MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION AND USE
PRODUCT IDENTIFICATION NUMBER (PIN):
PRODUCT IDENTIFIER
Ethyl Ether ET100X
PRODUCT USE
MANUFACTURERS NAME: SUPPLIERS NAME:
Xenex Labs XENEX LABORATORIES INC.
STREET ADDRESS: STREET ADDRESS:
2402 CANOE AVENUE
CITY: PROVINCE: CITY: PROVINCE:
COQUITLAM B.C.
POSTAL CODE: EMERGENCY TELEPHONE NO: POSTAL CODE: EMERGENCY TELEPHONE NO:
SPE100 V3K 6C2 (CHEMTREC) 1-800-424-9300
SECTION 2 - HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS
% CAS NUMBER LD50 / LC50 OF INGREDIENT
/ CHEMICAL FORMULA
(SPECIFY SPECIES) (SPECIFY ROUTE AND DOSE)
Ethyl Ether 100 60-29-7 RAT ORAL 1215mg/kg
C4H10O RAT VAPOR 73000ppm 2 hours
SECTION 3 - PHYSICAL DATA
PHYSICAL STATE AND APPEARANCE ODOR TASTE ODOR THRESHOLD (ppm)
Liquid (Clear Colorless. Volatile, mobile liquid Sweetish, Pungent, Ethereal Burning, Sweet 0.83ppm
MELTING POINT (C) BOILING POINT (C) VAPOR PRESSURE VAPOR DENSITY VOLATILITY
-116.3掳C (-177.3掳F) 34.6掳C (94.3掳F) 58.6kPa 2.56 Not Available
pH SPECIFIC GRAVITY COEFF. WATER/OIL DIST. DISPERSION PROPERTIES / SOLUBILITY
Not Available 0.7134 log(oil/water)=0.9 Soluble in Acetone. Partially soluble in cold water
SECTION 4 - FIRE AND EXPLOSION DATA
NO YES
FLAMMABILITY IF YES, UNDER WHAT CONDITIONS?
Flammable - Flammable liquid, soluble or dispersed in water.
Extremely flammable in presence of open flames and sparks, of heat.
Slightly flammable to flammable in presence of oxidizing materials, of acids.
Highly explosive in presence of open flames and sparks, of heat.
Slightly explosive in presence of oxidizing materials.
Highly flammable. Will be easily ignited by heat, sparks, and flames. Vapors may travel to source of ignition and flash
back. Most vapors are heavier than air.
Burns with Smokey greenish flame.
Violent reaction or ignition on contact with halogens (e.g., bromine, chlorine), interhalogens (e.g., iodine heptafluoride),
oxidants (e.g., silver perchlorate, nitrosyl perchlorate, nitryl perchlorate, chromyl chloride, fluorine nitrate, permanganic
acid, nitric acid, hydrogen peroxide, peroxodisulfuric acid, iodine (VII) oxide, sodium peroxide, ozone, and liquid air),
sulfur and sulfur compounds (e.g., sulfur when dried with peroxidized ether, sulfuryl chloride).
Vapors may form explosive mixtures with air. Vapor explosion hazard indoors, outdoors, or in sewers. Run off to sewer
may create a fire or explosion hazard. Containers may explode when heated. Tends to form explosive peroxides under
influence of light and air and evaporated to dryness.
Explosive reaction with boron triazide, bromine trifluoride, bromine pentafluoride, perchloric acid, uranyl nitrate + light,
wood pulp extracts + heat.
Only electrical equipment of explosion proof type (group C classification) is permitted to be operated in ether areas.
May explode when brought in contact with anhydrous nitric acid.
MEANS OF EXTINCTION
Flammable liquid, soluble or dispersed in water.
SMALL: Use DRY chemical powder.
LARGE: Use water spray, fog or foam. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or
explosion.
FLASHPOINT (C) AND METHOD FLAMMABLE LIMITS (% BY VOLUME) CRITICAL TEMPERATURE
CLOSED CUP: -45掳C (-49掳F). UPPER: 36% LOWER: 1.9% 192.7掳C (378.9掳F)
AUTOIGNITION TEMPERATURE (C) HAZARDOUS COMBUSTION PRODUCTS
180掳C (356掳F) (CO,CO2) Oxides of carbon.
MATERIAL SAFETY DATA SHEET
ET100X
PRODUCT IDENTIFIER
Ethyl Ether
SECTION 5 - REACTIVITY DATA
YES NO IF NO, UNDER WHICH CONDITIONS?
CHEMICAL STABILITY
The product is stable - Avoid Heat, Ignition sources, Incompatible materials, Light, Air
YES
NO
INCOMPATIBILITY WITH OTHER SUBSTANCES IF SO, WHICH ONES?
Highly reactive with oxidizing agents, acids.
REACTIVITY, AND UNDER WHAT CONDITIONS
Air and light sensitive. Hygroscopic.
Also incompatible with bromoazide, chlorine, chlorine trifluoride, chromic anhydride, chromyl chloride, lithium aluminum hydride, nitrosyl perchlorate, nitryl
perchlorate, ozone, perchloric acid, permanganated, sulfuric acid, potassium peroxide, sodium peroxide, triethyl aluminum trimethyl aluminum, bromine, iodine
heptafluoride, silver perchlorate, fluorine nitrate, permanganic acid, nitric acid, hydrogen peroxide, peroxodisulfuric acid, iodine (VII) oxide, peat soils, thiotr
perchlorate, sulfonyl chloride, sulfur, uranyl nitrate, acetyl peroxide, and wood pulp extracts.
Can react vigorously with acetyl peroxide, air, bromoazide, ClF3, CrO3, Cr(OCl)2, LiAlH2, NOClO4, O2, NClO2, (H2SO4 + permanganates), K2O2,
[(C2H5)3Al + air], [(CH3)3Al + air].
HAZARDOUS DECOMPOSITION PRODUCTS
WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE
WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO LEACH INTO GROUNDWATER.
WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS NOT EXPECTED TO BIODEGRADE.
WHEN RELEASED INTO WATER, THIS MATERIAL IS NOT EXPECTED TO BIODEGRADE.
WHEN RELEASED INTO WATER, THIS MATERIAL IS EXPECTED TO HAVE HALF-LIFE OF LESS THAN 1 DAY.
WHEN RELEASED INTO WATER, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE.
THIS MATERIAL IS NOT EXPECTED TO SIGNIFICANTLY BIOACCUMULATE.
THIS MATERIAL HAS A LOG OCTANOL-WATER PARTITION COEFFICIENT LESS THAN 3.0.
WHEN RELEASED INTO THE AIR, THIS MATERIAL IS EXPECTED TO BE READILY DEGRADED BY REACTION WITH PHOTOCHEMICALLY
PRODUCED HYDROXYL RADICAL
WHEN RELEASED INTO THE AIR, THIS MATERIAL IS NOT EXPECTED TO BE DEGRADED BY PHOTOLYSIS.
WHEN RELEASED INTO THE AIR, THIS MATERIAL IS EXPECTED TO HAVE HALF-LIFE BETWEEN 1 AND 10 DAYS.
Possible hazardous short term degradation products are not likely. However long term degradation products may arise. The products of degradation are less
toxic than the product itself.
SECTION 6 - TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY
INGESTION
INHALATION
SKIN CONTACT SKIN ABSORPTION EYE CONTACT
EFFECTS OF ACUTE EXPOSURE TO PRODUCT
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Skin: Causes skin irritation. It is not appreciably absorbed through intact skin.
Eyes: Causes eye irritation. Can cause slight , reversible eye injury from contact with liquid or vapor.
Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting
Inhalation: It is rapidly absorbed through lungs. Vapor mist causes irritation of the respiratory tract and mucous membranes.
Affects behavior, sense organs, peripheral and central nervous systems, liver and metabolism, cardiovascular system.
Symptoms may include excitement, drowsiness, headache, nausea, vomiting, paleness, decreased pulse and temperature, irregular respiration, coughing,
bronchodilation, increase in respiratory rate, increase in heart rate, excessive salivation, muscle relaxation, anesthetic effects, and possible kidney irritation or
injury, and temporarily abnormal liver function tests.
EFFECTS OF CHRONIC EXPOSURE TO PRODUCT
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.
The substance may be toxic to skin, central nervous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage.
Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Slightly hazardous in case of skin contact (permeator).
EXPOSURE LIMITS
TWA: 400 (ppm) from OSHA (PEL) [United States]
TWA: 400 STEL: 500 CEIL: 500 (ppm) from ACGIH (TLV) [United States]
TWA: 1200 STEL: 1520 CEIL: 1500 (mg/m3) from ACGIH (TLV) [United States]
STEL: 500 (ppm) [Australia]
TWA: 1200 (mg/m3) from OSHA (PEL) [United States]
Consult local authorities for acceptable exposure limits.
SYNERGISTIC PRODUCTS
IRRITANCY OF PRODUCT SENSITIZATION OF PRODUCT
Yes Not Available Not Available
REPRODUCTIVE TOXICITY MUTAGENICITY
TERATOGENICITY CARCINOGENICITY
Not Available Not Available As Specified Not Available
MATERIAL SAFETY DATA SHEET
ET100X
PRODUCT IDENTIFIER
Ethyl Ether
SECTION 7 - PREVENTATIVE MEASURE
PERSONAL PROTECTIVE EQUIPMENT
GLOVES (SPECIFY) RESPIRATOR (SPECIFY) EYE (SPECIFY)
Yes ( impervious ) Approved / Certified respirator Safety goggles, face shield
FOOTWEAR (SPECIFY) CLOTHING (SPECIFY) OTHER (SPECIFY)
No Coveralls / Lab coat Eyewash equipment nearby
ENGINEERING CONTROLS (SPECIFY eg. VENTILATION, ENCLOSED PROCESS)
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.
LEAK AND SPILL PROCEDURE
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
WASTE DISPOSAL
According to local, provincial, and federal regulations.
HANDLING PROCEDURES AND EQUIPMENT
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue
under a fume hood. Ground all equipment containing material. Do not breathe gas/fumes/ vapor/spray. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek
medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles.
STORAGE REQUIREMENTS
Keep container tightly closed. Keep container in a cool, dry, well-ventilated area. Container may be hazardous when
empty since they retain product residues observe all warnings and precautions listed for the product.
SPECIAL SHIPPING INFORMATION
DOT CLASS 3: Flammable liquid.
UNNA: 1155: Diethyl ether PG: I
WHMIS (Canada) CLASS B-2: Flammable liquid with a flash point lower than 37.8掳C (100掳F).
SECTION 8 - FIRST AID MEASURES
SPECIFIC MEASURES
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
SKIN
emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
EYES
water for at least 15 minutes. Get medical attention
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
INHALATION
oxygen. Get medical attention if symptoms appear.
INGESTION Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
IF IRRITATION PERSISTS AND IN ALL OTHER CASES, GET IMMEDIATE MEDICAL ATTENTION.
SECTION 9 - PREPARATION DATE OF M.S.D.S.
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packa
If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the us
responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical
data judged to be reliable, Xenex Laboratories Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
PREPARED BY (GROUP, DEPARTMENT, ETC.) PHONE NUMBER DATE:
CONTROL DEPARTMENT (604) 552 3031 July 24 2008
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