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MSDS 
:
 Benzoin methyl ether, 96% (tlc)
CAS 
:
 3524-62-7
SYNONYMS 
:
 2-Methoxy-2-phenylacetophenone
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3524-62-7 |Benzoin methyl ether, 97% | | 222-538-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful if swallowed.

Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 3524-62-7:


Personal Protective Equipment

Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Powder
Color: white to pale yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 188.0 - 189.0 deg C @ 15.00mm
Freezing/Melting Point: 47.50 - 48.50 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C15H14O2
Molecular Weight: 226.27

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 3524-62-7: AM9350000
LD50/LC50:
CAS# 3524-62-7: Oral, mouse: LD50 = 300 mg/kg; Oral, mouse: LD50 =
2750 mg/kg; Oral, rat: LD50 = 7560 mg/kg.
Carcinogenicity:
Benzoin methyl ether, 97% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 3524-62-7: No information available.
Canada
CAS# 3524-62-7 is listed on Canada's NDSL List.
CAS# 3524-62-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3524-62-7 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
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Phenylmercuric Acetate, 98.0-100.5% 62-38-4
Kaolin 1332-58-7
Triethyl orthoformate, 98% 122-51-0
n-Methylbenzylamine, 97% 103-67-3
Triphenylmethyl chloride 76-83-5
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis) 6358-69-6
Trans-2-Aminocyclohexanol Hydrochloride, 99% 5456-63-3
Benzoin methyl ether, 96% (tlc) 3524-62-7
Heptanoic Acid, 98% 111-14-8
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane 110-54-3
Diisobutylaluminum hydride (1.0M solution in toluene) 108-88-3
1-Phenyltridecane 123-02-4
Glycolic Acid, 99% 79-14-1
Phenylacetyl chloride, 98% 103-80-0
Rubidium Hydroxide, 99%, 50 wt% Solution In Water 1310-82-3
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC) 987-65-5
TRICHLOROACETYL CHLORIDE, 99% 76-02-8
Silver Carbonate, 99% 534-16-7
Tetrabutylammonium Hydrogen Sulfate, 98% 32503-27-8
Adipoyl Chloride, 99+% (Titr.) 111-50-2
Benzylamine, 99% 100-46-9
1,3-Cyclopentanedione, 97% 3859-41-4
Poly(n-vinylcarbazole), secondary standard 25067-59-8
Nonanoic Acid, Tech., 90% 112-05-0
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97% 403-40-7
Selenium(iv) oxide, p.a. 7446-08-4
Selenium(IV) oxide 7446-08-4
4'-Nitroacetanilide 104-04-1
Manganese(II) chloride, anhydrous 7773-01-5
Pinacolone, 96% (gc) 75-97-8
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis 16069-36-6
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+% 15128-66-2
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98% 525-05-3
2-Naphthol, 98% 135-19-3
2-Naphthol (techn) 135-19-3
3-Bromopropionic Acid, 97% 590-92-1
4'-Chloroacetophenone, 97% 99-91-2
Ethyl chloroformate, 99% 541-41-3
6-Chloro-1-Hexanol, 95% 2009-83-8
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT 592-57-4
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract. 2903-34-6
Camphene, 80% 79-92-5
N,N'-Methylenebisacrylamide, 96% 110-26-9
3-Chlorobenzoic Acid, 99+% 535-80-8
3,5-Dimethylphenol, 98% 108-68-9
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol 98-29-3
Cyanogen Bromide, 97% 506-68-3
Tin, Powder, 99.9999% 7440-31-5

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