MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec) Health : 3
Lonza Inc.90 Boroline Road Allendale NJ 07401 Flammability : 2
800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm) Reactivity : 0
95318 Bardac 208M PAGE 1 OF 7
************************************************************************************
MATERIAL DATE ISSUED DOT HAZARD CLASSIFICATION
Bardac 208M 10/30/04 鈥? Revised 8, PG II
DOT SHIPPING NAME
CAS. NO. Mixture Disinfectants, Liquid, Corrosive, N.O.S.
SUPERCEDES
09/22/04 DOT LABEL Corrosive
Mixture
FORMULA IMO SHIPPING NAME
Corrosive liquid, flammable, N.O.S.
Marine Pollutant
(Active) mixture of N,N-Dialkyl-N,N-dimethylammonium Chloride and
CHEMICAL NAME
N-Alkyl-N,N-dimethyl-N-benzylammonium Chloride
****************************** I - INGREDIENTS *************************************
APPROXIMATE
WEIGHT % TWA/TLV
N,N-Dialkyl(C8-10)-N,N-dimethylammonium Chloride 48 None established
(CAS No. 68424-95-3)
N-Alkyl(C12-16)-N,N-dimethyl-N-benzylammonium 32 None established
Chloride (CAS No. 68424-85-1)
Ethanol (CAS No. 64-17-5) 10 1000 ppm (OSHA-PEL)
1000 ppm (ACGIH-TWA)
Water (CAS No. 7732-18-5) 10 None established
********************** II - PHYSICAL AND CHEMICAL PROPERTIES ***********************
APPEARANCE Colorless to pale yellow liquid pH 6.5 to 9.0 @ 10%
VISCOSITY <100 cps @ 25oC ODOR Mild ethanol-like
MELTING OR FREEZING POINT -20 oC
BOILING POINT Not known
VAPOR DENSITY (Air=1) Not known VAPOR PRESSURE (mm Hg) Not known
PERCENT VOLATILE (by weight) 20 SOLUBILITY IN WATER Soluble
SPECIFIC GRAVITY (Water=1) 0.91 @ 25oC
EVAPORATION RATE (Butyl Acetate=1) Not
known
*********************** III - FIRE AND EXPLOSION INFORMATION ***********************
FLASH POINT 116掳F AUTO IGNITION TEMPERATURE Not known
LOWER EXPLOSION LIMIT (%) Not applicable UPPER EXPLOSION LIMIT (%) Not applicable
ALCOHOL FOAM X CO2 X
EXTINGUISHING MEDIA FOAM
DRY CHEMICAL X WATER X OTHER
SPECIAL FIRE FIGHTING PROCEDURES:
Must wear NIOSH approved self-contained breathing apparatus and protective clothing.
Cool fire-exposed containers with water spray.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Products of combustion are toxic. Heated solvent vapor can travel to an ignition source
and flash back.
The information provided herein is compiled from internal reports and data from professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95318 Bardac 208M PAGE 2 OF 7
************************ IV - HEALTH EFFECTS INFORMATION ***************************
ROUTES OF ENTRY - SKIN CONTACT X EYE CONTACT X
X
INHALATION INGESTION
EFFECTS OF OVEREXPOSURE
Eye Contact: Direct contact can produce severe eye damage. Corrosive.
Skin Contact: Direct or prolonged contact can produce severe irritation. Corrosive.
Ingestion: Immediate burning pain in the mouth, throat, abdomen and severe swelling of
the larynx, skeletal muscle paralysis affecting the ability to breathe, circulatory
shock, convulsions. May be fatal.
Inhalation: Solvent vapors or mist of product can produce irritation of mucous
membranes. Exposure to ethyl alcohol concentrations of over 1,000 ppm may cause
headache, irritation of the eyes, nose and throat, and, if prolonged, drowsiness and
lassitude, loss of appetite and inability to concentrate.
OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS:
No effects indicated.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Flush eyes with large amounts of running water for at least 15 minutes. Hold
eyelids apart to ensure rinsing of the entire surface of the eye and lids with water.
Get immediate medical attention. If physician not available, flush for additional 15
minutes and then transport victim to medical care.
Skin: Wash with large amounts of running water, and soap if available, for 15 minutes.
Remove contaminated clothing and shoes. Get immediate medical attention. Wash
clothing and decontaminate shoes before reuse.
Ingestion: If swallowed, immediately give 3-4 glasses of milk (if unavailable, give
water). DO NOT induce vomiting. If vomiting occurs, give fluids again. Get immediate
medical attention. Have physician determine if patient's condition allows for
induction of vomiting or evacuation of the stomach. Do not give anything by mouth to a
convulsing or unconscious person.
Inhalation: Remove from area to fresh air. If not breathing, clear airway and start
artificial respiration. If victim is having trouble breathing, give supplemental
oxygen, if available. Get immediate medical attention.
NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. Measures against
circulatory shock, as well as measures to support breathing manually or mechanically
may be needed. Provide Oxygen, if individual is having difficulty breathing.
CHEMICALS LISTED AS CARCINOGEN BY:
NATIONAL TOXICOLOGY PROGRAM - No
- No
I.A.R.C. MONOGRAPHS
- No
OSHA
*************************** V - REACTIVITY INFORMATION *****************************
X
STABILITY: STABLE CONDITIONS TO AVOID
None known
UNSTABLE
95318 Bardac 208M PAGE 3 OF 7
********************** V - REACTIVITY INFORMATION (continued)*************
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition may produce toxic vapors/fumes of hydrogen chloride, amines and
other organic materials, and oxides of carbon and nitrogen.
HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID
WILL NOT X None known
MAY
OCCUR OCCUR
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
INCOMPATIBILITY (MATERIALS TO AVOID)
OTHER X Strong oxidizing or reducing agents.
WATER
************************ VI - SPILL AND DISPOSAL INFORMATION ***********************
STEPS TO BE TAKEN IN CASE OF MATERIAL SPILL OR RELEASE
DANGER! Corrosive and flammable material. Remove all sources of ignition and ground
all equipment before beginning cleanup. Wear appropriate protective equipment and
respiratory protection where mists or vapors of unknown concentrations may be generated
(self-contained breathing apparatus preferred).
Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid
and solid separately to containers for recovery or disposal. Keep spill out of sewers
and open bodies of water.
WASTE DISPOSAL METHODS
Dispose of in compliance with all Federal, state and local laws and regulations.
Incineration is the preferred method.
CONTAINER DISPOSAL
Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture
and dispose of in a sanitary landfill, or, if allowed by state and local authorities,
by burning. If burned, stay out of smoke.
*********************** VII - PERSONAL PROTECTION INFORMATION **********************
ENGINEERING CONTROLS
In processes where mists or vapors may be generated, proper ventilation must be
provided in accordance with good ventilation practices.
RESPIRATORY PROTECTION
In processes where mists or vapors may be generated, a NIOSH/MSHA jointly approved
respirator is advised in the absence of proper environmental controls.
PROTECTIVE GLOVES
Rubber or neoprene, to prevent skin contact.
EYE PROTECTION
Wear chemical splash goggles where there is a potential for eye contact. Use safety
glasses with side shields where there is no potential for eye contact.
OTHER PROTECTIVE EQUIPMENT
Eye wash; safety shower; protective clothing (long sleeves, coveralls or other, as
appropriate), to prevent skin contact.
95318 Bardac 208M PAGE 4 OF 7
*************************** VIII - STORAGE AND HANDLING ***************************
PRECAUTIONS FOR STORAGE AND HANDLING:
Store containers in compliance with the most recent NFPA Code (NFPA 30). Ground all
containers prior to pouring. Take appropriate measures to avoid exposure to high vapor
concentrations, which can occur when transferring material from container to container.
Keep container tightly closed when not in use. Do not contaminate drinking water, food
or feed by storage or disposal. Maximum storage temperature: 140oF.
Empty containers retain product residues and can be dangerous. Do not pressurize, cut
weld, braze, solder, drill, grind or expose such containers to heat or flame. They may
explode and cause injury. Follow all MSDS precautions in handling empty containers.
******************* IX - TOXICOLOGY & ECOTOXICITY INFORMATION ***********************
The toxicity and ecotoxicity information provided below is for this product, similar
product(s) and/or components of this product.
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
TOXICITY
ACUTE
For Bardac 208M:
- oral LD50 (rat): 366 mg/kg
For Bardac 205M (50% Actives mixture 鈥? Dialkyl(C8-10)dimethylammonium Chloride and
Alkyl(C12-16)dimethylbenzylammonium Chloride)
- dermal LD50 (rabbit): 645 mg/kg
- skin irritation (rabbit): Severe irritant
- eye irritation (rabbit): Extreme irritant
- skin corrosivity(rabbit 鈥? DOT): Corrosive
- skin sensitization (guinea pig - Buehler test): Not a skin sensitizer
For the Dialkyl(C8-10)dimethylammonium chloride:
- skin photosensitivity (guinea pig): Not a direct sensitizer or photosensitizer
GENOTOXICITY/MUTAGENICITY
For the Dialkyl(C8-10)dimethylammonium chloride:
- Ames assay (Salmonella sp.): Not mutagenic with or without metabolic activation.
- HGPRT assay (in vitro 鈥? CHO cells): Not clastogenic with or without metabolic
activation
- Micronucleus test (in vivo 鈥? rat): No evidence of chromosomal damage in the bone
marrow of rats treated at a dosage of 600 mg/kg
- not teratogenic in rats treated with 10 to 50 mg/kg on days 6 to 15 gestation (50%
active)
For Alkyldimethyl(C12-16)benzylammonium chloride:
- unscheduled DNA synthesis (in vitro 鈥? rat hepatocytes): Not mutagenic with or without
metabolic activation.
- HGPRT (in vitro 鈥? CHO cells): Not mutagenic with or without metabolic activation. (2
tests)
REPRODUCTIVE/DEVELOPMENTAL
For Alkyldimethyl(C12-16)benzylammonium chloride:
- developmental (rat 鈥? oral): NOAEL 鈥? 10 mg/kg/day for both maternal and neonatal. No
evidence of developmental toxicity effects was observed at exposure doses ranging
from 10-100 mg/kg/day administered from day 6 through 18 of gestation. Clear signs
of maternal toxicity were observed at the high-dose level of 100 mg/kg/day.
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95318 Bardac 208M PAGE 5 OF 7
************* IX - TOXICOLOGY & ECOTOXICITY INFORMATION (continued)******
- developmental (rabbit - oral): NOAEL 鈥? 3 mg/kg/day for both maternal and neonatal.
No evidence of developmental toxicity effects was observed at exposure doses ranging
from 1 to 9 mg/kg/day administered from day 6 through 18 of gestation. Clear signs
of maternal toxicity were observed at the high-dose level of 9 mg/kg/day.
- reproductive/developmental (rat 鈥? two generation feeding): NOAEL 鈥? 1000 ppm.
Neonatal and maternal adverse effects were observed in animals dosed at 2000 ppm.
ECOTOXICITY
AQUATIC
For Alkyldimethylbenzylammonium chloride:
- LC 50 (bluegill sunfish 鈥? 96 hour, static): 0.52 mg/l
- LC 50 (rainbow trout 鈥? 96 hour, static): 0.93 mg/l
- LC 50 (sheepshead minnow 鈥? 96 hour, static): 0.86 mg/l
- EC 50 (Daphnia magna 鈥? 48 hour, static): 0.058 mg/l
******************* X - MISCELLANEOUS AND REGULATORY INFORMATION ********************
FEDERAL REGULATIONS:
TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS:
The components in this product are all listed on the U.S. TSCA 8(b) Inventory.
TSCA Section 12(b) Export Notification
Components present in this product which, if exported, could require either annual
or one-time reporting under this regulation are as follows:
Typical Maximum
Chemical Name CAS Number Concentration
EXEMPT 鈥? U.S. EPA FIFRA Registered Product
US EPA Regulation on Pesticides:
This product is an EPA FIFRA registered pesticide (EPA Registration No. 6836-67).
This product can be used commercially only in the EPA registered application(s)
noted on the product label.
US FDA Regulations on Food Contact:
This product is regulated under the following section(s) of the Code of Federal
Regulations (CFR) when used in permitted food contact applications:
21 CFR 177.1010
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of
1980 requires notification of the National Response Center
(Telephone 800-424-8802) in the event of a release of quantities of the
following hazardous materials contained in this product, if the release is
equal to or greater than the Reportable Quantities (RQs) listed in
40 CFR 302.4: RQ is 500 lbs
Typical Maximum
Chemical Name CAS Number Concentration
Methanol 67-56-1 0.5%
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95318 Bardac 208M PAGE 6 OF 7
******************* X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ********
FEDERAL REGULATIONS (continued):
SARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of
1986) - This act requires emergency planning, including agency notification, for
possible release of the following components of this material, based upon the
Threshhold Planning Quantities (TPQs) and release Reportable Quantities (RQs)
listed for the Components in 40 CFR 355:
Typical Maximum
Chemical Name CAS Number Concentration
None known
SARA Title III Sections 311/312 - This act requires reporting under the Community
Right-to-Know provisions due to the inclusion of the following components of this
material in one or more of the five hazard categories listed in 40 CFR 370:
Hazard *)
Chemical Name CAS Number Categories
N,N-dialkyl-N,N-dimethylammonium Chloride 68424-95-3 A
N-Alkyl-N,N-dimethyl-N-benzylammonium Chloride 68424-85-1 A
Ethanol 64-17-5 F
*) The five hazard categories are as follows: F=FIRE HAZARD; S= SUDDEN RELEASE OF
PRESSURE; R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC)
HEALTH HAZARD
SARA Title III Section 313 - This act requires submission of annual reports off the
releases of the following components of this material if the threshold reporting
quantities as listed in 40 CFR 372, are met or exceeded:
Typical Maximum
Chemical Name CAS Number Concentration
None known
STATE RIGHT-TO-KNOW REGULATIONS:
CALIFORNIA PROPOSITION 65 - Components present in this material which the State of
California has found to cause cancer, birth defects or other reproductive harm
are as follows:
Typical Maximum
Chemical Name CAS Number Concentration
Acetaldehyde 75-07-0 1 ppm
Benzene 71-43-2 100 ppm
Benzyl Chloride 100-44-7 100 ppm
N-Nitrosodimethylamine 62-75-9 500 ppb
Propylene Oxide 75-56-9 10 ppm
Toluene 108-88-3 100 ppm
MASSACHUSETTS Right-to-Know - The following components of this material are included
in the Massachusetts Substance List and are present at or above reportable
levels:
Typical Maximum
Chemical Name CAS Number Concentration
Ethanol 64-17-5 10 %
Benzyl Chloride 100-44-7 100 ppm
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE 800-424-9300 (Chemtrec)
Lonza Inc. 90 Boroline Road Allendale NJ 07401 800-777-1875 (9am - 5pm) 309-697-7200 (After 5pm)
95318 Bardac 208M PAGE 7 OF 7
******************* X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ********
MICHIGAN Critical Materials - The following components of this material are included
in the Michigan Critical Materials List:
Chemical Name CAS Number
None known
STATE RIGHT-TO-KNOW REGULATIONS:
NEW JERSEY Right-to-Know - The following components of this material are included in
the New Jersey Hazardous Substance List and are present at or above reportable
levels:
Typical Maximum
Chemical Name CAS Number Concentration
N,N-dialkyl-N,N-dimethylammonium Chloride 68424-95-3 48%
N-Alkyl-N,N-dimethyl-N-benzylammonium Chloride 68424-85-1 32%
Ethanol 64-17-5 10%
PENNSYLVANIA Right-to-Know - The following components of this material are included
in the Pennsylvania Hazardous Substance List and are present at or above
reportable levels:
Typical Maximum
Chemical Name CAS Number Concentration
Ethanol 64-17-5 10%
The information provided herein is compiled form internal reports and data form professional publications. IT IS FURNISHED WITHOUT WARRANTY OF ANY
KIND, EXPRESSED OR IMPLIED. It is intended to assist in evaluating the suitability and proper use of the material in manufacturing and in the development and
implementation of safety precautions and procedures.
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