Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : SHEETING BOND A.F.-U.S. 5 US GL
Product code : 361581 805
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Paste. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue.
May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
:
fatigue. May cause slight irritation to the respiratory system.
Eyes Direct contact may cause moderate irritation. Direct contact may cause temporary
:
redness and discomfort.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause moderate irritation. May cause itching, reddening, inflammation. May cause a
:
rash. May cause sensitization.
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated skin contact with asphalt may result in skin sensitivity, such as irritation, rashes, and
dermatitis. Prolonged or repeated exposure to polycyclic aromatic hydrocarbons and other volatiles which are
contained in trace amounts in asphalt have been shown to cause cancer or respiratory damage in animals.
Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis,
central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver,
kidney damage. Xylene overexposure may affect fetal development. Carbon black is classified by IARC to be a
known animal carcinogen and a possible human carcinogen (Group 2B). Carbon black is encapsulated by resin
and not expected to have adverse effects unless made airborne. The International Agency for Research on
Cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based
on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans. Fillers are encapsulated and not expected to be released from product under normal
conditions of use.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
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Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Polybutene 9003-29-6 15.0 - 40.0
Xylene 1330-20-7 15.0 - 40.0
Carbon Black 1333-86-4 15.0 - 40.0
Asphalt 8052-42-4 10.0 - 30.0
Isobutylene isoprene copolymer NJ TSRN# 51721300-5275P 7.0 - 13.0
Ethylbenzene 100-41-4 3.0 - 7.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Oxides of
products sulfur can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
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Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Xylene 1330-20-7 ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
OSHA PEL: 435 mg/m3
Carbon Black 1333-86-4 ACGIH TWA: 3.5 mg/m3
OSHA PEL: 3.5 mg/m3
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Asphalt 8052-42-4 ACGIH TWA: 0.5 mg/m3 Inhalable fraction.as
benzene solubles
Ethylbenzene 100-41-4 ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm
OSHA PEL: 435 mg/m3
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Paste
Color : Black
Odor : Aromatic
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Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.065
% Volatile Weight : 25 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 3,523 - 8,600 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 6,350 mg/l ( Rat )
Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
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Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Xylene 1330-20-7
Ethylbenzene 100-41-4
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
Xylene 1330-20-7
Carbon Black 1333-86-4
Asphalt 8052-42-4
Ethylbenzene 100-41-4
OSHA Status: Considered : Irritant
hazardous based on the Carcinogen
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 273 g/l
exempt solvent)
VOC Method 310 : 25 %
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Carbon Black 1333-86-4
U.S. State Regulations:
MASS RTK Components : Xylene 1330-20-7
Carbon Black 1333-86-4
Asphalt 8052-42-4
Ethylbenzene 100-41-4
Penn RTK Components : Polybutene 9003-29-6
Xylene 1330-20-7
Carbon Black 1333-86-4
Asphalt 8052-42-4
Isobutylene isoprene copolymer NJ TSRN# 51721300-5275P
Ethylbenzene 100-41-4
NJ RTK Components : Polybutene 9003-29-6
Xylene 1330-20-7
Carbon Black 1333-86-4
Asphalt 8052-42-4
Isobutylene isoprene copolymer NJ TSRN# 51721300-5275P
Ethylbenzene 100-41-4
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
1333-86-4 Carbon Black
8052-42-4 Asphalt
100-41-4 Ethylbenzene
108-88-3 Toluene
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Material Safety Data Sheet
SHEETING BOND A.F.-U.S. 5 US GL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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