MATERIAL SAFETY DATA SHEET
10726 HRP* 06/01/2004
MSDS NO. Trade Name: Revision Date:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HRP*
Trade Name:
Mixture
Chemical Family:
Oil well drilling fluid additive. Viscosifier
Product Use:
281-561-1600
Emergency Telephone (24 hr.):
M-I L.L.C.
Supplied by:
P.O. Box 42842
Houston, TX 77242
www.miswaco.com
281-561-1511
Telephone Number:
Catherine Miller, Product Safety Specialist
Contact Person:
4
Revision Number:
HMIS Rating
Health: 2 1 0 PPE: J
Flammability: Physical Hazard:
HMIS Key: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard. *Chronic effects - See Section 11. See
Section 8 for Personal Protective Equipment recommendations.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS No. Wt. % Comments:
Triethylene glycol monobutyl 143-22-6 30 - 60 No comments.
ether
Propylene carbonate 108-32-7 1-5 No comments.
Polyamide 30 - 60 No comments.
3. HAZARDS IDENTIFICATION
Warning! May cause severe eye irritation. Prolonged contact may cause burns. May
Emergency Overview:
cause skin irritation.
Canadian Classification:
Not regulated D2B
UN PIN No: WHMIS Class:
L铆quid Mild Amber
Physical Odor: Color:
State:
Potential Health Effects:
Acute Effects
May cause severe eye irritation. Prolonged contact may damage eye.
Eye Contact:
May be irritating to the skin.
Skin Contact:
Not expected to be an inhalation hazard under anticipated workplace exposures.
Inhalation:
Overexposure to vapors and mists which may be released at high temperatures may
cause central nervous system (CNS) effects and respiratory tract irritation.
May cause gastric distress, nausea and vomiting if ingested.
Ingestion:
MATERIAL SAFETY DATA SHEET
Trade Name: HRP*
MSDS NO. 10726 Revision Date: 06/01/2004 Page 2/6
Carcinogenicity & Chronic IARC: Not Listed; OSHA: Not regulated; NTP: Not listed.
Effects:
Routes of Exposure: Eyes. Dermal (skin) contact. Inhalation.
Target Organs/Medical Eyes. Skin. Respiratory System. Central Nervous System (CNS).
Conditions Aggravated by
Overexposure:
4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get
immediate medical attention.
Skin Contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and
launder before reuse. Get medical attention if any discomfort continues.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Ingestion: Dilute with 2 - 3 glasses of water or milk, if conscious. Never give anything by mouth
to an unconscious person. If signs of irritation or toxicity occur seek medical
attention.
General Notes: Persons seeking medical attention should carry a copy of this MSDS with them.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point: F (C): >200F (>93C)
Flash Point Method: PMCC
Flammable Limits in Air - Lower (%): ND
Flammable Limits in Air - Upper (%): ND
Autoignition Temperature: F(C) ND
Flammability Class: IIIB
Other Flammable Properties: ND
Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Do not enter fire area without proper personal protective equipment, including
NIOSH/MSHA approved self-contained breathing apparatus. Evacuate area and fight fire from a safe distance. Water
spray may be used to keep fire-exposed containers cool. Keep water run off out of sewers and waterways.
Hazardous Combustion Products: Oxides of carbon and nitrogen.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Use personal protective equipment identified in Section 8.
Spill Procedures: Evacuate surrounding area, if necessary. Keep personnel removed and upwind of
spill. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Shut
off leak if it can be done safely. Contain spilled material. Absorb in vermiculite, dry
sand or earth. Place into containers for disposal.
Environmental Precautions: Do not allow to enter sewer or surface and subsurface waters. Waste must be
disposed of in accordance with federal, state and local laws. In the U.S., for products
with reportable quanitity (RQ) components - if the RQ is exceeded, report to National
Spill Response Office at 1 800 424 8802.
MATERIAL SAFETY DATA SHEET
Trade Name: HRP*
MSDS NO. 10726 Revision Date: 06/01/2004 Page 3/6
7. HANDLING AND STORAGE
Handling: Put on appropriate personal protective equipment. Avoid contact with skin and eyes.
Avoid breathing vapors or spray mists. Use only in a well ventilated area. Wash
thoroughly after handling.
Storage: Store in dry, well-ventilated area. Keep container closed. Keep away from heat,
sparks and flames. Store away from incompatibles. Follow safe warehousing
practices regarding palletizing, banding, shrink-wrapping and/or stacking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits (TLV & PEL - 8H TWA):
Ingredient CAS No. Wt. % ACGIH TLV OSHA PEL Other Notes
Triethylene glycol monobutyl 143-22-6 30 - 60 NA NA NA None
ether
Propylene carbonate 108-32-7 1-5 NA NA NA None
Polyamide 30 - 60 NA NA NA None
Engineering Controls: Local exhaust ventilation as necessary to maintain exposures to within applicable limits.
Personal Protection Equipment
Eye/Face Protection: Wear chemical safety goggles.
Skin Protection: Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear
chemical resistant gloves such as: Butyl rubber.
Respiratory Protection: If exposed to particulates/aerosols:
Use at least a NIOSH-approved N95 half-mask disposable particulate respirator. In
work environments containing oil mist/aerosol use at least a NIOSH-approved P95
half-mask disposable or reuseable particulate respirator.
If exposed to organic vapors:
Use a NIOSH/MSHA-approved organic vapor respirator. CCROV: CCR with organic
vapor cartridge.
A NIOSH/MSHA approved respirator with ammonia/methylamine cartridges should
be used to protect against ammonia or amine inhalation exposure.
Refer to Exposure Limits table (Section 8) for component specific respiratory
protection recommendations.
General Hygiene Considerations: Work clothes should be washed separately at the end of each work day. Disposable
clothing should be discarded, if contaminated with product.
"Safe Handling Guide for Oil-Base and Synthetic-Base Fluid Systems" pamphlet is
available from M-I's Occupational Health Department.
9. PHYSICAL AND CHEMICAL PROPERTIES
Color: Amber
Odor: Mild
Physical State: L铆quid
pH: 8 - 10 (1% solution)
Specific Gravity (H2O = 1): 0.99 - 1.01 g/cc
Solubility (Water): Soluble.
Flash Point: F (C): >200F (>93C)
Melting/Freezing Point: ND
Boiling Point: ND
Vapor Pressure: ND
Vapor Density (Air=1): ND
MATERIAL SAFETY DATA SHEET
Trade Name: HRP*
MSDS NO. 10726 Revision Date: 06/01/2004 Page 4/6
Evaporation Rate: ND
Odor Threshold(s): ND
10. STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: Keep away from heat, sparks and flame.
Materials to Avoid: Oxidizers. Acids. Alkalies. Aluminum. Galvanized metals. Neoprene. Nitrile.
Natural rubber. Viton.
Hazardous Decomposition None known
Products:
Hazardous Polymerization: Will not occur
11. TOXICOLOGICAL INFORMATION
Component Toxicological Data: Any adverse component toxicological effects are listed below. If no effects are listed,
no such data were found.
Ingredient CAS No. Acute Data
Triethylene glycol monobutyl ether 143-22-6 Oral LD50: 5300 mg/kg (rat); Dermal LD50: 3540 ul/kg
(rabbit); Inhalation LC50: >200 mg/l/1H (rat)
Propylene carbonate 108-32-7 Oral LD50: 29,100 ul/kg (rat); Dermal LD50: >20 ml/kg
(rabbit)
Product Toxicological Information:
No toxicological data is available for this product.
12. ECOLOGICAL INFORMATION
Ingredient CAS No. Data
Triethylene glycol monobutyl ether 143-22-6 LC50 48H: 2990 - 5520 mg/l (Daphnia); EC50 48H: 4300 -
5200 mg/l (Daphnia); NOEC 96H: 1400 mg/l (fathead
minnow); LC50 96H 2400 - 5000 mg/l (fathead minnow)
Propylene carbonate 108-32-7 LC50 96H: 5,300 mg/l (Leuciscus idus); EC50 48H: >500
mg/l (Daphnia magna); EC50 72H: >500 mg/l
(Scenedesmus subspicatus)
Product Ecotoxicity Data: Contact M-I Environmental Affairs Department for available product ecotoxicity data.
Biodegration: ND
Bioaccumulation: ND
Octanol/Water Partition ND
Coefficient:
13. DISPOSAL CONSIDERATIONS
Waste Classification: ND
Waste Management: Under U.S. Environmental Protection Agency (EPA) Resource Conservation and
Recovery Act ( RCRA), it is the responsibility of the user to determine at the time of
disposal, whether the product meets RCRA criteria for the hazardous waste. This is
because product uses, transformations, mixtures, processes, etc., may render the
resulting materials hazardous. Empty containers retain residues. All labeled
precautions must be observed.
MATERIAL SAFETY DATA SHEET
Trade Name: HRP*
MSDS NO. 10726 Revision Date: 06/01/2004 Page 5/6
Disposal Method: Recover and reclaim or recycle, if practical. Should this product become a waste,
dispose of in a permitted industrial landfill. Ensure that the containers are empty by
the RCRA criteria prior to disposal in a permitted industrial landfill.
14. TRANSPORT INFORMATION
U.S. DOT Shipping Description: Not regulated for transportation by DOT, TDG, IMDG,
ICAO/IATA.
Canada TDG Shipping Description: Not regulated
UN PIN No: Not regulated
IMDG Shipping Description: Not regulated
ICAO/IATA Shipping Description: Not regulated
15. REGULATORY INFORMATION
U.S. Federal and State Regulations
SARA 311/312 Hazard Catagories:Immediate (acute) health hazard.
SARA 302/304, 313; CERCLA RQ, Note: If no components are listed below, this product is not subject to the referenced
California Proposition 65: SARA and CERCLA regulations and is not known to contain a Proposition 65 listed
chemical at a level that is expected to pose a significant risk under anticipated use
conditions.
Ingredient SARA 302 SARA 313 CERCLA CA 65 CA 65 CA 65 CA 65
/ TPQs RQ Cancer Dev. Tox. Repro. F Repro. M
Triethylene glycol monobutyl --- 1.0% --- --- --- --- ---
ether
International Chemical Inventories
Australia AICS - Contains a component(s) that is not listed.
Canada DSL - Components are listed or exempt from listing.
China Inventory - Contains a component that is not listed.
European Union EINECS - Contains a component(s) that is not listed.
Japan METI ENCS - Contains a component that is not listed.
Korea TCCL ECL - Contains a component that is not listed.
Philippine PICCS - Contains a component that is not listed.
U.S. TSCA - Components are listed or exempt from listing.
U.S. TSCA - No components are subject to TSCA 12(b) export notification requirements.
Canadian Classification:
Controlled Products Regulations Statement: This product has been classified in accordance with the hazard criteria of the
CPR and the MSDS contains all the information required by the CPR.
WHMIS Class: D2B
16. OTHER INFORMATION
The following sections have been revised: All sections.
NA - Not Applicable, ND - Not Determined.
*A mark of M-I L.L.C.
MATERIAL SAFETY DATA SHEET
Trade Name: HRP*
MSDS NO. 10726 Revision Date: 06/01/2004 Page 6/6
Disclaimer:
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We can not make any assertions as to its reliability or completeness; therefore, user may rely on it only at user麓s
risk. We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which
this information and product may be used, we make no guartantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
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