**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104-04-1 |Acetamide, N-(4-Nitrophenyl)- | 100 | 203-169-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Wash clothing before reuse.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 104-04-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 215.00 - 217.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H8N2O3
Molecular Weight: 180.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104-04-1: AE5075000
LD50/LC50:
Not available.
Carcinogenicity:
Acetamide, N-(4-Nitrophenyl)- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 104-04-1: 2
Canada
CAS# 104-04-1 is listed on Canada's DSL List.
CAS# 104-04-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-04-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/07/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zincon, monosodium salt
| 62625-22-3 |
|
Propylamine, 98%
| 107-10-8 |
|
Phenylmercuric Acetate, 98.0-100.5%
| 62-38-4 |
|
Kaolin
| 1332-58-7 |
|
Triethyl orthoformate, 98%
| 122-51-0 |
|
n-Methylbenzylamine, 97%
| 103-67-3 |
|
Triphenylmethyl chloride
| 76-83-5 |
|
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis)
| 6358-69-6 |
|
Trans-2-Aminocyclohexanol Hydrochloride, 99%
| 5456-63-3 |
|
Benzoin methyl ether, 96% (tlc)
| 3524-62-7 |
|
Heptanoic Acid, 98%
| 111-14-8 |
|
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane
| 110-54-3 |
|
Diisobutylaluminum hydride (1.0M solution in toluene)
| 108-88-3 |
|
1-Phenyltridecane
| 123-02-4 |
|
Glycolic Acid, 99%
| 79-14-1 |
|
Phenylacetyl chloride, 98%
| 103-80-0 |
|
Rubidium Hydroxide, 99%, 50 wt% Solution In Water
| 1310-82-3 |
|
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC)
| 987-65-5 |
|
TRICHLOROACETYL CHLORIDE, 99%
| 76-02-8 |
|
Silver Carbonate, 99%
| 534-16-7 |
|
Tetrabutylammonium Hydrogen Sulfate, 98%
| 32503-27-8 |
|
Adipoyl Chloride, 99+% (Titr.)
| 111-50-2 |
|
Benzylamine, 99%
| 100-46-9 |
|
1,3-Cyclopentanedione, 97%
| 3859-41-4 |
|
Poly(n-vinylcarbazole), secondary standard
| 25067-59-8 |
|
Nonanoic Acid, Tech., 90%
| 112-05-0 |
|
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97%
| 403-40-7 |
|
Selenium(iv) oxide, p.a.
| 7446-08-4 |
|
Selenium(IV) oxide
| 7446-08-4 |
|
4'-Nitroacetanilide
| 104-04-1 |
|
Manganese(II) chloride, anhydrous
| 7773-01-5 |
|
Pinacolone, 96% (gc)
| 75-97-8 |
|
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis
| 16069-36-6 |
|
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+%
| 15128-66-2 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98%
| 525-05-3 |
|
2-Naphthol, 98%
| 135-19-3 |
|
2-Naphthol (techn)
| 135-19-3 |
|
3-Bromopropionic Acid, 97%
| 590-92-1 |
|
4'-Chloroacetophenone, 97%
| 99-91-2 |
|
Ethyl chloroformate, 99%
| 541-41-3 |
|
6-Chloro-1-Hexanol, 95%
| 2009-83-8 |
|
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT
| 592-57-4 |
|
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract.
| 2903-34-6 |
|
Camphene, 80%
| 79-92-5 |
|
N,N'-Methylenebisacrylamide, 96%
| 110-26-9 |
|
3-Chlorobenzoic Acid, 99+%
| 535-80-8 |
|
3,5-Dimethylphenol, 98%
| 108-68-9 |
|
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
Cyanogen Bromide, 97%
| 506-68-3 |
|
Tin, Powder, 99.9999%
| 7440-31-5 |
|
|