MATERIAL SAFETY DATA SHEET
MSDS NO. 10166 Trade Name: CLEAN UP鈩? Revision Date: 09/09/2003
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: CLEAN UP鈩?
Chemical Family: Mixture
Product Use: Detergent.
Emergency Telephone (24 hr.): 281-561-1600
Supplied by: M-I L.L.C.
A Smith/Schlumberger Company
P.O. Box 42842
Houston, TX 77242
Telephone Number: 281-561-1511
Contact Person: Catherine Miller, Product Safety
Revision Number: 3
HMIS Rating
Health: 2 Flammability: 1 Physical Hazard: 0 PPE: E
HMIS Key: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard. *Chronic effects - See Section 11. See
Section 8 for Personal Protective Equipment recommendations.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS NO: Wt. % Ingredient Comments:
Water 7732-18-5 60 - 100 No comments.
Diethanolamine 111-42-2 0-5 No comments.
Surfactant 5 - 10 No comments.
Surfactant 5 - 15 No comments.
Ethoxylated alcohols 5 - 10 No comments.
Glycol ether 5 - 10 No comments.
3. HAZARDS IDENTIFICATION
Emergency Overview: Warning! May cause severe eye irritation. May cause skin and respiratory tract
irritation. May be harmful if absorbed through skin.
Canadian WHMIS:
UN PIN No: Not regulated WHMIS Class: D2B
Physical Liquid Odor: Mild Color: Colorless
State:
Potential Health Effects:
Acute Effects
Eye Contact: May cause severe eye irritation.
Skin Contact: May be irritating to the skin. May be harmful if absorbed through skin.
Inhalation: Vapors or mists may be irritating to the respiratory tract. Overexposure to
vapors and mists which may be released at high temperatures may cause central
nervous system (CNS) effects and respiratory tract irritation.
MATERIAL SAFETY DATA SHEET
Trade Name: CLEAN UP鈩?
MSDS NO. 10166 Revision Date: 09/09/2003 Page 2/6
Ingestion: May cause gastric distress, nausea and vomiting if ingested.
Acute Effects Note: This product may release ammonia or amines when heated or exposed to high pH. Ammonia is
a severe eye, skin and respiratory irritant. Ammonia has a very strong odor and can be detected at levels as low as 5
ppm. Many amines are also eye, skin and respiratory irritants.
Carcinogenicity & Chronic See Section 11 - Toxicological Information.
Effects:
Routes of Exposure: Eyes. Dermal (skin) contact. Dermal (skin) absorption. Inhalation.
Target Organs: Eyes. Skin. Respiratory System. Central Nervous System (CNS). Kidney. Liver.
Medical Conditions Aggravated Skin. Respiratory. Central Nervous System (CNS). Kidney. Liver.
By Over Exposure:
4. FIRST AID MEASURES
Eye Contact: Promptly wash eyes with lots of water while lifting eye lids. Continue to rinse for at
least 15 minutes. Get medical attention if any discomfort continues.
Skin Contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and
launder before reuse. Get medical attention if any discomfort continues.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Ingestion: Dilute with 2 - 3 glasses of water or milk, if conscious. Never give anything by
mouth to an unconscious person. If signs of irritation or toxicity occur seek medical
attention.
General Notes: Persons seeking medical attention should carry a copy of this MSDS with them.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point: F (C): >210F (98.9C)
Flash Point Method: PMCC
Flammable Limits in Air - Lower (%): Not Determined
Flammable Limits in Air - Upper (%): Not Determined
Autoignition Temperature: F(C) Not Determined
Flammability Class: IIIB
Other Flammable Properties: Not determined.
Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Do not enter fire area without proper personal protective equipment,
including NIOSH/MSHA approved self-contained breathing apparatus. Evacuate area and fight fire from a safe
distance. Water spray may be used to keep fire-exposed containers cool. Keep water run off out of sewers and
waterways.
Hazardous Combustion Products: Oxides of: Sulfur. Carbon. Nitrogen. Ammonia or amines.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Use personal protective equipment identified in Section 8.
Spill Procedures: Evacuate surrounding area, if necessary. Keep personnel removed and upwind of
spill. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.
Shut off leak if it can be done safely. Spilled product is very slippery. Contain
spilled material. Absorb in vermiculite, dry sand or earth. Place into containers for
disposal.
MATERIAL SAFETY DATA SHEET
Trade Name: CLEAN UP鈩?
MSDS NO. 10166 Revision Date: 09/09/2003 Page 3/6
Environmental Precautions: Do not allow to enter sewer or surface and subsurface waters. Waste must be
disposed of in accordance with federal, state and local laws. In the U.S., for
products with reportable quanitity (RQ) components - if the RQ is exceeded, report
to National Spill Response Office at 1 800 424 8802.
7. HANDLING AND STORAGE
Handling: Put on appropriate personal protective equipment. Avoid contact with skin and
eyes. Avoid breathing vapors or spray mists. Spilled product is very slippery. Use
only in a well ventilated area. Wash thoroughly after handling.
Storage: Store in dry, well-ventilated area. Keep container closed. Keep away from heat,
sparks and flames. Store away from incompatibles. Follow safe warehousing
practices regarding palletizing, banding, shrink-wrapping and/or stacking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Ingredient CAS NO: Wt. % ACGIH TLV OSHA PEL Other Notes
TWA TWA
Water 7732-18-5 60 - 100 Not Listed Not Listed None
2 mg/m3
Diethanolamine 111-42-2 0-5 3 ppm (skin)
Surfactant 5 - 10 Not Listed Not Listed (6)
Surfactant 5 - 15 Not Listed Not Listed None
Ethoxylated alcohols 5 - 10 Not Listed Not Listed None
Glycol ether 5 - 10 200 ppm 100 ppm (skin)
Notes
(6) Ammonia or amines may be released when this component is heated or exposed to high pH. The recommended
exposure limits for ammonia are ACGIH TLV 25 ppm and OSHA PEL 50 ppm. No general recommended exposure
limit is available for amines. A NIOSH/MSHA approved respirator with ammonia/methylamine cartridges should be
used to protect against ammonia or amine inhalation exposure.
Engineering Controls: Local exhaust ventilation as necessary to maintain exposures to within applicable limits.
Personal Protection Equipment
Eye/Face Protection: Wear chemical safety goggles.
Skin Protection: Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear
chemical resistant gloves such as nitrile or neoprene.
Respiratory Protection: If exposed to particulates/aerosols:
Use at least a NIOSH-approved N95 half-mask disposable particulate respirator.
In work environments containing oil mist/aerosol use at least a NIOSH-approved
P95 half-mask disposable or reuseable particulate respirator.
If exposed to organic vapors:
Use a NIOSH/MSHA-approved organic vapor respirator. CCROV: CCR with
organic vapor cartridge.
Refer to Exposure Limits table (Section 8) for component specific respiratory
protection recommendations.
General Hygiene Work clothes should be washed separately at the end of each work day.
Considerations: Disposable clothing should be discarded, if contaminated with product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Color: Colorless
MATERIAL SAFETY DATA SHEET
Trade Name: CLEAN UP鈩?
MSDS NO. 10166 Revision Date: 09/09/2003 Page 4/6
Odor: Mild
Physical State: Liquid
pH: 8.3
Vapor Pressure: Not determined
Vapor Density (Air=1): Not determined
Flash Point: F (C): >210F (98.9C)
Boiling Point: Not determined
Melting/Freezing Point: Not determined
Solubility (Water): Soluble.
Specific Gravity (H2O = 1): 1.008 at 68F (20C)
Evaporation Rate: Not deterrmined
Odor Threshold(s): Not determined
10. STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: Keep away from heat, sparks and flame.
Materials to Avoid: Oxidizers. Alkalies.
Hazardous Decomposition For thermal decomposition products, see Section 5.
Products:
Hazardous Polymerization: Will not occur
11. TOXICOLOGICAL INFORMATION
Component Toxicological Data
Ingredient CAS NO: Acute Data
Diethanolamine 111-42-2 LD50 0.45 - 1.85 ml/kg (rat); LD50 Dermal: 5.05 -
13.6 ml/kg (24H occluded)
Glycol ether Oral LD50 5.4 g/kg (rat); Dermal LD50 5.1 g/kg
(rabbit); Inhalation LC50 >400 ppm/7H (rat)
Ingredient Component Toxicological Summary
Diethanolamine There are reports that ingestion of diethanolamine (DEA) produced nervous system
injury in dogs and rats. Heart and salivary gland lesions have also been observed in
mice treated with DEA cutaneously and in drinking water. Rats given high doses of DEA
developed anemia and testicular lesions. An increased incidence of some skeletal
variations suggestive of a slight developmental delay was seen only in the fetuses of rats
given 1500 mg/kg/day cutaneously which also caused significant maternal toxicity.
However, no fetal malformations were observed in either rats or rabbits similarly treated.
Preliminary findings from the National Toxicology
Program (NTP) suggest an increased incidence of liver tumors in both sexes of mice
and an increased incidence of kidney tumors in male mice dermally exposed for their
lifetime to DEA. The significance of these findings and their relevance to humans are not
clear as DEA was not genotoxic (neither mutagenic (causing changes in genes) nor
clastogenic (causing breakage of chromosomes)), and did not induce tumors in rats or in
transgenic mice similarly treated. Additional research which is designed to provide a
better understanding of the significance of these observations to humans, if any, is
underway. (Vendor MSDS)
Product Toxicological Information:
No toxicological data is available for this product.
12. ECOLOGICAL INFORMATION
MATERIAL SAFETY DATA SHEET
Trade Name: CLEAN UP鈩?
MSDS NO. 10166 Revision Date: 09/09/2003 Page 5/6
Ingredient CAS NO: Data
Diethanolamine 111-42-2 LC50 96H 4710 mg/l (fathead minnow); LC50 24H:
800 mg/l (goldfish); EC50 5M: 73 mg/l
(Photobacterium)
Glycol ether LC50 96H: 10,000 mg/l (fathead minnow); EC50
48H: 5000 mg/l (Daphnia)
Product Ecotoxicity Data: Contact M-I Environmental Affairs Department for available product ecotoxicity
data.
Biodegration: Not determined
Bioaccumulation: Not determined
Octanol/Water Partition Not determined
Coefficient:
13. DISPOSAL CONSIDERATIONS
Waste Classification: Not determined.
Waste Management: Under U.S. Environmental Protection Agency (EPA) Resource Conservation and
Recovery Act ( RCRA), it is the responsibility of the user to determine at the time of
disposal, whether the product meets RCRA criteria for the hazardous waste. This
is because product uses, transformations, mixtures, processes, etc., may render
the resulting materials hazardous. Empty containers retain residues. All labeled
precautions must be observed.
Disposal Method: Recover and reclaim or recycle, if practical. Should this product become a waste,
dispose of in a permitted industrial landfill. Ensure that the containers are empty
by the RCRA criteria prior to disposal in a permitted industrial landfill.
14. TRANSPORT INFORMATION
U.S. DOT
Shipping Description: Not regulated for transportation by DOT, TDG, IMDG, ICAO/IATA.
Product RQ: 588 gal (Diethanolamine)
TDG (Canada):
Shipping Description: Not regulated
UN PIN No: Not regulated
IMDG:
Shipping Description: Not regulated
ICAO/IATA:
Shipping Description: Not regulated
15. REGULATORY INFORMATION
U.S. Federal and State Regulations
SARA 311/312:
SARA 311/312 Hazard Catagories: Immediate (acute) health hazard.
MATERIAL SAFETY DATA SHEET
Trade Name: CLEAN UP鈩?
MSDS NO. 10166 Revision Date: 09/09/2003 Page 6/6
Ingredient SARA 313 CERCLA SARA 302 CA 65 CA 65 CA 65 CA 65
RQ / TPQs Cancer Dev. Tox. Repro. F Repro. M
Water Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Diethanolamine Listed, 100 lbs Not Listed Not Listed Not Listed Not Listed Not Listed
1.0% (45.4 kg)
Surfactant Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Surfactant Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Ethoxylated alcohols Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Glycol ether Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
State Comments: Proposition 65: This product is not known to contain chemicals considered by the State of
California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer and/or reproductive toxicity at
levels that are expected to pose a significant risk under anticipated use conditions.
International Chemical Inventories
Australia AICS - Components are listed or exempt from listing.
Canada DSL - Components are listed or exempt from listing.
European Union EINECS - Contains a component(s) that is not listed.
U.S. TSCA - Components are listed or exempt from listing.
U.S. TSCA - No components are subject to TSCA 12(b) export notification requirements.
Canadian WHMIS:
Controlled Products Regulations Statement: This product has been classified in accordance with the hazard criteria of
the CPR and the MSDS contains all the information required by the CPR.
WHMIS Class: D2B
16. OTHER INFORMATION
The following sections have been revised: All sections.
Disclaimer:
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are
obtained from sources beyond our direct supervision. We can not make any assertions as to its reliability or completeness; therefore, user may
rely on it only at user麓s risk. We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or
control the conditions under which this information and product may be used, we make no guartantee that the precautions we have suggested will
be adequate for all individuals and/or situations. It is the obligation of each user of this product to comply with the requirements of all applicable
laws regarding use and disposal of this product. Additional information will be furnished upon request to assist the user; however, no warranty,
either expressed or implied, nor liability of any nature with respect to this product or to the data herein is made or incurred hereunder.
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