Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMLAR PTM
Product code : 351535 805
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Coating
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid solution. May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
throat. May cause moderate irritation to the respiratory system. May cause allergic respiratory sensitization.
Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained
personnel. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
:
throat. May cause moderate irritation to the respiratory system. May cause allergic
respiratory sensitization.
Eyes Vapor and/or mist may cause eye irritation.
:
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Chronic Health Effects
Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis,
central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver,
kidney damage. Xylene overexposure may affect fetal development. Prolonged or repeated contact/exposure
to aromatic petroleum distillates may cause defatting, drying, and irritation of the skin, dermatitis, and central
nervous system (CNS) effects. A long-term NTP study showed that oral exposure to toluene diisocyanate (TDI)
caused cancer in rats and mice. A lifetime inhalation study sponsored by the International Isocyanate Institute
did not show carcinogenic activity in rats. May cause allergic skin and respiratory sensitization. Fillers are
encapsulated and not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Lung, Liver, Kidney, Nerve, Blood, Reproductive
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Polyurethane Prepolymer NJ TSRN# 51721300-5684P > 60.0
Aromatic petroleum distillates 64742-95-6 10.0 - 30.0
Calcium carbonate 471-34-1 10.0 - 30.0
Trimethyl benzene (mixed isomers) 25551-13-7 3.0 - 7.0
Titanium dioxide 13463-67-7 3.0 - 7.0
1,3,5-Trimethylbenzene 108-67-8 1.0 - 5.0
Xylene 1330-20-7 1.0 - 5.0
2,4-Toluene diisocyanate 584-84-9 - <1.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : 110 掳 43 掳
F, C
Method : Tag Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke,
products fumes.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Closed
container, may burst when exposed to extreme heat.Empty containers
may contain ignitable vapors.Vapors may travel to sources of ignition
and flashback.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
not in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands
thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To prevent
generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Store
under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) are expected to exceed exposure limits
indicated on the MSDS. Select positive pressure supplied air respirator
(TC19C or equivalent) for isocyanates.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium carbonate 471-34-1 ACGIH TWA: 10 mg/m3
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Trimethyl benzene 25551-13-7 ACGIH TWA: 25 ppm
(mixed isomers)
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
1,3,5-Trimethylbenzene 108-67-8 ACGIH TWA: 25 ppm
Xylene 1330-20-7 ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
OSHA PEL: 435 mg/m3
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : Gray
Odor : Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.13
% Volatile Weight : 16 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.Amines.Water or moisture.Alcohols.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Calcium carbonate, CAS-No.: 471-34-1
Acute oral toxicity (LD-50 oral) 6,450 mg/kg ( Rat )
Trimethyl benzene (mixed isomers), CAS-No.: 25551-13-7
Acute oral toxicity (LD-50 oral) 8,970 mg/kg ( Rat )
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 3,523 - 8,600 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 6,350 mg/l ( Rat )
2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l ( Rat )
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability)
This classification applies only to the material as it was originally produced.
Disposal Method : Subject to hazardous waste treatment, storage and disposal requirements under
RCRA. Dispose of in a contained chemical landfill in compliance with federal, state
and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Xylene 1330-20-7
2,4-Toluene diisocyanate 584-84-9
SARA 311/312 Hazards : Acute Health Hazard
Fire Hazard
OSHA Hazardous Components :
Calcium carbonate 471-34-1
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
1,3,5-Trimethylbenzene 108-67-8
Xylene 1330-20-7
2,4-Toluene diisocyanate 584-84-9
OSHA Status: Considered : Irritant
hazardous based on the Sensitizer
following criteria:
OSHA Flammability : II
Regulatory VOC (less water and : 184 g/l
exempt solvent)
VOC Method 310 : 16 %
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
U.S. State Regulations:
MASS RTK Components : Calcium carbonate 471-34-1
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
1,3,5-Trimethylbenzene 108-67-8
Xylene 1330-20-7
Penn RTK Components : Polyurethane Prepolymer NJ TSRN# 51721300-5684P
Aromatic petroleum distillates 64742-95-6
Calcium carbonate 471-34-1
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
1,3,5-Trimethylbenzene 108-67-8
Xylene 1330-20-7
NJ RTK Components : Polyurethane Prepolymer NJ TSRN# 51721300-5684P
Aromatic petroleum distillates 64742-95-6
Calcium carbonate 471-34-1
Trimethyl benzene (mixed isomers) 25551-13-7
Titanium dioxide 13463-67-7
Xylene 1330-20-7
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
584-84-9 2,4-Toluene diisocyanate
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information
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Material Safety Data Sheet
TREMLAR PTM
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
System
OSHA - Occupational Safety and Health Administration
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