Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
Revision Date: 06/30/2006
CRABGRASS KILLER READY-TO-SPRAY
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
BAYER ADVANCED ALL-IN-ONE LAWN WEED & CRABGRASS KILLER
Product Name
READY-TO-SPRAY
102000015602
MSDS Number
2217-894-72155
EPA Registration No.
Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-800-331-2867
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
2,4-D, dimethylamine salt 2008-39-1 4.85
Quinclorac 84087-01-4 1.61
Dicamba, dimethylamine salt 2300-66-5 0.45
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Caution! Harmful if swallowed. Moderate eye irritation. Avoid contact with skin,
Emergency Overview
eyes and clothing. Avoid breathing spray mist.
opaque liquid
Physical State
mild sweet
Odor
brown to black
Appearance
Skin contact, Inhalation, Ingestion
Routes of Exposure
Immediate Effects
Moderate eye irritation. Do not get in eyes.
Eye
Moderate skin irritation. Harmful if absorbed through skin. Avoid contact with skin
Skin
and clothing.
Page 1 of 7 Bayer Environmental Science
A Business Group of Bayer
CropScience
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
Harmful if swallowed. Do not take internally.
Ingestion
Irritation of mucous membranes. Mists may cause respiratory tract irritation,
Inhalation
coughing, a burning sensation. Harmful if inhaled. Avoid breathing spray mist.
This product contains ingredients that are considered to be probable or
Chronic or Delayed
suspected human carcinogens (see Section 11 - Chronic).
Long-Term
Skin contact may aggravate existing skin disease. Individuals with allergic history
Medical Conditions
or pre-existing dermatitis should use extra care in handling this product.
Aggravated by Exposure
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a physician or poison control center immediately.
Wash off immediately with plenty of water for at least 15 minutes. Take off
Skin
contaminated clothing and shoes immediately. Call a physician or poison control
center immediately.
Call a physician or poison control center immediately. Rinse out mouth and give
Ingestion
water in small sips to drink. DO NOT induce vomiting unless directed to do so by
a physician or poison control center. Never give anything by mouth to an
unconscious person. Do not leave victim unattended.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
Inhalation may provoke the following symptoms:
Signs and
burning sensation
Symptoms
discomfort in the chest
cough
dizziness
Ingestion may provoke the following symptoms:
vomiting
discomfort in the chest
abdominal pain
diarrhoea
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
Page 2 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
SECTION 5. FIRE FIGHTING MEASURES
54.5 掳C / 130.1 掳F
Flash Point
Test type: closed cup
In case of fire the evolution of dangerous gases is possible.
Fire and Explosion
Hazards
foam, carbon dioxide (CO2), dry chemical, water
Suitable Extinguishing
Media
Keep out of smoke. Fight fire from upwind position. Cool closed containers
Fire Fighting
exposed to fire with water spray. Dike area to prevent runoff and contamination
Instructions
of water sources. Inform authorities at once if material enters sewers or
watercourses. Equipment or materials involved in pesticide fires may become
contaminated.
Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled
Personal Precautions
product or contaminated surfaces.
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary
Methods for Cleaning Up
absorbent material). Keep in suitable, closed containers for disposal. Clean
contaminated floors and objects thoroughly, observing environmental
regulations.
Use personal protective equipment. Do not allow product to enter streams,
Additional Advice
sewers or other waterways.
SECTION 7. HANDLING AND STORAGE
Handle and open container in a manner as to prevent spillage.
Handling Procedures
Do not contaminate water, food, or feed by storage or disposal. Store in original
Storing Procedures
container and out of the reach of children, preferably in a locked storage area.
Do not freeze.
Wash hands thoroughly with soap and water after handling and before eating,
Work/Hygienic
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.
Procedures
Page 3 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
Take off contaminated clothing and shoes immediately. Then wash thoroughly
and put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after handling this
product. Before removing gloves clean them with soap and water. As soon as
practical, wash thoroughly and change into clean clothing.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Follow all label instructions. Train employees in safe use of the product.
General Protection
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such
instructions for washables, use detergent and warm/tepid water. Keep and wash
PPE separately from other laundry.
Ensure adequate ventilation. Use with local exhaust ventilation.
Engineering Controls
tightly fitting safety goggles
Eye/Face Protection
Chemical resistant nitrile rubber gloves
Hand Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Body Protection
When respirators are required, select NIOSH approved equipment based on
Respiratory Protection
actual or potential airborne concentrations and in accordance with the
appropriate regulatory standards and/or Industry recommendations.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
brown to black
Appearance
opaque liquid
Physical State
mild sweet
Odor
7.5 - 8.5 (100 %)
pH
2.266 kPa / 17 mm Hg at 20 掳C
Vapor Pressure
ca. 1.02 g/cm鲁 at 20 掳C
Density
100 掳C / 212 掳F
Boiling Point
< 1.7 掳C / 35.1 掳F
Melting / Freezing Point
Page 4 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
SECTION 10. STABILITY AND REACTIVITY
Stable under normal conditions.
Chemical Stability
acids
Incompatibility
In case of fire hazardous decomposition products may be produced such as:
Hazardous
hydrogen chloride (HCl)
Decomposition Products
nitrogen oxides (NOx)
Carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
Mild eye irritation.
Eye Irritation
Assessment Carcinogenicity
ACGIH
2,4-D, dimethylamine salt 2008-39-1 Group A4
NTP
None.
IARC
None.
OSHA
None.
SECTION 12. ECOLOGICAL INFORMATION
Toxic to aquatic invertebrates. Drift or runoff may adversely affect aquatic
Environmental
invertebrates and non-target plants. Do not apply directly to water, to areas
Precautions
where surface water is present or to intertidal areas below the mean high water
mark. Do not contaminate surface or ground water by cleaning equipment or
disposal of wastes, including equipment wash water. Apply this product as
specified on the label.
Page 5 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
SECTION 13. DISPOSAL CONSIDERATIONS
Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide,
General Disposal
spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be
Guidance
disposed of by use according to label instructions, contact your State Pesticide
or Environmental Control Agency, or the Hazardous Waste representative at the
nearest EPA Regional Office for guidance.
Do not re-use empty containers. Triple rinse containers. Then offer for recycling
Container Disposal
or reconditioning or puncture and dispose of in a sanitary landfill or incineration,
or if allowed by State and Local authorities, by burning. If burned, stay out of
smoke.
The RCRA Classifications may be on the individual component(s) and not
RCRA Classification:
necessarily on the product as a whole.
2008-39-1 2,4-D, dimethylamine salt
US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous
Wastes and Appendix VIII Hazardous Constituents (40 CFR 261): U240
2008-39-1 2,4-D, dimethylamine salt
US. EPA Resource Conservation and Recovery Act (RCRA) U List of Hazardous Wastes (40
CFR 261.33(f) and 40 CFR 302 [CERCLA]): U240
SECTION 14. TRANSPORT INFORMATION
TRANSPORTATION CLASSIFICATION:
Not regulated for Domestic Surface Shipment
FREIGHT CLASSIFICATION:
Compounds, Tree or WeedKilling, N.O.I., other than poison, Having a density of
greater than 20 LBS. per cubic foot
SECTION 15. REGULATORY INFORMATION
2217-894-72155
EPA Registration No.
US Federal Regulations
TSCA list
None.
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
Page 6 of 7
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000015602
MSDS Version 1.0
BAYER ADVANCED ALL-IN-ONE LAWN WEED &
CRABGRASS KILLER READY-TO-SPRAY
None.
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer.
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
2,4-D, dimethylamine salt 2008-39-1 CT
Canadian Regulations
Canadian Domestic Substance List
Quinclorac 84087-01-4
Environmental
CERCLA
2,4-D, dimethylamine salt 2008-39-1 100 lbs
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
2,4-D, dimethylamine salt 2008-39-1
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 2 Flammability - 1 Reactivity - 0 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: New Material Safety Data Sheet.
Revision Date: 06/30/2006
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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