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MSDS 
:
 n-Methylbenzylamine, 97%
CAS 
:
 103-67-3
SYNONYMS 
:
 N-Methylbenzylamine
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 103-67-3 |N-Benzylmethylamine | 97.0 | 203-133-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Causes burns.The toxicological properties of this material have not
been fully investigated.

Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found. Amines can cause eye irritation.
Skin:
No information regarding skin irritation and other potential effects
was found. Amines have been known to cause skin irritation and
sensitization.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe irritation of the respiratory tract with possible
burns.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 103-67-3:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 184.0 - 189.0 deg C @ 760.00m
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 380 deg C ( 716.00 deg F)
Flash Point: 77 deg C ( 170.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 65 g/l (20 c)
Specific Gravity/Density: .9390g/cm3
Molecular Formula: C8H11N
Molecular Weight: 121.18

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 103-67-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-Benzylmethylamine -
Not listed by ACGIH, IARC, or NTP.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 103-67-3: 1
Canada
CAS# 103-67-3 is listed on Canada's NDSL List.
CAS# 103-67-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 103-67-3 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 1/30/1998 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
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Triphenylmethyl chloride 76-83-5
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Trans-2-Aminocyclohexanol Hydrochloride, 99% 5456-63-3
Benzoin methyl ether, 96% (tlc) 3524-62-7
Heptanoic Acid, 98% 111-14-8
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane 110-54-3
Diisobutylaluminum hydride (1.0M solution in toluene) 108-88-3
1-Phenyltridecane 123-02-4
Glycolic Acid, 99% 79-14-1
Phenylacetyl chloride, 98% 103-80-0
Rubidium Hydroxide, 99%, 50 wt% Solution In Water 1310-82-3
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC) 987-65-5
TRICHLOROACETYL CHLORIDE, 99% 76-02-8
Silver Carbonate, 99% 534-16-7
Tetrabutylammonium Hydrogen Sulfate, 98% 32503-27-8
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Poly(n-vinylcarbazole), secondary standard 25067-59-8
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Pinacolone, 96% (gc) 75-97-8
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2-Naphthol, 98% 135-19-3
2-Naphthol (techn) 135-19-3
3-Bromopropionic Acid, 97% 590-92-1
4'-Chloroacetophenone, 97% 99-91-2
Ethyl chloroformate, 99% 541-41-3
6-Chloro-1-Hexanol, 95% 2009-83-8
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT 592-57-4
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract. 2903-34-6
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3,5-Dimethylphenol, 98% 108-68-9
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Cyanogen Bromide, 97% 506-68-3
Tin, Powder, 99.9999% 7440-31-5

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