Material Safety Data Sheet
TREMLAR PTM
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : TREMLAR PTM
Product code : 351536 805
Supplier : Tremco Canada division
220 Wicksteed Avenue
Toronto, ON M4H 1G7
Telephone : (416) 421-3300
Emergency Phone: : (613) 996-6666
Product use : Coating
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 08/31/2006
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid solution. May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
throat. May cause moderate irritation to the respiratory system. May cause allergic respiratory sensitization.
Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained
personnel. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
:
throat. May cause moderate irritation to the respiratory system. May cause allergic
respiratory sensitization.
Eyes Vapor and/or mist may cause eye irritation.
:
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Chronic Health Effects
Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis,
central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver,
kidney damage. Xylene overexposure may affect fetal development. Prolonged or repeated contact/exposure
to aromatic petroleum distillates may cause defatting, drying, and irritation of the skin, dermatitis, and central
nervous system (CNS) effects. Fillers are encapsulated and not expected to be released from product under
normal conditions of use.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve, Blood, Reproductive
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Material Safety Data Sheet
TREMLAR PTM
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Aromatic petroleum distillates 64742-95-6 10.0 - 30.0
Trimethyl benzene (mixed isomers) 25551-13-7 3.0 - 7.0
Methylene bis (4-cyclohexy
5124-30-1 1.0 - 5.0
isocyanate)
Xylene 1330-20-7 1.0 - 5.0
1,3,5-Trimethylbenzene 108-67-8 1.0 - 5.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 110 掳 43 掳
F, C
Method : Tag Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke,
products fumes.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Closed
container, may burst when exposed to extreme heat.Empty containers
may contain ignitable vapors.Vapors may travel to sources of ignition
and flashback.
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
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Material Safety Data Sheet
TREMLAR PTM
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands
thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To prevent
generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Store
under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) are expected to exceed exposure limits
indicated on the MSDS. Select positive pressure supplied air respirator
(TC19C or equivalent) for isocyanates.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Trimethyl benzene (mixed 25551-13-7 Ontario TWA: 123 mg/m3
isomers) ACGIH TWA: 25 ppm
Methylene bis (4- 5124-30-1 Ontario TWA: 0.005 ppm
cyclohexy isocyanate) ACGIH TWA: 0.005 ppm
Xylene 1330-20-7 Ontario TWA: 435 mg/m3
Ontario STEL: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
1,3,5-Trimethylbenzene 108-67-8 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid
Form : Liquid solution
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Material Safety Data Sheet
TREMLAR PTM
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
Color : Gray
Odor : MildSolvent
pH : Not available.
Vapour pressure : 9.5 hPa
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 1.13
% Volatile Weight : 17 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.Amines.Water or moisture.Alcohols.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Trimethyl benzene (mixed isomers), CAS-No.: 25551-13-7
Acute oral toxicity (LD-50 oral) 8,970 mg/kg ( Rat )
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 3,523 - 8,600 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 6,350 mg/l ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability)
This classification applies only to the material as it was originally produced.
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
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Material Safety Data Sheet
TREMLAR PTM
Version 1.1 Print Date 09/01/2006
REVISION DATE: 08/31/2006
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
Canadian Regulations:
WHMIS Classification : D2A, D2B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 202 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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