**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 32503-27-8 |Tetrabutylammonium hydrogen sulfate | 98 | 251-068-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Hygroscopic (absorbs moisture from the air).The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid breathing dust, vapor, mist, or
gas. Avoid contact with eyes, skin, and clothing.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 32503-27-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 169.00 - 171.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water: >50% w/w
Specific Gravity/Density:
Molecular Formula: C16H37NO4S
Molecular Weight: 339.53
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 32503-27-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrabutylammonium hydrogen sulfate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
BOD7: 0.93 gO2/g; COD: 1.70 gO2/g
Microtox(EC50, 15 min.): 170 mg/ml
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 32503-27-8: No information available.
Canada
CAS# 32503-27-8 is listed on Canada's DSL List.
CAS# 32503-27-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 32503-27-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/23/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zincon, monosodium salt
| 62625-22-3 |
|
Propylamine, 98%
| 107-10-8 |
|
Phenylmercuric Acetate, 98.0-100.5%
| 62-38-4 |
|
Kaolin
| 1332-58-7 |
|
Triethyl orthoformate, 98%
| 122-51-0 |
|
n-Methylbenzylamine, 97%
| 103-67-3 |
|
Triphenylmethyl chloride
| 76-83-5 |
|
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis)
| 6358-69-6 |
|
Trans-2-Aminocyclohexanol Hydrochloride, 99%
| 5456-63-3 |
|
Benzoin methyl ether, 96% (tlc)
| 3524-62-7 |
|
Heptanoic Acid, 98%
| 111-14-8 |
|
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane
| 110-54-3 |
|
Diisobutylaluminum hydride (1.0M solution in toluene)
| 108-88-3 |
|
1-Phenyltridecane
| 123-02-4 |
|
Glycolic Acid, 99%
| 79-14-1 |
|
Phenylacetyl chloride, 98%
| 103-80-0 |
|
Rubidium Hydroxide, 99%, 50 wt% Solution In Water
| 1310-82-3 |
|
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC)
| 987-65-5 |
|
TRICHLOROACETYL CHLORIDE, 99%
| 76-02-8 |
|
Silver Carbonate, 99%
| 534-16-7 |
|
Tetrabutylammonium Hydrogen Sulfate, 98%
| 32503-27-8 |
|
Adipoyl Chloride, 99+% (Titr.)
| 111-50-2 |
|
Benzylamine, 99%
| 100-46-9 |
|
1,3-Cyclopentanedione, 97%
| 3859-41-4 |
|
Poly(n-vinylcarbazole), secondary standard
| 25067-59-8 |
|
Nonanoic Acid, Tech., 90%
| 112-05-0 |
|
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97%
| 403-40-7 |
|
Selenium(iv) oxide, p.a.
| 7446-08-4 |
|
Selenium(IV) oxide
| 7446-08-4 |
|
4'-Nitroacetanilide
| 104-04-1 |
|
Manganese(II) chloride, anhydrous
| 7773-01-5 |
|
Pinacolone, 96% (gc)
| 75-97-8 |
|
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis
| 16069-36-6 |
|
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+%
| 15128-66-2 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98%
| 525-05-3 |
|
2-Naphthol, 98%
| 135-19-3 |
|
2-Naphthol (techn)
| 135-19-3 |
|
3-Bromopropionic Acid, 97%
| 590-92-1 |
|
4'-Chloroacetophenone, 97%
| 99-91-2 |
|
Ethyl chloroformate, 99%
| 541-41-3 |
|
6-Chloro-1-Hexanol, 95%
| 2009-83-8 |
|
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT
| 592-57-4 |
|
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract.
| 2903-34-6 |
|
Camphene, 80%
| 79-92-5 |
|
N,N'-Methylenebisacrylamide, 96%
| 110-26-9 |
|
3-Chlorobenzoic Acid, 99+%
| 535-80-8 |
|
3,5-Dimethylphenol, 98%
| 108-68-9 |
|
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
Cyanogen Bromide, 97%
| 506-68-3 |
|
Tin, Powder, 99.9999%
| 7440-31-5 |
|
|