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MSDS 
:
 2-Naphthol, 98%
CAS 
:
 135-19-3
SYNONYMS 
:
 2-Hydroxynaphthalene; beta-naphthol
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 135-19-3 |2-NAPHTHOL | 98 | 205-182-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.Highly toxic.Light sensitive.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Aspiration hazard. May cause irritation of the
digestive tract.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Chronic:
Chronic inhalation may cause effects similar to those of acute
inhalation.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Do not
ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Do not store in direct sunlight. Keep container closed when not in
use. Store in a tightly closed container. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep away from strong bases. Material
darkens in color on storage.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits
CAS# 135-19-3:

Russia: 0.1 mg/m3 TWA

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: slightly brown
Odor: Slight phenolic
pH: Not available.
Vapor Pressure: 10 mm Hg @145.5
Viscosity: Not available.
Boiling Point: 285 - 286 deg C @ 760.00mm Hg
Freezing/Melting Point: 122 - 123 deg C
Autoignition Temperature: Not available.
Flash Point: 400 deg C ( 752.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 400 deg C
Solubility in water: 1 G/L WATER (20C)
Specific Gravity/Density:
Molecular Formula: C10H8O
Molecular Weight: 144.17

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases - acid chlorides - acid
anhydrides - concentrated sulfuric and nitric acids - antipyrine -
camphor - phenol - ferric salts - menthol - urethane - potassium
permanganate.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, toxic fumes of sodium oxide.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 135-19-3: QL2975000
LD50/LC50:
CAS# 135-19-3: Draize test, rabbit, eye: 100 mg Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >770
mg/m3/1H; Oral, mouse: LD50 = 98 mg/kg; Oral, rabbit: LD50 = 5400
mg/kg; Oral, rat: LD50 = 1960 mg/kg; Oral, rat: LD50 = 1980 mg/kg;
Skin, rabbit: LD50 = >10 gm/kg.
Carcinogenicity:
2-NAPHTHOL -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish toxicity:
LC50 fathead minnow 3.5 mg/L/96H
LC50 rainbow trout
0.12 mg/L/27day
Invertebrate toxicity:
LC50 Daphnia magna 3.5
mg/L/48H
EC50 Selenastrum capricornutum 19 mg/L/4H
EC50
Photobacterium phosphoreum 0.275 ppm/5-30 min Microtox test (The
Dictionary of Substances and their Effects, 1992).

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 135-19-3: 2
Canada
CAS# 135-19-3 is listed on Canada's DSL List.
CAS# 135-19-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 135-19-3 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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