Munkadur® Classic (Hardener � 1060) Safety Data Sheet acc. to 2001/58/EC
1. Identification of the Substance/Preparation and of the Company
Identification of the substance or preparation:
-
®
- Commercial product name: Munkadur 1060
- Manufacturer/Distributor: Munk + Schmitz Oberflächentechnik GmbH & Co. KG
Telephone no. Poller Kirchweg 92-104, 51105 Köln / Germany Tel.: ..49 (0)221/83908-0
- Further information from: Dept: BT � Quality Control / Laboratory
2 Composition / Information on Ingredients
- Chemical characterization: Epoxy hardener. Compound comprising following ingredients with non-hazardous
admixtures.
- Hazardous ingredients: CAS-No. Identification % ld. letter R-
phrases_ _
101-577-9 4.4�-methylene dianiline 17-21 T 45-20/21/22
26761-45-5 glycidyl ester of the 4-8 Xi 43
neodecane acid
100-51-6 benzyl alcohol 4-8 Xn 20/22
(as reactive diluent)
25068-38-6 epoxy resins MG <700 <4 Xi 36/38-43
69-72-7 salicylic acid <4 Xn 22
3 Hazards Identification:
- Critical hazards to man: T toxic
- Safety risks: R 45 May cause cancer
R2 20/21/22 Harmfull by inhalation, in contact with skin and if swallowed.
R 43 May cause sensitization by skin contact
Contains expoxy-containing components. Observe data of manufacturer.
The classification is based on the safety data provided by the manufacturer of the crude resin in accordance with
the EC Safety Data Sheet.
4 First Aid Measures
- General information: Symptoms of intoxication may become evident after several hours only. Therefore
patient should remain under medial observation for at least 48 hours after the
accident
has occurred.
- Inhalation: Move the patient at once to fresh air and seek medical advice.
In case of unconsciousness turn patient’s body and head to stable side position.
- Skin contamination: Wash affected area with soap and water and flush with plenty of water.
- Eye contamination: Hold eyelids apart and immediately flush eyes with plenty of water.
Seek medical advice.
- Ingestion: If swallowed, call a physican immediately. Flush mouth with water and let patient
drink plenty of water. Do not induce vomiting.
Munk + Schmitz Telefon (0221) 8 39 08-0 Revision: 22.03.04
Certified to Oberflächentechnik GmbH & Co. KG Fax (0221) 8 39 08-27
DIN EN ISO 9001 Poller Kirchweg 92-104, 51105 Köln E-mail info@munk-schmitz.de Page 1 of 5
Munkadur® Classic (Hardener � 1060) Safety Data Sheet acc. to 2001/58/EC
5 Fire-fighting Measures
- Suitable extinguishing
media: CO2, extinguishing powder or water spray. In case of large fire use water spray
or alcohol foam.
- Unsuitable extinghuishing
media: Full water jet
- Special hazards: May generate toxic gases in case of fire or when exposed to high temperatures.
- Special protective
equipment: Firefighters should wear self-contained respirators.
- Other information: Use water spray to cool fire-exposed containers and to desperse vapors.
Residues from fire and contaminated water to be disposed of in accordance with
federal, state and local regulations.
6 Accidental Release Measures
- Personal precautions: Wear protective clothing. Keep away unprotected persons.
- Protective clothing: Gloves made from
chloroprene rubber (CR) minimum thickness: 0.700 mm
natural rubber (NR) minimum thickness: 0.792 mm
nitrille rubber, e.g. (NBR) minimum thickness: 0.420 mm
polyblend made from PE /EVAL minimum thickness: 0.070 mm
PVC mininum thickness: 1,305 mm
- Environmental precautions: Avoid penetration into sewerage, pits and cellars.
- Methods for cleaning-up: Admix with liquid absorbent (sand, sileceous earth, acid neutralizer,
universal neutralizer) and dispose of in accordance with
regulations.
Dispose of contaminated material as waste in acc. w. pt. 13.
Ensure adequate ventilation.
7 Handling and Storage
- Handling:
- Precautions for safe handling: Ensure adequate ventilation/exhausting at the workplace.
Handle and open container prudently.
- Precautions against fire and explosion: Provide for breathing units
Storage:
-
- Conditions of storage rooms and vessels: Do not store outdoors.
- Advice of storage of imcompatible materials: Not required.
- Further information for storage: Keep in tightly closed containers.
- VbF class: Not applicable.
Munk + Schmitz Telefon (0221) 8 39 08-0 Revision: 22.03.04
Certified to Oberflächentechnik GmbH & Co. KG Fax (0221) 8 39 08-27
DIN EN ISO 9001 Poller Kirchweg 92-104, 51105 Köln E-mail info@munk-schmitz.de Page 2 of 5
Munkadur® Classic (Hardener � 1060) Safety Data Sheet acc. to 2001/58/EC
8 Exposure Controls / Personal Protection
- Exposure limits: CAS-No. identification of substance %, species value unit:
101-77-9 4,4´-Methylendianilin TRK 0.1 mg/cbm
Additional remarks: Because of its content of free 4,4´-Methylendianilin this product
has been ranked carcinogen in animal experiments.
Personal protection equipment:
-
- Respiratory protection: For temporary exposure or exposure with low concentrations use respirator;
for intensive or prolonged exposure use self-contained breathing apparatus.
- Hand protection: Protective gloves
- Eye protection: Tight safety glasses
- Skin protection: Protective clothing
- General Protection and
Hygiene Measures: Keep away from food, beverages and feed.
Promptly remove clothing that becomes contaminated.
Wash hands each time before a break and at the end of a working day.
Avoid eye and skin contact.
9 Physical and Chemical Properties
- Physical form: Viscous
- Color: dark brown
- Odor: typical for the species
- Change in physical state: Value/Range Unit Method
- Boiling point/boiling range: > 205 °
C
- Flame point: > 152 °
C
Ignition temperature: 435 °
C
Steam pressure: at 20 °
C < 0,004 Pa
- Density: at 20 °
C. 1,82 g/ml
- Solubility in water/Mixability with water: at 20 °C practically not mixable
- Viscosity (dynamic): at 25 °
C > 6500 mPas
Stability and Reactivity
10
- Thermal decomposition/conditions to avoid: starts at 200 to 250 °
C
- Hazardous reaction: High exothermal reaction with acids and strong oxidising agents.
- Hazardous decomposition products: Hazardous decomposition products unknown.
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Munk + Schmitz Telefon (0221) 8 39 08-0 Revision: 22.03.04
Certified to Oberflächentechnik GmbH & Co. KG Fax (0221) 8 39 08-27
DIN EN ISO 9001 Poller Kirchweg 92-104, 51105 Köln E-mail info@munk-schmitz.de Page 3 of 5
Munkadur® Classic (Hardener � 1060) Safety Data Sheet acc. to 2001/58/EC
11 Toxicological Information
- Acute toxicity:
- Acute oral / dermal / inhalation toxicity (LD/LC 50)
Component Type Value Species
- 4.4�-methylene dianiline oral > 347 mg/kg rat
dermal > 1000 mg/kg rabbit
inhalative > 850 mg/L/4h rat
- Primary irritation: skin: not irritating
eye: not irritating
sensitization: may cause sensitization by skin contact
12 Ecological Information
- Other ecological German water pollution category: 3 (self-classification) highly water polluting
Information: Do not let penetrate into ground water, waters or sewerage, also not small
quantities thereof.
Pollutes potable water already when small quantities penetrate into subsoil.
________________________________________________________________________________________________
13 Disposal Considerations
- Disposal of remainders: Recommendation: Must not be disposed of with domestic waste.
Do not let penetrate into sewerage.
- Hazardous waste number: 070204 „Resin remainder, non-cured�
- Disposal: Special waste combustion
- Disposal of containers: In accordance with federal, state and local regulations.
14 Transport Information
- Transport/Other Information: Non-hazardous material in terms of the transport
regulations in accordance with expertise of the Federal
Health Department dated 23rd September and
5th October 1992 respectively
15 Regulatory Information
- Identification to EC Directives: The product has been classified and identified according
to EC directives / hazardous material directives.
- Danger symbol and danger text: T toxic
- Danger defining components for labelling: expoxy resin molecular weight: < 700
4.4�-methylene dianiline, benzyl alcohol
Munk + Schmitz Telefon (0221) 8 39 08-0 Revision: 22.03.04
Certified to Oberflächentechnik GmbH & Co. KG Fax (0221) 8 39 08-27
DIN EN ISO 9001 Poller Kirchweg 92-104, 51105 Köln E-mail info@munk-schmitz.de Page 4 of 5
Munkadur® Classic (Hardener � 1060) Safety Data Sheet acc. to 2001/58/EC
- Risk-phrases: R 45 May cause cancer
R 20/21/22 Harmfull by inhalation, in contact with skin and if
swallowed
R 43 May cause sensitization by skin contact.
- Safety-phrases: S 26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
S 37/39 Wear suitable protective gloves and eye/face protection.
S 53 Avoid exposure - obtain special instructions before use.
- Special identification of specific preparations: Contains epoxy-containing compounds.
- National Regulations:
- Classification to VbF: Not applicable.
- German water pollution category: WGK 3: highly water polluting.
16 Other Information
This information is based on current knowledge and experience. It does not represent a guarantee for properties
of the described product and does not establish a contractual relationship. The product is destined exclusively for
industrial application/use.
- Data Sheet prepared by: Dept. BT, Laboratory
- Translated into English (German original)
Munk + Schmitz Telefon (0221) 8 39 08-0 Revision: 22.03.04
Certified to Oberflächentechnik GmbH & Co. KG Fax (0221) 8 39 08-27
DIN EN ISO 9001 Poller Kirchweg 92-104, 51105 Köln E-mail info@munk-schmitz.de Page 5 of 5
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