MATERIAL SAFETY DATA SHEET
3735 GREEN ROAD TELEPHONE: (216)292-5000 EMERGENCIES: (216)765-6727 8:30-5:00 EST
BEACHWOOD, OHIO 44122-8068 AFTER HOURS: CHEMTREC (800)424-9300
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SECTION 1
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Order Code: 364101L805
Product Name: BURMASTIC FR
Chemical Family: Roof Coating
Product Code: 364-101L Date Prepared: 03-MAY-96
MSDS Preparer: C. R. BRUNO Replaces Date: 09-MAY-94
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Section 2 - Molecular Compostion
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Common Name and Chemical Name Weight % CAS Number
Exposure Limits
ASPHALT 50.0-55.0 8052-42-4
OSHA:TWA - STEL -
ACGIH:TWA 5 mg/M3 STEL - (fumes)
STODDARD SOLVENT (MINERAL SPIRITS) 25.0-30.0 8052-41-3
OSHA:TWA 100 ppm STEL -
ACGIH:TWA 100 ppm STEL -
FIRE RETARDANT 10.0-15.0 Trade Secret
OSHA:TWA 15 mg/M3 STEL - (total nuisance dust)
ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)
MAGNESIUM ALUMINUM SILICATE (CLAY) 1.0-5.0 8031-18-3
OSHA:TWA 15 mg/M3 STEL - (total nuisance dust)
ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)
FIRE RETARDANT 1.0-5.0 Trade Secret
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
CRYSTALLINE SILICA (QUARTZ) 0.1-0.4 14808-60-7
OSHA:TWA 0.10 mg/M3 STEL - (skin) (respirable dust)
ACGIH:TWA 0.10 mg/M3 STEL - (respirable dust)
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Section 3 - Hazards Identification
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Emergency Overview:
Black liquid. Can cause headache, dizziness, drownsiness, or irritation to
the skin, eyes and respiratory system. If inhaled leave area to breathe
fresh air. Avoid further overexposure. If symptoms persist, get medical
attention immediately.
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Potential Hlth Effect/Rte of Entry:
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Inhalation:
Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to
respiratory system.
Eyes:
Can cause irritation.
Ingestion:
Can cause gastrointestinal irritation.
Skin:
Can cause irritation.
Acute Health Effects:
Not established.
Chronic Health Effects:
Asphalt contains small amounts of polynuclear aromatic compounds which have
been shown to cause cancer and respiratory damage in laboratory animals.
IARC concluded that there is sufficient evidence for carcinogenicity of
crystalline silica (quartz) in experimental animals, but only limited
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Order Code: 364101L805
evidence in humans. Prolonged and repeated overexposure to free crystalline
silica dust above the TLV level may cause scarring of the lungs with cough
and shortness of breath. A delayed lung injury, silicosis may result from
breathing free silica. However, silica is encapsulated in this product and
release is not expected. Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling
contents may be harmful or fatal. Overexposure to mineral spirits can
adversely affect the lung, CNS or cardiac system. Prolonged and repeated
exposure caused kidney damage in male rats.
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Section 4 - First Aid Measures
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Inhalation:
Leave area to breathe fresh air. Avoid further overexposure. If symptoms
persist, get medical attention immediately.
Eyes:
Flush immediately with running water for 15 minutes, lifting the upper and
lower lids occasionaly. Get medical attention immediately.
Ingestion:
Get medical attention immediately.
Skin:
Wash area of contact thoroughly with hand cleaner followed by soap and
water. If irritation, rash or other disorders develop, get medical
attention immediately.
Notes to Physician: N/A
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Section 5 - Fire Fighting Measures
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Flash Point: 110 F
Method: PMCC
Lower Flammability Limit: 0.7% (SOLVENT)
Upper Flammability Limit: 6% (SOLVENT)
Autoignition Temperature: Not Established
Extinguishing Media:
If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Fire and Explosion Hazards:
Never use welding or cutting torch on or near container (even empty).
Product, residue or vapor may ignite. See section IX for additional
precautions.
Special Fire Fighting Procedures:
During a fire, personnel at the scene are to prevent exposure to fumes
using accepted fire fighting techniques.
Fire Fighting Equipment: N/A
Other Precautions:
Small amounts of ammonia, phosphoric acid may form.
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Section 6 - Accidental Release Measures
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Release Response Overview:
Remove sources of ignition immediately. Ventilate to reduce the airborne
contaminant concentration below the exposure limit in Section II of the
MSDS. Absorb spill in sand, earth or other suitable material. Transfer to
appropriate container for disposal.
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Order Code: 364101L805
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Section 7 - Handling and Storage
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Handling and Storage Precautions:
Store in closed container. Keep product and vapor away from heat,
sparks and flame. Do not store in direct sunlight. Prevent inhalation of
vapor, ingestion, and contact with skin and eyes. Keep container closed
when not in use. Vapor may migrate to sources of ignition. Do not smoke,
weld, generate sparks, or use flame near container. Change soiled
workclothes frequently. Clean hands thoroughly after handling. Precautions
also apply to emptied containers.
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Section 8 - Exposure Controls/Personal Protection
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Respiratory:
Wear appropriate, properly fitted NIOSH/MSHA approved respirator when the
airborne contaminant level(s) exceed the exposure limits indicated on the
MSDS. Follow respirator manufacturer's directions for respirator use.
Skin:
Protect hands with impervious rubber gloves and wear rubber apron and
overshoes. Prevent contact with skin.
Eyes:
Chemical splash goggles.
Face:
Face shield is recommended.
Engineering:
Use local exhaust when the general ventilation is not sufficient to keep
the airborne contaminant concentration below the exposure limit in Section
II of the MSDS.
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Section 9 - Physical and Chemical Properties
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Odor/Appearance: SOLVENT/BLACK LIQUID
Color: BLACK
Physical State: Liquid
pH: N/A
Vapor Pressure: Not Established
Vapor Density: >1
Boiling Point: Not Establ.
Melting Point: N/A
Freezing Point: Not Establ.
Solubility in Water: Negligible
Specific Gravity: 0.99
% Volatile Weight: 30.0
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Section 10 - Reactivity/Stability
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Stability:
Stable
Incompatible Products:
Avoid contact with strong oxidizing agents.
Conditions to Avoid Polymerization:
Hazardous polymerization will not occur.
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Section 11 - Toxicological Information
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Eyes: N/A
Ingestion: N/A
Inhalation: N/A
Skin: N/A
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Order Code: 364101L805
Subchronic: N/A
Chronic: N/A
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Section 12 - Ecological Information
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Ecotoxicological Data: N/A
Chemical Fate: N/A
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Section 13 - Disposal Considerations
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RCRA Class:
D001 - IGNITABLE LIQUID OR SOLID WASTE (RQ = 100.0 LB)
Disposal Method:
Subject to hazardous waste treatment, storage, and disposal requirements
under RCRA. Incinerate at EPA approved facility or dispose of in compliance
with federal, state and local regulations.
EPA Reportable Quantities
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N/A
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Section 14 - Transportation Data
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DOT Shipping Name: NOT REGULATED(SEE BELOW)
DOT Hazard Class: NOT APPLICABLE
DOT Label: NONE
UN/NA Number: BELOW
Packing Group: BELOW
Special Provisions:
Packaging
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Exceptions:
Non-Bulk:
Bulk:
Quantity Limitations
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Passenger Aircraft or Railcar:
Cargo Aircraft:
Vessel Stowage Requirements
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Vessel Stowage:
Other Stowage:
Transportation Notes:
TYPE OF CONTAINER/SHIPMENT PROPER SHIPPING NAME HAZARD CLASS UN/NA#
LESS THAN 110 GAL/DOMESTIC NOT REGULATED NOT REGULATED N/A
MORE THAN 110 GAL/DOMESTIC COMBUSTIBLE LIQUID
N.O.S.(MINERAL SPIRITS) COMBUSTIBLE, NA1993
CLASS3,PGIII
ALL CONTAINERS/FOR AIR- FLAMMABLE LIQUID
FREIGHT OR INTERNATIONAL N.O.S.(MINERAL SPIRITS) FLAMMABLE, UN1993
SHIPMENTS CLASS3,PGIII
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Section 15 - Regulatory Information
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TSCA Status: On the TSCA Inventory
OSHA Status: Considered hazardous based on the following criteria:
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Order Code: 364101L805
Irritant
Target Organs
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Liver
Kidney
Nerve
Lung
Skin
OSHA Hazardous Components CAS Number
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* CRYSTALLINE SILICA (QUARTZ) 14808-60-7
* ASPHALT 8052-42-4
* - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN
Compliance Quantites
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Source Type Threshold Unit of Measure
RCRA(D001) REPORTABLE QUANTITY 100.0 POUNDS
SARA 311 Ratings
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Immediate Health Hazard: Y
Delayed Health Hazard: Y
Fire Hazard: Y
Reactivity Hazard: N
Sudden Release of Pressure Hazard: N
SARA 313 Ingredients
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No SARA 313 Ingredients
Proposition 65 Ingredients
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Chemicals known to the State of California to cause cancer or
birth defects or other reproductive harm CAS Number
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CRYSTALLINE SILICA (QUARTZ) 14808-60-7
ASPHALT 8052-42-4
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Section 16 - Other Information
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FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN.
THE HAZARD INFORMATIOM HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION
OF THE USER, SUBJECT TO HIS OWN INVESTIGATION OF COMPLIANCE WITH APPLICABLE
REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE
CONDITION.
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