 5812; S-0160.200
PRODUCT CODES: 74270-01
MANUFACTURER: ELECTRON MICROSCOPY SCIENCES
DIVISION: 1560 INDUSTRY ROAD/P.O. BOX 550
ADDRESS: HATFIELD, PA 19440
EMERGENCY PHONE: 215-412-8400
CHEMTREC PHONE: 800-424 -4300
FAX PHONE: 215-412-8450
CHEMICAL NAME: N/A
CHEMICAL FAMILY: N/A
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT:
CONCENTRATE:
WATER
SODIUM BISULFITE
SODIUM SULFITE
SODIUM CITRATE
WORKING SOLUTION:
WATER
SODIUM BISULFITE
SODIUM SULFITE
SODIUM CITRATE
% WT % VOL SARA 313 REPORTABLE
CAS NO.
-
007732-18-5 70-75 N/A
007631-90-5 15-20 N/A
007757-83-7 5-10 N/A
000068-04-2 <1 N/A
-
007732-18-5 95-100 N/A
007631-90-5 1-5 N/A
007757-83-7 1-5 N/A
000068-04-2 <1 N/A
mg/m3
ppm
OSHA PEL-TWA: N/A N/A
OSHA PEL STEL : N/A N/A
OSHA PEL CEILING: N/A N/A
ACGIH TLV-TWA: N/A N/A
ACGIH TLV STEL: N/A N/A
ACGIH TLV CEILING: N/A N/A
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES SKIN AND EYE IRRITATION
ROUTES OF ENTRY: INHALATION, EYES, SKIN, INGESTION
POTENTIAL HEALTH EFFECTS
EYES: CONCENTRATE: CAUSES IRRITATION
WORKING SOLUTION: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION.
SKIN: CONCENTRATE: CAUSES IRRITATION. THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED.
WORKING SOLUTION: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS;
HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED.
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MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
INGESTION: CONCENTRATE: MAY BE HARMFUL IF SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS
MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND
DIARRHEA. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
WORKING SOLUTION: MAY BE HARMFUL IF SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR
DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY
EXPIRIENCE DIFFICULT BREATHING.
ACUTE HEALTH HAZARDS: N/A
CHRONIC HEALTH HAZARDS: N/A
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A
CARCINOGENICITY
OSHA: N/A ACGIH: N/A NTP: N/A IARC: N/A
OTHER: N/A
SECTION 4: FIRST AID MEASURES
EYES: FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATION OCCURS, SEEK MEDICAL ATTENTION
SKIN: WASH WITH SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED
CLOTHING BEFORE REUSE. DESTROY OF THOROUGHLY CLEAN CONTAMINATED SHOES. IF IRRITATION OCCURS, SEEK
MEDICAL ATTENTION.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICALATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS
PERSIST.
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: N/A
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, UPPER: N/A
(% BY VOLUME) LOWER: N/A
FLASH POINT: NONE (NON COMBUSTIBLE LIQUID)
F:
C:
METHOD USED: N/A
AUTOIGNITION TEMPERATURE: N/A
F: N/A
C: N/A
NFPA HAZARD CLASSIFICATION
HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
OTHER:N/A
HMIS HAZARD CLASSIFICATION
HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
PROTECTION: B
EXTINGUISHING MEDIA: USE APPROPRIATE AGENT FOR ADJACENT FIRE.
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MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE
OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DEOMPOSITION PRODUCTS
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH
VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: AVOID BREATHING MIST OF VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLIING.
CONCENTRATE: KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
WORKING SOLUTION: KEEP CONTAINER CLOSED.
OTHER PRECAUTIONS: N/A
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
VENTILATION: GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES
SHOULD BE MATCHED TO CONDITIONS.
RESPIRATORY PROTECTION: NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION
PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED.
RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND REACTIVITY SECTION. IF RESPIRATORS ARE USED, A PROGRAM SHOULD
BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION: WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
WORK HYGIENIC PRACTICES: N/A
EXPOSURE GUIDELINES: LIMITS:
ACGIH THRESHOLD LIMIT VALUE (TLV:
SODIUM BISULFATE: 5 MG/M3 TWA
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: COLORLESS
ODOR: ODORLESS
PHYSICAL STATE: LIQUID
pH AS SUPPLIED: CONCENTRATE: 5.7 WORKING SOLUTION:6.3
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MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
pH (Other): N/A
BOILING POINT:
F: > 212 DEG
C: > 100 DEG
MELTING POINT:N/A
F: N/A
C: N/A
FREEZING POINT: N/A
F: N/A
C: N/A
VAPOR PRESSURE (mmHg): 24 MBAR (18 MM HG)
@
F: 68 DEG
C: 20 DEG
VAPOR DENSITY (AIR = 1): 0.6
@
F: N/A
C: N/A
@
F: N/A
C: N/A
EVAPORATION RATE: N/A
BASIS (=1): N/A
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (con鈥檛)
SOLUBILITY IN WATER: COMPLETE
PERCENT SOLIDS BY WEIGHT: N/A
PERCENT VOLATILE: N/A
BY WT/ BY VOL @
F: N/A
C: N/A
VOLATILE ORGANIC COMPOUNDS (VOC): N/A
WITH WATER: N/A LBS/GAL
WITHOUT WATER: N/A LBS/GAL
MOLECULAR WEIGHT: N/A
VISCOSITY: N/A
@
F: N/A
C: N/A
SECTION 10: STABILITY AND REACTIVITY
STABILITY: STABLE
CONDITIONS TO AVOID (STABILITY):
INCOMPATIBILITY (MATERIAL TO AVOID): CONCENTRATE: STRONG ACIDS
WORKING SOLUTION: NONE WITH COMMON MATERIALS AND CONTAMINANTS
WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: SULFUR DIOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID (POLYMERIZATION): N/A
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MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
EYES: CONCENTRATE: CAUSES IRRITATION
WORKING SOLUTION: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION.
SKIN: CONCENTRATE: CAUSES IFFITATION. THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED.
WORKING SOLUTION: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS;
HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED.
INGESTION: CONCENTRATE: MAY BE HARMFUL IF SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS
MAY EXPIRIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND
DIARRHEA. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
WORKING SOLUTION: MAY BE HARMFUL IF SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPIRIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE
GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPIRIENCE DIFFICULT BREATHING.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE
PREPARATIONS.
POTENTIAL TOXICITY CONCENTRATE WORKING SOLUTION
FISH LC50 MG/L: > 100 > 100
DAPHNID EC50 MG/L: > 100 > 100
ALGAL IC50 MG/L: > 100 > 100
ORGANICS READILY DEGRADABLE (> 70%): YES (7 DAYS) YES (7 DAYS)
POTENTIAL BIOACCUMULATION: LOG POW < 1 LOG POW <1
COD (APPROXIMATE G/L): 51 5
BOD5 (APPROXIMATE G/L) 51 5
WASTE TREATMENT MICROORGANISMS
EC50 (MG/L): > 100 > 100
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: COMPLY WITH FEDERAL, STATE, LOCAL REGULATIONS.
RCRA HAZARD CLASS: N/A
SECTION 13: DISPOSAL CONSIDERATIONS (con鈥檛)
DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH
LARGE AMOUNTS OF WATER.
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME: FOR TRANSPORT INFORMATION REGARDING THIS PRODUCT CALL THE KODAK
HAZARD CLASS: WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 22-2400 BETWEEN
ID NUMBER: 8 a.m. AND 5 p.m. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY.
PACKING GROUP:
LABEL STATEMENT:
WATER TRANSPORTATION
PROPER SHIPPING NAME: SAME
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
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MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
LABEL STATEMENTS:
AIR TRANSPORTATION
PROPER SHIPPING NAME: SAME
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
LABEL STATEMENTS:
OTHER AGENCIES: N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT): N/A
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): N/A
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): NONE
311/312 HAZARD CATEGORIES: NONE
313 REPORTABLE INGREDIENTS: NONE
STATE REGULATIONS:
MATERIALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE
MATERIALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSDE REPRODUCTIVE EFFECTS: NONE
CARCINOGENICITY CLASSIFICATION ( COMPONENTS PRESENT AT 0.1 % OR MORE):
-INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE
-AMERICAN CONFERENCE OF GOVERMENTAL INDUSTRIAL HYGEINISTS (ACGIH): SODIUM BISULFITE, A4, NOT CLASSIFIABLE AS
A HUMAN CARCINOGEN.
- NATIONAL TOXICOLOGY PROGRAM (NTP): NONE
-OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION ( OSHA): NONE
INTERNATIONAL REGULATIONS: N/A
SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
US/CANADIAN LABEL STATEMENTS
CONCENTRATE:
CONTAINS SODIUM BISULFITE; SODIUM SULFITE
WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES IRRITATION
AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION.
WASH THOROUGHLY AFTER HANDLING.
FIRST AID: IF SWALLOWED, SEEK MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IN
CASE OF CONTACT, IMMEDIATELY FLUSH EYES AND SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED
CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES.
KEEP OUT OF REACH OF CHILDREN.
WORKING SOLUTION:
CONTAINS SODIUM BISULFITE; SODIUM SULFITE
WARNING! MAY BE HARMFUL IF SWALLOWED
AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE
WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
FIRST AID: IF SWALLOWED, SEEK MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
KEEP OUT OF REACH OF CHILDREN.
PREPARATION INFORMATION:
PAGE 6 OF 7
MATERIAL SAFETY DATA SHEET
MSDS DATE:08/14/07
DISCLAIMER: IN COMPLIANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD, 2.9 C.F.R
1910. 1200, WE ARE PROVIDING YOU WITH A MSDS FOR THE HAZARDOUS MATERIAL YOU ARE
PURCHASING.
IT IS YOUR RESPONSIBILITY TO EDUCATE YOUR EMPLOYEES ON THE SAFE USE OF THE HAZARDOUS
MATERIAL.
ELECTRON MICROSCOPY SCIENCES MAKES NO PRESENTATION AS TO THE ACCURACY OF THE
INFORMATION IN THE MSDS. THE INFORMATION IS BELIEVED TO BE CORRECT; HOWEVER, YOU
(THE CUSTOMER), SHOULD PERFORM YOUR OWN INVESTIGATION AND INDEPENDENT
VERIFICATION. IF YOU RESELL THE PRODUCT, YOU ARE RESPONSIBLE TO FORWARD THE
INFORMATION IN THE MSDS TO YOUR CUSTOMER.
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