MATERIAL SAFETY DATA SHEET
3735 GREEN ROAD TELEPHONE: (216)292-5000 EMERGENCIES: (216)765-6727 8:30-5:00 EST
BEACHWOOD, OHIO 44122-8068 AFTER HOURS: CHEMTREC (800)424-9300
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SECTION 1
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Order Code: 364100L805
Product Name: BURMASTIC ADHESIVE LV
Chemical Family: Roof Adhesive
Product Code: 364-100L Date Prepared: 02-MAY-96
MSDS Preparer: C.R. Bruno Replaces Date: 02-FEB-95
Other Applications:
TYPE OF CONTAINER/SHIPMENT PROPER SHIPPING NAME HAZARD CLASS UN/NA#
LESS THAN 110 GAL/DOMESTIC NOT REGULATED NOT REGULATED N/A
MORE THAN 110 GAL/DOMESTIC COMBUSTIBLE LIQUID
N.O.S.(MINERAL SPIRITS) COMBUSTIBLE NA1993
ALL CONTAINERS/FOR AIR- FLAMMABLE LIQUID
FREIGHT OR INTERNATIONAL N.O.S.(MINERAL SPIRITS) FLAMMABLE UN1993
SHIPMENTS
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Section 2 - Molecular Compostion
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Common Name and Chemical Name Weight % CAS Number
Exposure Limits
ASPHALT 60.0-65.0 8052-42-4
OSHA:TWA - STEL -
ACGIH:TWA 5 mg/M3 STEL - (fumes)
STODDARD SOLVENT (MINERAL SPIRITS) 20.0-25.0 8052-41-3
OSHA:TWA 100 ppm STEL -
ACGIH:TWA 100 ppm STEL -
CALCIUM CARBONATE (LIMESTONE) 5.0-10.0 1317-65-3
OSHA:TWA 15 mg/M3 STEL - (tot dust,5mg/M3 respirable)
ACGIH:TWA 10 mg/M3 STEL - (tot dust,no asbest,<1%SiO2)
MAGNESIUM ALUMINUM SILICATE (CLAY) 1.0-5.0 8031-18-3
OSHA:TWA 15 mg/M3 STEL - (total nuisance dust)
ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)
MAGNESIUM CARBONATE 0.5-1.0 546-93-0
OSHA:TWA 15 mg/M3 STEL - (tot dust,5mg/M3 respirable)
ACGIH:TWA 10 mg/M3 STEL - (total nuisance dust)
CRYSTALLINE SILICA (QUARTZ) 0.1-0.5 14808-60-7
OSHA:TWA 0.10 mg/M3 STEL - (respirable dust)
ACGIH:TWA 0.10 mg/M3 STEL - (respirable dust)
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Section 3 - Hazards Identification
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Emergency Overview:
Black liquid. Can cause headache, dizziness, drownsiness, or irritation to
the skin, eyes and respiratory system. If inhaled leave area to breathe
fresh air. Avoid further overexposure. If symptoms persist, get medical
attention immediately.
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Potential Hlth Effect/Rte of Entry:
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Inhalation:
Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to
respiratory system.
Eyes:
Can cause irritation.
Ingestion:
Can cause gastrointestinal irritation.
Skin:
Can cause irritation.
Acute Health Effects:
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Order Code: 364100L805
Not established.
Chronic Health Effects: Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and
nervous system damage. Intentional misuse by deliberately concentrating and
inhaling contents may be harmful or fatal. Asphalt contains small amounts
of polynuclear aromatic compounds which have been shown to cause cancer and
respiratory damage in laboratory animals. Overexposure to mineral spirits
can adversely affect the lung, CNS or cardiac system. Prolonged and
repeated exposure caused kidney damage in male rats. IARC concluded that
there is sufficient evidence for carcinogenicity of crystalline silica
(quartz) in experimental animals, but only limited evidence in humans.
Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath.
A delayed lung injury, silicosis may result from breathing free silica.
However, silica is encapsulated in this product and release is not expected.
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Section 4 - First Aid Measures
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Inhalation:
Leave area to breathe fresh air. Avoid further overexposure. If symptoms
persist, get medical attention immediately.
Eyes:
Flush immediately with running water for 15 minutes, lifting the upper and
lower lids occasionaly. Get medical attention immediately.
Ingestion:
Get medical attention immediately.
Skin:
Wash area of contact thoroughly with hand cleaner followed by soap and
water. If irritation, rash or other disorders develop, get medical
attention immediately.
Notes to Physician: N/A
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Section 5 - Fire Fighting Measures
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Flash Point: 115 F
Method: SETA
Lower Flammability Limit: Not Established
Upper Flammability Limit: Not Established
Autoignition Temperature: Not Established
Extinguishing Media:
If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Fire and Explosion Hazards:
Never use welding or cutting torch on or near container (even empty).
Product, residue or vapor may ignite. See section IX for additional
precautions.
Special Fire Fighting Procedures:
During a fire, personnel at the scene are to prevent exposure to fumes
using accepted fire fighting techniques.
Fire Fighting Equipment: N/A
Other Precautions:
N/A
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Section 6 - Accidental Release Measures
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Release Response Overview:
Remove sources of ignition immediately. Ventilate to reduce the airborne
contaminant concentration below the exposure limit in Section II of the
MSDS. Absorb spill in sand, earth or other suitable material. Transfer to
appropriate container for disposal.
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Section 7 - Handling and Storage
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Handling and Storage Precautions: Store in closed container.
Keep liquid and vapor away from heat, sparks and flame. Do not store in direct
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Order Code: 364100L805
sunlight. Prevent inhalation of vapor, ingestion, and contact with skin and
eyes. Keep container closed when not in use. Vapor may migrate to sources of
ignition. Do not smoke, weld, generate sparks, or use flame near container.
Change soiled workclothes frequently. Clean hands thoroughly after handling. To
prevent gases, vapors or fumes from migrating into occupied sections of the
building, close or cover all openings including windows, doors and air intakes
during and after application until gases, vapors or fumes dissipate.
Precautions also apply to emptied containers.
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Section 8 - Exposure Controls/Personal Protection
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Respiratory:
Wear appropriate, properly fitted NIOSH/MSHA approved respirator when the
airborne contaminant level(s) exceed the exposure limits indicated on the
MSDS. Follow respirator manufacturer's directions for respirator use.
Skin:
Protect hands with impervious rubber gloves and wear rubber apron and
overshoes. Prevent contact with skin.
Eyes:
Chemical splash goggles.
Face:
Face shield is recommended.
Engineering:
Use local exhaust when the general ventilation is not sufficient to keep
the airborne contaminant concentration below the exposure limit in Section
II of the MSDS.
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Section 9 - Physical and Chemical Properties
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Odor/Appearance: SOLVENT/BLACK LIQUID
Color: BLACK
Physical State: LIQUID
pH: N/A
Vapor Pressure: Not established
Vapor Density: >1
Boiling Point: N/A
Melting Point: N/A
Freezing Point: N/A
Solubility in Water: Negligible
Specific Gravity: 0.97
% Volatile Weight: 26.0
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Section 10 - Reactivity/Stability
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Stability:
Stable
Incompatible Products:
Avoid contact with strong oxidizing agents.
Conditions to Avoid Polymerization:
Hazardous polymerization will not occur.
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Section 11 - Toxicological Information
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Eyes: N/A
Ingestion: N/A
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Order Code: 364100L805
Inhalation: N/A
Skin: N/A
Subchronic: N/A
Chronic: N/A
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Section 12 - Ecological Information
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Ecotoxicological Data: N/A
Chemical Fate: N/A
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Section 13 - Disposal Considerations
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RCRA Class:
A,H - Group A Waste, Hazardous Contaminated Garbage
D001 - Ignitable Liquid or Solid Waste
Disposal Method:
Subject to hazardous waste treatment, storage, and disposal requirements
under RCRA. Incinerate at EPA approved facility or dispose of in compliance
with federal, state and local regulations.
EPA Reportable Quantities
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CERCLA Reportable Quantity: N/A
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Section 14 - Transportation Data
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DOT Shipping Name: SEE BELOW
DOT Hazard Class:
DOT Label: NONE (INTERN'L FLAMMABLE)
UN/NA Number: SEE BELOW
Packing Group: NO
Special Provisions:
Packaging
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Exceptions: 49CFR173.13
Non-Bulk:
Bulk:
Quantity Limitations
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Passenger Aircraft or Railcar:
Cargo Aircraft:
Vessel Stowage Requirements
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Vessel Stowage:
Other Stowage:
Transportation Notes:
TYPE OF CONTAINER/SHIPMENT PROPER SHIPPING NAME HAZARD CLASS UN/NA#
LESS THAN 110 GAL/DOMESTIC NOT REGULATED NOT REGULATED N/A
MORE THAN 110 GAL/DOMESTIC COMBUSTIBLE LIQUID
N.O.S.(MINERAL SPIRITS) COMBUSTIBLE NA1993
ALL CONTAINERS/FOR AIR- FLAMMABLE LIQUID
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Product 364-100L Page 4 of 5
Order Code: 364100L805
FREIGHT OR INTERNATIONAL N.O.S.(MINERAL SPIRITS) FLAMMABLE UN1993
SHIPMENTS
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Section 15 - Regulatory Information
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TSCA Status: On the TSCA Inventory
OSHA Status: Considered hazardous based on the following criteria:
Irritant
Target Organs
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Liver
Kidney
Nerve
Lung
OSHA Hazardous Components CAS Number
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CRYSTALLINE SILICA (QUARTZ) 14808-60-7
ASPHALT 8052-42-4
Compliance Quantites
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Source Type Threshold Unit of Measure
RCRA REPORTABLE QUANTITY 100.0 POUNDS
SARA 311 Ratings
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Immediate Health Hazard: Y
Delayed Health Hazard: Y
Fire Hazard: Y
Reactivity Hazard: N
Sudden Release of Pressure Hazard: N
SARA 313 Ingredients
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No SARA 313 Ingredients
California Proposition 65 Ingredients
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Chemicals known to the State of California to cause cancer or
birth defects or other reproductive harm. CAS Number
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CRYSTALLINE SILICA (QUARTZ) 14808-60-7
ASPHALT 8052-42-4
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Section 16 - Other Information
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FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN.
THE HAZARD INFORMATIOM HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION
OF THE USER, SUBJECT TO HIS OWN INVESTIGATION OF COMPLIANCE WITH APPLICABLE
REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE
CONDITION.
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