**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 103-80-0 |Phenylacetyl chloride | 98 | 203-146-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. The toxicological properties of this
substance have not been fully investigated.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. The
toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will react
with water to form toxic and corrosive fumes. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. Do NOT use straight streams of water. Most foams
will react with the material and release corrosive/toxic gases. Use
dry chemical or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation. Do not get water inside
containers. Cover with dry earth, dry sand, or other non-combustible
material followed with plastic sheet to minimize spreading and
contact with water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not breathe dust, vapor, mist, or gas. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Do not allow contact with water. Use only
in a chemical fume hood. Discard contaminated shoes. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 103-80-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow to light pink
Odor: pungent odor
pH: Not available.
Vapor Pressure: 0.199 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 94-95 deg C @ 12 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.1690 g/cm3
Molecular Formula: C8H7ClO
Molecular Weight: 154.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive. Forms hydrochloric acid with water.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Alcohols, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 103-80-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Phenylacetyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENYLACETYL CHLORIDE
Hazard Class: 8
UN Number: 2577
Packing Group: II
IMO
Shipping Name: PHENYLACETYL CHLORIDE
Hazard Class: 8
UN Number: 2577
Packing Group: II
RID/ADR
Shipping Name: PHENYLACETYL CHLORIDE
Hazard Class: 8
UN Number: 2577
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 103-80-0: 1
Canada
CAS# 103-80-0 is listed on Canada's DSL List.
CAS# 103-80-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 103-80-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/23/1999 Revision #3 Date: 10/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zincon, monosodium salt
| 62625-22-3 |
|
Propylamine, 98%
| 107-10-8 |
|
Phenylmercuric Acetate, 98.0-100.5%
| 62-38-4 |
|
Kaolin
| 1332-58-7 |
|
Triethyl orthoformate, 98%
| 122-51-0 |
|
n-Methylbenzylamine, 97%
| 103-67-3 |
|
Triphenylmethyl chloride
| 76-83-5 |
|
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis)
| 6358-69-6 |
|
Trans-2-Aminocyclohexanol Hydrochloride, 99%
| 5456-63-3 |
|
Benzoin methyl ether, 96% (tlc)
| 3524-62-7 |
|
Heptanoic Acid, 98%
| 111-14-8 |
|
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane
| 110-54-3 |
|
Diisobutylaluminum hydride (1.0M solution in toluene)
| 108-88-3 |
|
1-Phenyltridecane
| 123-02-4 |
|
Glycolic Acid, 99%
| 79-14-1 |
|
Phenylacetyl chloride, 98%
| 103-80-0 |
|
Rubidium Hydroxide, 99%, 50 wt% Solution In Water
| 1310-82-3 |
|
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC)
| 987-65-5 |
|
TRICHLOROACETYL CHLORIDE, 99%
| 76-02-8 |
|
Silver Carbonate, 99%
| 534-16-7 |
|
Tetrabutylammonium Hydrogen Sulfate, 98%
| 32503-27-8 |
|
Adipoyl Chloride, 99+% (Titr.)
| 111-50-2 |
|
Benzylamine, 99%
| 100-46-9 |
|
1,3-Cyclopentanedione, 97%
| 3859-41-4 |
|
Poly(n-vinylcarbazole), secondary standard
| 25067-59-8 |
|
Nonanoic Acid, Tech., 90%
| 112-05-0 |
|
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97%
| 403-40-7 |
|
Selenium(iv) oxide, p.a.
| 7446-08-4 |
|
Selenium(IV) oxide
| 7446-08-4 |
|
4'-Nitroacetanilide
| 104-04-1 |
|
Manganese(II) chloride, anhydrous
| 7773-01-5 |
|
Pinacolone, 96% (gc)
| 75-97-8 |
|
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis
| 16069-36-6 |
|
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+%
| 15128-66-2 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98%
| 525-05-3 |
|
2-Naphthol, 98%
| 135-19-3 |
|
2-Naphthol (techn)
| 135-19-3 |
|
3-Bromopropionic Acid, 97%
| 590-92-1 |
|
4'-Chloroacetophenone, 97%
| 99-91-2 |
|
Ethyl chloroformate, 99%
| 541-41-3 |
|
6-Chloro-1-Hexanol, 95%
| 2009-83-8 |
|
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT
| 592-57-4 |
|
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract.
| 2903-34-6 |
|
Camphene, 80%
| 79-92-5 |
|
N,N'-Methylenebisacrylamide, 96%
| 110-26-9 |
|
3-Chlorobenzoic Acid, 99+%
| 535-80-8 |
|
3,5-Dimethylphenol, 98%
| 108-68-9 |
|
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
Cyanogen Bromide, 97%
| 506-68-3 |
|
Tin, Powder, 99.9999%
| 7440-31-5 |
|
|