Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : BURMASTIC ADHESIVE SF - 5 GAL
Product code : 365600 805
Supplier : Tremco Canada division
220 Wicksteed Avenue
Toronto, ON M4H 1G7
Telephone : (416) 421-3300
Emergency Phone: : (613) 996-6666
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 08/31/2006
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Liquid. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue.
May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
:
fatigue. May cause slight irritation to the respiratory system.
Eyes Direct contact may cause moderate irritation. Direct contact may cause temporary
:
redness and discomfort.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause moderate irritation. May cause itching, reddening, inflammation. May cause a
:
rash. May cause sensitization.
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated skin contact with asphalt may result in skin sensitivity, such as irritation, rashes, and
dermatitis. Prolonged or repeated exposure to polycyclic aromatic hydrocarbons and other volatiles which are
contained in trace amounts in asphalt have been shown to cause cancer or respiratory damage in animals.
Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, and
irritation of the skin, dermatitis, and central nervous system (CNS) effects. Prolonged or repeated exposure to
butyl benzyl phthalate may cause reduced body weights and adverse effects on the liver, kidney, spleen,
pancreas, and reproductive organs. Overexposure to maleic anhydride can cause allergic asthmatic responses
and, after long-term exposure, bronchitis. Diphenylmethane diisocyanate (methylene bisphenyl isocyanate)
caused an increased incidence of lung tumors in experimental animals following long term inhalation at
concentrations in excess of 100 times the exposure limit. Fillers are encapsulated and not expected to be
released from product under normal conditions of use.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Asphalt 64741-56-6 15.0 - 40.0
Butyl benzyl phthalate 85-68-7 15.0 - 40.0
Heavy aromatic naphtha 64742-94-5 7.0 - 13.0
4,4'-Methylene bis(phenylisocyanate) 101-68-8 5.0 - 10.0
Maleic anhydride 108-31-6 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 149 掳 300 掳
C, F
Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Oxides of
products sulfur can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Butyl benzyl phthalate 85-68-7
4,4'-Methylene 101-68-8 Ontario TWA: 0.005 ppm
bis(phenylisocyanate) ACGIH TWA: 0.005 ppm
Maleic anhydride 108-31-6 Ontario TWA: 0.1 ppm
ACGIH TWA: 0.1 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid
Form : Liquid
Color : Black
Odor : Petroleum
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 1.09
% Volatile Weight : 15 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Butyl benzyl phthalate, CAS-No.: 85-68-7
Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )
4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8
Acute inhalation toxicity (LC-50) 0.38 mg/l ( Rat )
Maleic anhydride, CAS-No.: 108-31-6
Acute oral toxicity (LD-50 oral) 900 mg/kg ( Albino Sprague-Dawley rat )
Acute dermal toxicity (LD-50 dermal) 631 mg/kg ( Albino rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
Canadian Regulations:
WHMIS Classification : D2B, D2A
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 164 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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