Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMLAR LRM V 5 US GL
Product code : 351507 805
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Coating
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black / Brown. Semi-Solid. May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose
and throat. May cause moderate irritation to the respiratory system. May cause allergic respiratory sensitization.
Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained
personnel. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
:
throat. May cause moderate irritation to the respiratory system. May cause allergic
respiratory sensitization.
Eyes Vapor and/or mist may cause eye irritation.
:
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Repeated overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless
suitable engineering controls and/or personal protective equipment are used. Aromatic tar contains polycyclic
aromatic hydrocarbons, some of which have been shown to cause skin cancer following prolonged and
repeated skin contact. Should be considered potentially carcinogenic by inhalation. Carbon black is classified by
IARC to be a known animal carcinogen and a possible human carcinogen (Group 2B). Di(2-ethylhexyl)
phthalate, (dioctyl phthalate) given in the diet, produced increased incidence of liver cancers in female rats and
male and female mice. An increased incidence of liver cancers or neoplasms were observed in male rats. A
long-term NTP study showed that oral exposure to toluene diisocyanate (TDI) caused cancer in rats and mice.
A lifetime inhalation study sponsored by the International Isocyanate Institute did not show carcinogenic activity
in rats. May cause allergic skin and respiratory sensitization.
Target Organs: Eye, Lung, Liver, Kidney, Skin, Nerve
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Aromatic process oil 64742-90-1 30.0 - 60.0
Polyurethane Polymer NJ TSRN# 51721300-5024P 30.0 - 60.0
Calcium Carbonate (Limestone) 1317-65-3 10.0 - 30.0
Carbon Black 1333-86-4 7.0 - 13.0
Calcium oxide 1305-78-8 3.0 - 7.0
Anthracene 120-12-7 1.0 - 5.0
Dioctyl phthalate 117-81-7 - <1.0
2,4-Toluene diisocyanate 584-84-9 - <1.0
Toluene-2,6-Diisocyanate 91-08-7 - <0.1
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 - <0.1
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not applicable.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke,
products fumes.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Closed
container, may burst when exposed to extreme heat.Empty containers
may contain ignitable vapors.Vapors may travel to sources of ignition
and flashback.
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands
thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To prevent
generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Store
under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) are expected to exceed exposure limits
indicated on the MSDS. Select positive pressure supplied air respirator
(TC19C or equivalent) for isocyanates.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Carbon Black 1333-86-4 ACGIH TWA: 3.5 mg/m3
OSHA PEL: 3.5 mg/m3
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
Chemical Name CAS Number Regulation Limit Form
Calcium oxide 1305-78-8 ACGIH TWA: 2 mg/m3
OSHA PEL: 5 mg/m3
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Dioctyl phthalate 117-81-7 ACGIH TWA: 5 mg/m3
OSHA PEL: 5 mg/m3
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
Toluene-2,6-Diisocyanate 91-08-7 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
Crystalline Silica 14808-60-7 OSHA TWA: 0.1 mg/m3 Respirable.
(Quartz)/ Silica Sand OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
ACGIH TWA: 0.025 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Semi-Solid
Color : Black / Brown
Odor : Solvent odor
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.09
% Volatile Weight : 4%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.Amines.Water or moisture.Alcohols.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Dioctyl phthalate, CAS-No.: 117-81-7
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
Acute oral toxicity (LD-50 oral) 25,000 mg/kg ( Rat ) 30,000 mg/kg ( Mouse ) 33,900 mg/kg
( Rabbit ) 26,300 mg/kg ( Guinea pig )
Acute dermal toxicity (LD-50 dermal) 10,000 mg/kg ( Guinea pig ) 25,000 mg/kg ( Rabbit )
2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4
h ( Guinea pig ) 11 mg/l for 4 h ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Anthracene 120-12-7
Dioctyl phthalate 117-81-7
2,4-Toluene diisocyanate 584-84-9
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
Aromatic process oil 64742-90-1
Calcium Carbonate (Limestone) 1317-65-3
Carbon Black 1333-86-4
Calcium oxide 1305-78-8
Anthracene 120-12-7
Dioctyl phthalate 117-81-7
2,4-Toluene diisocyanate 584-84-9
Toluene-2,6-Diisocyanate 91-08-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
OSHA Status: Considered : Irritant
hazardous based on the Sensitizer
following criteria: Carcinogen
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 53 g/l
exempt solvent)
VOC Method 310 : 4%
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Carbon Black 1333-86-4
U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3
Carbon Black 1333-86-4
Calcium oxide 1305-78-8
Anthracene 120-12-7
2,4-Toluene diisocyanate 584-84-9
Toluene-2,6-Diisocyanate 91-08-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Penn RTK Components : Aromatic process oil 64742-90-1
Polyurethane Polymer NJ TSRN# 51721300-5024P
Calcium Carbonate (Limestone) 1317-65-3
Carbon Black 1333-86-4
Calcium oxide 1305-78-8
Anthracene 120-12-7
2,4-Toluene diisocyanate 584-84-9
NJ RTK Components : Aromatic process oil 64742-90-1
Polyurethane Polymer NJ TSRN# 51721300-5024P
Calcium Carbonate (Limestone) 1317-65-3
Carbon Black 1333-86-4
Calcium oxide 1305-78-8
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
64742-90-1 Aromatic process oil
1333-86-4 Carbon Black
117-81-7 Dioctyl phthalate
584-84-9 2,4-Toluene diisocyanate
91-08-7 Toluene-2,6-Diisocyanate
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
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Material Safety Data Sheet
TREMLAR LRM V 5 US GL
Version 2. Print Date 08/09/2008
REVISION DATE: 08/08/2008
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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