MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec) Health : 3
Lonza Inc.90 Boroline Road Allendale NJ 07401 Flammability : 1
800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm) Reactivity : 0
95003 Carboquat 250 T PAGE 1 OF 6
************************************************************************************
MATERIAL DATE ISSUED DOT HAZARD CLASSIFICATION
Carboquat 250 T 10/31/04鈥? Revised 8, PG III
DOT SHIPPING NAME
CAS. NO. Mixture Corrosive Liquid, N.O.S.
SUPERCEDES
10/27/03 DOT LABEL Corrosive
Mixture
FORMULA
(Active) N-,N-Dialkyl-N,N-dimethylammonium bicarbonate/carbonate
CHEMICAL NAME
****************************** I - INGREDIENTS *************************************
APPROXIMATE
WEIGHT % TWA/TLV
N-,N-Dialkyl-N,N-dimethylammonium bicarbonate * None established
(CAS No. Proprietary)
N-,N-Dialkyl-N,N-dimethylammonium carbonate * None established
(CAS No. Proprietary)
N-Dialkyl-N,N-dimethylamine (CAS No. Proprietary) 1 None established
Methanol (CAS No. 67-56-1) 3 200 ppm OSHA TWA
200 ppm ACGIH TLV
250 ppm ACGIH STEL
Propylene glycol (CAS No. 57-55-6) 9
Water (CAS No. 7732-18-5) 36 None established
* The sum of the two asterisked components is approximately 50%
********************** II - PHYSICAL AND CHEMICAL PROPERTIES ***********************
APPEARANCE Colorless to pale yellow liquid pH 9 - 11
VISCOSITY 350 cps@21oC ODOR Slight amine
MELTING OR FREEZING POINT -10oC
BOILING POINT Not known
VAPOR DENSITY (Air=1) Not known VAPOR PRESSURE (mm Hg) Not known
PERCENT VOLATILE (by weight) 49 SOLUBILITY IN WATER Soluble
SPECIFIC GRAVITY (Water=1) 0.96 @ 25oC
EVAPORATION RATE (Butyl Acetate=1) Not
known
*********************** III - FIRE AND EXPLOSION INFORMATION ***********************
FLASH POINT >200掳F (Pensky鈥揗artin) AUTO IGNITION TEMPERATURE Not known
LOWER EXPLOSION LIMIT (%) Not known UPPER EXPLOSION LIMIT (%) Not known
ALCOHOL FOAM X CO2 X
EXTINGUISHING MEDIA FOAM
DRY CHEMICAL X WATER X OTHER
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95003 Carboquat 250 T PAGE 2 OF 6
**************** III - FIRE AND EXPLOSION INFORMATION (continued)*******************
SPECIAL FIRE FIGHTING PROCEDURES:
Must wear NIOSH approved self-contained breathing apparatus and protective clothing.
Cool fire-exposed containers with water spray.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Products of combustion are toxic.
************************ IV - HEALTH EFFECTS INFORMATION ***************************
ROUTES OF ENTRY - SKIN CONTACT X EYE CONTACT X
INHALATION INGESTION
EFFECTS OF OVEREXPOSURE
No information available on effects of overexposure. Based upon animal toxicity
information available for this and closely related materials, the following effects can
be anticipated: Direct skin or eye contact may produce severe irritation and/or
chemical burns with possibly irreversible tissue damage. Ingestion can cause immediate
burning pain in the mouth, throat and abdomen with severe swelling of the larynx.
Ingestion may cause skeletal muscle paralysis affecting the ability to breathe;
circulatory shock; and/or convulsions. May be fatal if ingested.
OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS:
No effects indicated.
EMERGENCY AND FIRST AID PROCEDURES:
For eyes contact, immediately flush eyes with large amounts of running water for at
least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of the
eye and lids with water. Get immediate medical attention. If physician not available,
flush for additional 15 minutes and then transport victim to medical care.
For skin contact, wash with plenty of running water, and soap if available, for 15
minutes. Remove contaminated clothing and shoes. Get immediate medical attention.
Wash clothing and decontaminate shoes before reuse.
If swallowed, immediately give 3-4 glasses of milk (if unavailable, give water). DO
NOT induce vomiting. If vomiting does occur, give fluids again. Get immediate medical
attention. Have physician determine if patient's condition allows for induction of
vomiting or evacuation of the stomach. Do not give anything by mouth to a convulsing
or unconscious person. (See "Note to Physician" in Section X).
If inhaled, remove from area to fresh air. Get immediate medical attention. If not
breathing, clear airway and start artificial respiration. If victim is having trouble
breathing, give supplemental oxygen, if available.
CHEMICALS LISTED AS CARCINOGEN BY:
NATIONAL TOXICOLOGY PROGRAM - No
- No
I.A.R.C. MONOGRAPHS
- No
OSHA
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95003 Carboquat 250 T PAGE 3 OF 6
********************* IV - HEALTH EFFECTS INFORMATION (continued)*******************
NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. Preventive
measures against circulatory shock should be followed, as well as, measures to support
respiration including manually or mechanically, including providing Oxygen, if needed.
*************************** V - REACTIVITY INFORMATION *****************************
X
STABILITY: STABLE CONDITIONS TO AVOID
None known
UNSTABLE
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition may produce toxic vapors/fumes of amines and other organic
materials, and oxides of carbon and nitrogen.
HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID
WILL NOT X None known
MAY
OCCUR OCCUR
INCOMPATIBILITY (MATERIALS TO AVOID)
OTHER X Strong oxidizing or reducing agents.
WATER
************************ VI - SPILL AND DISPOSAL INFORMATION ***********************
STEPS TO BE TAKEN IN CASE OF MATERIAL SPILL OR RELEASE
DANGER! Corrosive liquid. Floors may become slippery. Wear appropriate protective
equipment and NIOSH approved respirator where mists or vapors of unknown concentrations
may be generated (self-contained breathing apparatus preferred).
Dike and contain spill with inert material (sand, earth, etc.) and transfer the
liquid and solid separately to containers for recovery or disposal. Keep spill out
of sewers and open bodies of water.
WASTE DISPOSAL METHODS
Dispose of in compliance with all Federal, state and local laws and regulations.
Incineration is the preferred method.
CONTAINER DISPOSAL
Triple rinse (or equivalent). Then offer for recycling or reconditioning, or
puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by
state and local authorities, by burning. If burned, stay out of smoke.
*********************** VII - PERSONAL PROTECTION INFORMATION **********************
ENGINEERING CONTROLS
In processes where mists or vapors may be generated, proper ventilation must be
provided in accordance with good ventilation practices.
RESPIRATORY PROTECTION
In processes where mists or vapors may be generated, a NIOSH/MSHA jointly approved
respirator is advised in the absence of proper environmental controls.
PROTECTIVE GLOVES
Rubber or neoprene, to prevent skin contact.
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95003 Carboquat 250 T PAGE 4 OF 6
*********************** VII - PERSONAL PROTECTION INFORMATION **********************
EYE PROTECTION
Wear chemical splash goggles or face-shield where there is a potential for eye contact.
Use safety glasses with side shields under typical conditions, where face or eye
contact is unlikely.
OTHER PROTECTIVE EQUIPMENT
Eye wash; safety shower; protective clothing (long sleeves, coveralls or other, as
appropriate), when needed, to prevent skin contact.
*************************** VIII - STORAGE AND HANDLING ***************************
PRECAUTIONS FOR STORAGE AND HANDLING:
Maximum storage temperature: 140oF. Keep containers closed when not in use. Do not
contaminate drinking water, food or feed by storage or disposal.
Empty containers retain product residues and can be dangerous. Do not pressurize, cut
weld, braze, solder, drill, grind or expose such containers to heat or flame. They may
explode and cause injury. Follow all MSDS precautions in handling empty containers.
****************** IX - TOXICOLOGY & ECOTOXICOLOGY INFORMATION **********************
TOXICITY
The toxicology information provided below is for this material and closely related
material(s).
ACUTE
- oral LD50 (rat): 245 mg/kg
- skin irritation (rabbit): Corrosive.
- Photosensitization (guinea pig): Not a sensitizer or photoallergen.
GENOTOXICITY/MUTAGENICITY
For N,N-Dialkyl-N,N-dimethylammonium chloride:
- Ames test (in vitro 鈥? Salmonella sp.): Not mutagenic.
- CHO/HGPRT Assay (in vitro 鈥? CHO cells): Not mutagenic.
- unscheduled DNA synthesis (in vitro 鈥? CHO cells): No increase in activity.
- chromosome aberration (in vitro - CHO cells): Not clastogenic with or without
metabolic activation.
REPRODUCTIVE/DEVELOPMENTAL
For N,N-Dialkyl-N,N-dimethylammonium chloride:
- two generation reproductive/developmental study (rat - oral): No evidence of
reproductive or developmental toxicity effects was observed at exposure doses
ranging from 10-50 mg/kg/day.
- developmental (rabbit - oral): No evidence of developmental toxic effects was noted
at exposure doses ranging from 10-50 mg/kg/day administered from day 6 through 15 of
gestation.
ECOTOXICITY - AQUATIC
- LC50 (rainbow trout 鈥? 96-hour - Static): 0.810 mg/l
- LC50 (bluegill sunfish 鈥? 96-hour 鈥? Static/Renewal): 0.28 mg/l
- LC50 (sheepshead minnow 鈥? 96-hour 鈥? Static/Renewal): 1.110 mg/l
- EC50 (Daphnia magna 鈥? 48-hour - Static): 0.073 mg/l
- LC50 (mysid shrimp 鈥? 96-hour - Static): 0.066 mg/l
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95003 Carboquat 250 T PAGE 5 OF 6
******************* X - MISCELLANEOUS AND REGULATORY INFORMATION ********************
FEDERAL LEVEL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS:
Some components of this product are not currently listed on U.S. EPA TSCA 8(b)
inventory list. This material is an EPA FIFRA registered pesticide EPA
registration number 6836-236. This product can only be used commercially in the
EPA FIFRA applications(s) noted on the product label.
TSCA Section 12(b) Export Notification
Components present in this product which, if exported, could require either annual
or one-time reporting under this regulation are as follows:
Typical Maximum
Chemical Name CAS Number Concentration
None known
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of
1980 requires notification of the National Response Center
(Telephone 800-424-8802) in the event of a release of quantities of the
following hazardous materials contained in this product, if the release is
equal to or greater than the Reportable Quantities (RQs) listed in
40 CFR 302.4:
Typical Maximum
Chemical Name CAS Number Concentration
Methanol 67-56-1 3.99%
SARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of
1986) - This act requires emergency planning, including agency notification, for
possible release of the following components of this material, based upon the
Threshhold Planning Quantities (TPQs) and release Reportable Quantities (RQs)
listed for the Components in 40 CFR 355:
Typical Maximum
Chemical Name CAS Number Concentration
None known
SARA Title III Sections 311/312 - This act requires reporting under the Community
Right-to-Know provisions due to the inclusion of the following components of this
material in one or more of the five hazard categories listed in 40 CFR 370:
Hazard *)
Chemical Name CAS Number Categories
N,N-Dialkyl-N,N-dimethylammonium bicarbonate Proprietary A
N,N-Dialkyl-N,N-dimethylammonium carbonate Proprietary A
Methanol 67-56-1 A,F
*) The five hazard categories are as follows: F=FIRE HAZARD; S= SUDDEN RELEASE OF
PRESSURE; R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC)
HEALTH HAZARD
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95003 Carboquat 250 T PAGE 6 OF 6
******************* X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ********
FEDERAL LEVEL REGULATIONS (continued)
SARA Title III Section 313 - This act requires submission of annual reports of
releases of the following components of this material if the threshold reporting
quantities as listed in 40 CFR 372, are met or exceeded:
Typical Maximum
Chemical Name CAS Number Concentration
Methanol 67-56-1 3%
STATE RIGHT-TO-KNOW REGULATIONS:
CALIFORNIA PROPOSITION 65 - Components present in this material which the State of
California has found to cause cancer, birth defects or other reproductive harm
are as follows:
AS A CANCER HAZARD Typical Maximum
Chemical Name CAS Number Concentration
N-Nitrosodimethylamine 62-75-9 100 ppb
MASSACHUSETTS Right-to-Know - The following components of this material are included
in the Massachusetts Substance List and are present at or above reportable
levels:
Typical Maximum
Chemical Name CAS Number Concentration
Methanol 67-56-1 3%
MICHIGAN Critical Materials - The following components of this material are included
in the Michigan Critical Materials List:
Typical Maximum
Chemical Name CAS Number Concentration
None known
NEW JERSEY Right-to-Know - The following components of this material are included in
the New Jersey Hazardous Substance List and are present at or above reportable
levels:
Typical Maximum
Chemical Name CAS Number Concentration
N,N-Dialkyl-N,N-dimethylammonium bicarbonate Proprietary 30%
N,N-Dialkyl-N,N-dimethylammonium carbonate Proprietary 30%
Methanol 67-56-1 3%
PENNSYLVANIA Right-to-Know - The following components of this material are included
in the Pennsylvania Hazardous Substance List and are present at or above
reportable levels:
Typical Maximum
Chemical Name CAS Number Concentration
Methanol 67-56-1 3%
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
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