MSDS PAGE: CAS N/A MSDS enerfab_com---pl261msds9-28-04.asp

Page: 1 MATERIAL SAFETY DATA SHEET Printed : 09/27/04
For Coatings, Resins and Related Materials
Revised : 09/24/04
SECTION I �? PRODUCT INDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Manufacturer: SHERWIN−WILLIAMS CO. Information Phone: (800) 543�?7694
(GENERAL POLYMERS) Emergency Phone: (800) 424�?9300
145 CALDWELL DRIVE CHEMTREC Phone: (703) 527�?3887
CINCINNATI OH
45216
+−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?+
| Hazard Ratings: Health �? 1 |
Product Class: EPOXY RESIN (PIGMENTED) | none �?> extreme Fire �? 1 |
Trade Name : HOT SPRAY RESIN GRAY | 0 −−�?> 4 Reactivity �? 0 |
Product Code : PL261 PART A | |
C.A.S. Number: MIXTURE | |
+−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?+
SECTION II �? HAZARDOUS INGREDIENTS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Weight −−�? Exposure Limits −−−− VP
Ingredients CAS # % ACGIH/TLV OSHA/PEL mm HG
−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
REACTION PRODUCT OF 25068�?38�?6 > 75 N.E. N.E. N/AV
BISPHENOL A & EPICHLOROHYDRIN
TITANIUM DIOXIDE 13463�?67�?7 5�?20 10 mg/M3 15 mg/M3 0
***All ingredients are registered on TSCA***
N.E. = Not Established
SECTION III �? PHYSICAL DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
250 Deg. F Vapor Density: Heavier than Air.
Boiling Range:
Evap. Rate: Slower than n−Butyl Acetate Liquid Density: Heavier than Water.
Volatiles vol % 0 Wgt% 0 Wgt per gallon: 10.41 Pounds.
Spec. Gravity: 1.2497
Appearance: PIGMENTED LIQUID
V.O.C.: NONE
SECTION IV �? FIRE AND EXPLOSION HAZARD DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Flammability Class: IIIB GFlash Point: 251 F PMCC LEL: UEL: 0.00%
−EXTINGUISHING MEDIA:
Carbon Dioxide−−−Dry Chemical−−−Foam−−−Water Fog
Use water for cooling material stored in vicinity of fire.
−SPECIAL FIREFIGHTING PROCEDURES:
Use self−contained breathing apparatus with a full facepiece
operated in pressure−demand or other positive pressure mode.
−UNUSUAL FIRE & EXPLOSION HAZARDS:
Vapors are heavier than air and may travel along the ground
to an ignition source some distance from material handling
point. Ignition sources include pilot lights, smoking, heaters,
electric motors, sparks from electrical switches and static
discharges.
CAUTION: Never use cutting torch on empty containers!
Page: 2 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN GRAY(PL261 PART A)

SECTION V �? HEALTH HAZARD DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PERMISSIBLE EXPOSURE LEVEL:
SEE SECTION II
−EFFECTS OF OVEREXPOSURE:
Eyes: can cause severe irritation, redness, tearing, blurred
vision.
Skin: prolonged or repeated contact can cause moderate irrit�?
ation, defatting, dermatitis.
Breathing: excessive inhalation of vapors and/or spraymist can
cause respiratory irritation, dizziness, weakness, fatigue
nausea, headache, unconsciousness and even asphyxiation.
Swallowing: can cause gastrointestinal irritation,nausea,
vomiting and diarrhea; aspiration of material into the
lungs can cause chemical pneumonitis which can be fatal.
−FIRST AID:
Eyes: flush with large amounts of water lifting eyelids
occasionally; get prompt medical attention.
Skin: wash thoroughly with soap and water, remove contaminated
clothing promptly; wash clothing before reuse.
Swallowing: DO NOT induce vomiting! Keep person warm, quiet and
get medical attention. Aspiration of material into the
lungs due to vomiting can cause chemical pneumonitis which
can be fatal.
Breathing: move affected person to fresh air. If breathing is
difficult, administer oxygen. If breathing has stopped,
give artificial respiration. Keep person warm, quiet, and
get medical attention.
SECTION VI �? REACTIVITY DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
STABLITY: [ ] Unstable [x] Stable
HAZARDOUS POLYMERIZATION: [ ] May occur [x] Will not occur
−INCOMPATIBILITY
Avoid contact with strong oxidizing materials, acids and
bases. Avoid unintended contact with amines.
−CONDITIONS TO AVOID:
Keep away from heat and open flame.
−HAZARDOUS DECOMPOSITION PRODUCTS:
May form carbon monoxide and dioxide, various hydrocarbons, etc.
SECTION VII �? SPILL OR LEAK PROCEEDURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
SMALL SPILL: absorb liquid with rags, floor absorbent, vermicu�?
lite or other absorbent material and transfer to hood.
LARGE SPILL: eliminate all ignition sources−−−dike area of spill
to prevent spreading−−−ventilate area if indoors−−−pump liquid
into salvage tank−−−remaining liquid may be taken up with sand,
floor absorbent or other absorbent material and shoveled into
containers−−−prevent run−off to sewers and bodies of water−−�?
notify proper authorities as required by local, state and
federal regulations.
Page: 3 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN GRAY(PL261 PART A)

SECTION VII �? SPILL OR LEAK PROCEEDURES (cont.)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−WASTE DISPOSAL METHOD:
SMALL SPILL: allow volatile portion to evaporate in hood−−�?
dispose of remaining material in accordance with applicable
regulations.
LARGE SPILL: destroy by liquid incineration−−−contaminated
absorbent may be deposited in landfill in accordance with
local, state and federal regulations.
SECTION VIII �? SPECIAL PROTECTION INFORMATION:
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−RESPIRATORY PROTECTION:
If TLV of the product is exceeded, a NIOSH/MSHA jointly approv�?
ed air supply respirator is advised in absence of proper envi�?
ronmental control. OSHA regulations also permit other NIOSH/MSHA
respirators under specified conditions.(see your safety equipmt.
supplier). Engineering or administrative controls should be
implemented to reduce exposure.
−VENTILATION:
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below TLV.
−PROTECTIVE GLOVES:
Wear resistant gloves such as: nitrile rubber
−EYE PROTECTION:
Chemical splash goggles in compliance with OSHA regulations are
advised; however, OSHA regulations also also permit other type
safety glasses. ( consult your safety equipment supplier )
−OTHER PROTECTIVE EQUIPMENT:
NONE
SECTION IX �? SPECIAL PRECAUTIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Store in cool, dry area. Keep Containers closed. Avoid
elevated temperatures.
−OTHER PRECAUTIONS:
NONE
SECTION X �? ADDITIONAL REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of section 313 of the Emergency Planning
and Community Right To Know Act of 1986 and of 40 CFR 372:
Percent by
CAS# Chemical Name Weight
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−−�?
None
Page: 4 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN GRAY(PL261 PART A)

SECTION X �? ADDITIONAL REGULATORY INFORMATION (cont.)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PROP 65 (CARCINOGEN):
WARNING: This product contains the following chemical known to the state
of California to cause cancer.
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None

−PROP 65 (TETRATOGENIC):
WARNING: This product contains the following chemical known to the state
of California to cause birth defects or other reproductive harm.
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None

−PROP 65 (BOTH CARCINOGEN AND TETRATOGENIC):
WARNING: This product may contain a chemical known to the state of
California to cause cancer or birth defects or other reproductive harm
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None
Page: 1 MATERIAL SAFETY DATA SHEET Printed : 09/27/04
For Coatings, Resins and Related Materials
Revised : 09/24/04
SECTION I �? PRODUCT INDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Manufacturer: SHERWIN−WILLIAMS CO. Information Phone: (800) 543�?7694
(GENERAL POLYMERS) Emergency Phone: (800) 424�?9300
145 CALDWELL DRIVE CHEMTREC Phone: (703) 527�?3887
CINCINNATI OH
45216
+−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?+
| Hazard Ratings: Health �? 3 |
Product Class: EPOXY HARDENER | none �?> extreme Fire �? 1 |
Trade Name : HOT SPRAY RESIN HARDENER | 0 −−�?> 4 Reactivity �? 0 |
Product Code : PL261 PART B | |
C.A.S. Number: MIXTURE | |
+−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?+
SECTION II �? HAZARDOUS INGREDIENTS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Weight −−�? Exposure Limits −−−− VP
Ingredients CAS # % ACGIH/TLV OSHA/PEL mm HG
−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
DIETHYLENETRIAMINE 111�?40�?0 1�?5 1 ppm 1 ppm .2
STEL = N.E. N.E. @ 68F
TRADE SECRET 1�?5 0
NEW JERSEY TRADE SECRET
REGISTRY NO. 05995500�?(C1608U)
TETRAETHYLENEPENTAMINE 112�?57�?2 1�?5 N/AVppm N/AV ppm 1
(TEPA)
TALL OIL FATTY ACIDS 68953�?36�?6 5�?20 N/E N/E 0
(TOFA)
POLYAMIDE RESIN 68082�?29�?1 5�?20 N.E. N.E. 0
TRIETHYLENETETRAMINE 112�?24�?3 1�?5 N.E. N.E. 0
(TETA) @ 68F
NONYLPHENOL 84852�?15�?3 5�?20 N.E. N.E. 1
STEL = N.E. ppm
CARBON BLACK 1333�?86�?4 < 1. 3.5 mg/M3 3.5 mg/M3 0
***All ingredients are registered on TSCA***

N.E. = Not Established
SECTION III �? PHYSICAL DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Boiling Range: 404 �? 560 Deg. F Vapor Density: Heavier than Air.
Evap. Rate: Slower than n−Butyl Acetate Liquid Density: Heavier than Water.
Volatiles vol % 0 Wgt% 0 Wgt per gallon: 13.06 Pounds.
Spec. Gravity: 1.56783
Appearance: GRAY
V.O.C.: NONE
Page: 2 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN HARDENER(PL261 PART B)

SECTION IV �? FIRE AND EXPLOSION HAZARD DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
Flammability Class: IIIB Flash Point: 215 F LEL: N/D UEL: N/D
−EXTINGUISHING MEDIA:
Foam �? Carbon dioxide �? Dry Chemical
−SPECIAL FIREFIGHTING PROCEDURES:
Use water to keep exposed containers cool.
−UNUSUAL FIRE & EXPLOSION HAZARDS:
May generate toxic or irritating combustion products.

SECTION V �? HEALTH HAZARD DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PERMISSIBLE EXPOSURE LEVEL:
SEE SECTION II
−EFFECTS OF OVEREXPOSURE:
Repeated or prolonged contact may cause skin sensitization
or eye injuries. May also be harmful if swallowed.
Prolonged contact may cause burning and blistering of the
skin or may cause blindness of the eyes.
−FIRST AID:
In case of contact with skin, immediately wash with soap and
water. For eyes, flush with plenty of water (15 minutes) and
call physician. If inhaled remove to fresh air. If
swallowed, DO NOT induce vomitting. Give plenty of water
or milk and seek medical attention.

SECTION VI �? REACTIVITY DATA
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
STABLITY: [ ] Unstable [x] Stable
HAZARDOUS POLYMERIZATION: [ ] May occur [x] Will not occur
−INCOMPATIBILITY
Strong oxidizers, acids and some epoxy resins.
−CONDITIONS TO AVOID:
Uncontrolled reactions with epoxies.
−HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide and Oxides of Nitrogen.
Page: 3 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN HARDENER(PL261 PART B)

SECTION VII �? SPILL OR LEAK PROCEEDURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Absorb with sand or other absorbant material, scoop into
disposal container, and flush area with plenty of water.
−WASTE DISPOSAL METHOD:
Incinerate or bury in accordance with local, state and federal
laws and regulations.

SECTION VIII �? SPECIAL PROTECTION INFORMATION:
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−RESPIRATORY PROTECTION:
If TLV/PEL limits are exceeded, a NIOSH/MSHA jointly approved
air supply respirator is advised in absence of proper envi�?
ronmental control. OSHA regulations also permit other NIOSH/MSHA
respirators under specified conditions. (See your safety equip�?
ment supplier.) Engineering or administrative controls should be
implemented to reduce exposure.
−VENTILATION:
Mechanical
−PROTECTIVE GLOVES:
Impervious to amines, acids and solvents (Nitrile or Neoprene)
−EYE PROTECTION:
Safety glasses or goggles
−OTHER PROTECTIVE EQUIPMENT:
Safety shower and eye wash
Keep all bodily parts covered and protected.
SECTION IX �? SPECIAL PRECAUTIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Corrosive to eyes and skin. Severe eye & skin irritant.
Practice reasonable care and cleanliness. Store in cool dry
area. Avoid high temperatures. Do not use copper or copper
alloys for storage containers.
CAUTION �? CORROSIVE LIQUID �? HANDLE WITH CARE.
−OTHER PRECAUTIONS:
Always wash before eating, drinking, smoking or using the
restroom.
Page: 4 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN HARDENER(PL261 PART B)

SECTION X �? ADDITIONAL REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of section 313 of the Emergency Planning
and Community Right To Know Act of 1986 and of 40 CFR 372:
Percent by
CAS# Chemical Name Weight
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−−�?
None

−PROP 65 (CARCINOGEN):
WARNING: This product contains the following chemical known to the state
of California to cause cancer.
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None

−PROP 65 (TETRATOGENIC):
WARNING: This product contains the following chemical known to the state
of California to cause birth defects or other reproductive harm.
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None

−PROP 65 (BOTH CARCINOGEN AND TETRATOGENIC):
WARNING: This product may contain a chemical known to the state of
California to cause cancer or birth defects or other reproductive harm
CAS# Chemical Name
−−−−−−−−−−−−�? −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
None

(cont.)
Page: 5 SHERWIN−WILLIAMS CO.
Material Safety Data Sheet for: HOT SPRAY RESIN HARDENER(PL261 PART B)

SECTION X �? ADDITIONAL REGULATORY INFORMATION (cont.)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−�?
−PROP 65 (BOTH CARCINOGEN AND TETRATOGENIC): (cont.)

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fcsdchemicalsandlubricants_com---us171146us.asp	2007-03-1 110-91-8 67-63-0 111-76-2 112-80-1
fcsdchemicalsandlubricants_com---us173219us.asp	2007-01-2 8042-47-5 7440-66-6
fcsdchemicalsandlubricants_com---us174980us.asp	2008-07-1 64741-88-4