Material Safety Data Sheet
POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Product code : 365200 805
Supplier : Tremco Canada division
220 Wicksteed Avenue
Toronto, ON M4H 1G7
Telephone : (416) 421-3300
Emergency Phone: : (613) 996-6666
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 08/31/2006
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Liquid. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue.
May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
:
fatigue. May cause slight irritation to the respiratory system.
Eyes Direct contact may cause moderate irritation. Direct contact may cause temporary
:
redness and discomfort.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause moderate irritation. May cause itching, reddening, inflammation. May cause a
:
rash. May cause sensitization.
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated skin contact with asphalt may result in skin sensitivity, such as irritation, rashes, and
dermatitis. Prolonged or repeated exposure to polycyclic aromatic hydrocarbons and other volatiles which are
contained in trace amounts in asphalt have been shown to cause cancer or respiratory damage in animals.
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica. Fillers are encapsulated and not expected to be released from product
under normal conditions of use. Prolonged or repeated exposure to mineral spirits (petroleum naphtha or
stoddard solvent) may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system
(CNS) effects, and adverse liver, kidney, and lung effects.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve
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Material Safety Data Sheet
POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Asphalt 64741-56-6 40.0 - 70.0
Stoddard solvent (Mineral Spirits) 8052-41-3 15.0 - 40.0
1,2,4-Trimethylbenzene 95-63-6 1.0 - 5.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 50 掳 122 掳
C, F
Method : Pensky-Martens Closed Cup
Lower explosion limit : 1.00 %(V) Solvent
Upper explosion limit : 5 %(V) Solvent
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.Oxides of
products sulfur can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
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Material Safety Data Sheet
POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.Inspect and replace
equipment at regular intervals.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Stoddard solvent (Mineral 8052-41-3 Ontario TWA: 525 mg/m3
Spirits) ACGIH TWA: 100 ppm
1,2,4-Trimethylbenzene 95-63-6 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
Crystalline Silica (Quartz)/ 14808-60-7 Ontario TWA: 0.10 mg/m3 Respirable fraction.
Silica Sand ACGIH TWA: 0.05 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid
Form : Liquid
Color : Black
Odor : Petroleum
pH : Not available.
Vapour pressure : Not available.
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Material Safety Data Sheet
POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 243 掳C, 469 掳F
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 1.03
% Volatile Weight : 23 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability)
This classification applies only to the material as it was originally produced.
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
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Material Safety Data Sheet
POWERPLY RUBBERIZED COLD ADHESIVE 5 GAL
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
Canadian Regulations:
WHMIS Classification : B3, D2A, D2B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 246 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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