**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 76-02-8 |TRICHLOROACETYL CHLORIDE, 99% | 99 | 200-926-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 22 26 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Very toxic by inhalation. Causes severe
burns.Mutagen.Moisture sensitive.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 76-02-8:
Russia: 0.1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Color: Clear colourless liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.33 hPa @ 51 C
Viscosity: Not available.
Boiling Point: 114 - 116 deg C @ 760.00mm Hg
Freezing/Melting Point: -57 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.6290g/cm3
Molecular Formula: C2Cl4O
Molecular Weight: 181.83
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Water, oxidizing agents, strong bases, alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 76-02-8: AO7140000
LD50/LC50:
CAS# 76-02-8: Inhalation, mouse: LC50 = 445 mg/m3; Inhalation, rat:
LC50 = 475 mg/m3/4H; Oral, rat: LD50 = 600 mg/kg.
Carcinogenicity:
TRICHLOROACETYL CHLORIDE, 99% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRICHLOROACETYL CHLORIDE
(forbidden to ship via passenger or cargo air)
Hazard Class: 8
UN Number: 2442
Packing Group:
IMO
Shipping Name: TRICHLOROACETYL CHLORIDE
Hazard Class: 8
UN Number: 2442
Packing Group: II
RID/ADR
Shipping Name: TRICHLOROACETYL CHLORIDE
Hazard Class: 8
UN Number: 2442
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 22 Harmful if swallowed.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 76-02-8: 2
Canada
CAS# 76-02-8 is listed on Canada's DSL List.
CAS# 76-02-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 76-02-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/03/1998 Revision #2 Date: 10/08/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zincon, monosodium salt
| 62625-22-3 |
|
Propylamine, 98%
| 107-10-8 |
|
Phenylmercuric Acetate, 98.0-100.5%
| 62-38-4 |
|
Kaolin
| 1332-58-7 |
|
Triethyl orthoformate, 98%
| 122-51-0 |
|
n-Methylbenzylamine, 97%
| 103-67-3 |
|
Triphenylmethyl chloride
| 76-83-5 |
|
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis)
| 6358-69-6 |
|
Trans-2-Aminocyclohexanol Hydrochloride, 99%
| 5456-63-3 |
|
Benzoin methyl ether, 96% (tlc)
| 3524-62-7 |
|
Heptanoic Acid, 98%
| 111-14-8 |
|
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane
| 110-54-3 |
|
Diisobutylaluminum hydride (1.0M solution in toluene)
| 108-88-3 |
|
1-Phenyltridecane
| 123-02-4 |
|
Glycolic Acid, 99%
| 79-14-1 |
|
Phenylacetyl chloride, 98%
| 103-80-0 |
|
Rubidium Hydroxide, 99%, 50 wt% Solution In Water
| 1310-82-3 |
|
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC)
| 987-65-5 |
|
TRICHLOROACETYL CHLORIDE, 99%
| 76-02-8 |
|
Silver Carbonate, 99%
| 534-16-7 |
|
Tetrabutylammonium Hydrogen Sulfate, 98%
| 32503-27-8 |
|
Adipoyl Chloride, 99+% (Titr.)
| 111-50-2 |
|
Benzylamine, 99%
| 100-46-9 |
|
1,3-Cyclopentanedione, 97%
| 3859-41-4 |
|
Poly(n-vinylcarbazole), secondary standard
| 25067-59-8 |
|
Nonanoic Acid, Tech., 90%
| 112-05-0 |
|
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97%
| 403-40-7 |
|
Selenium(iv) oxide, p.a.
| 7446-08-4 |
|
Selenium(IV) oxide
| 7446-08-4 |
|
4'-Nitroacetanilide
| 104-04-1 |
|
Manganese(II) chloride, anhydrous
| 7773-01-5 |
|
Pinacolone, 96% (gc)
| 75-97-8 |
|
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis
| 16069-36-6 |
|
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+%
| 15128-66-2 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98%
| 525-05-3 |
|
2-Naphthol, 98%
| 135-19-3 |
|
2-Naphthol (techn)
| 135-19-3 |
|
3-Bromopropionic Acid, 97%
| 590-92-1 |
|
4'-Chloroacetophenone, 97%
| 99-91-2 |
|
Ethyl chloroformate, 99%
| 541-41-3 |
|
6-Chloro-1-Hexanol, 95%
| 2009-83-8 |
|
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT
| 592-57-4 |
|
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract.
| 2903-34-6 |
|
Camphene, 80%
| 79-92-5 |
|
N,N'-Methylenebisacrylamide, 96%
| 110-26-9 |
|
3-Chlorobenzoic Acid, 99+%
| 535-80-8 |
|
3,5-Dimethylphenol, 98%
| 108-68-9 |
|
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
Cyanogen Bromide, 97%
| 506-68-3 |
|
Tin, Powder, 99.9999%
| 7440-31-5 |
|
|