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MSDS Material Safety Data Sheet
CAS

16672-87-0
111-76-2

File Name: bayercropscience_co_uk---Cerone.asp
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 1/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Product information
Trade name CERONE
Product code (UVP) 05927242
Usage growth regulator
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain

Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature
Soluble concentrate (SL)
Ethephon 480 g/l SL
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Ethephon 16672-87-0 C R20/21, R34, 39.30
240-718-3 R52/53
2-Butoxyethanol 111-76-2 Xn R20/21/22, >= 1.00 - <= 5.00
203-905-0 R36/38


3. HAZARDS IDENTIFICATION

Risk advice to man and the environment
Risk of serious damage to eyes.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


4. FIRST AID MEASURES
General advice
Remove contaminated clothing immediately and dispose of safely.
Skin contact
Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison
control center immediately. Take off contaminated clothing and shoes immediately.
Eye contact
Call a physician or poison control center immediately. In case of eye contact, remove contact
lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 2/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

Ingestion
Rinse out mouth and give water in small sips to drink. Call a physician or poison control center
immediately. Do not induce vomiting. Keep at rest.
Notes to Physician
Symptoms
Local:, severe irritation, sensitising effects
Symptoms
Systemic:, gastro-intestinal irritation
Risks
Must NOT be confused with other organophosphorus compounds since no inhibition properties
have been detected.
Treatment
Systemic treatment:
In the event of a mouthful or more being ingested, the following measures should be
considered:
Gastric lavage with charcoal, if necessary further treatment.


5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray
foam
carbon dioxide (CO2)
dry powder
Specific hazards during fire fighting
The product itself does not burn.
In the event of fire the following can be released:
carbon monoxide (CO)
carbon dioxide (CO2)
nitrogen oxides (NOx)
phosphorus oxides (e.g. phosphorus pentoxide)
hydrogen chloride (HCl)
Special protective equipment for fire-fighters
Use breathing apparatus.
Further information
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.


6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear acid-resistant boots.
Avoid contact with skin and eyes.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 3/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

Methods for Cleaning Up
Recover the product by pumping, suction or absorption using a dry and inert absorbent clay.
Pick up and fill the product into a tightly closed container.
When picked up, treat material as prescribed in Ch. 13. "Disposal considerations".
Additional Advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Check also for any local site procedures.


7. HANDLING AND STORAGE
Handling
Advice on safe handling
Smoking, eating and drinking should be prohibited in the application area.

Storage
Requirements for storage areas and containers
Keep out of the reach of children.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Other data Freezing will affect the physical condition but will not damage
the material. Thaw and mix before using.
Suitable materials
High density polyethylene
Unsuitable material
carbon steel


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.

Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
2-Butoxyethanol 111-76-2 25 ppm 2005 EH40 WEL
(TWA)
2-Butoxyethanol 111-76-2 50 ppm 2005 EH40 WEL
(STEL)
2-Butoxyethanol 111-76-2 98 mg/m3 / 20 ppm 05 2003 EU ELV
(TWA)
2-Butoxyethanol 111-76-2 246 mg/m3 / 50 ppm 05 2003 EU ELV
(STEL)

Personal protective equipment
Respiratory Protection No personal respiratory protective equipment normally required.
Respiratory protection should only be used to control residual risk of
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 4/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.

Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

Skin and body protection Wear standard coverall and Type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.

Hygiene measures
Wash hands immediately after work, if necessary take a shower.


9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form liquid
Colour colourless to amber
Safety data
pH 1.8 at 1 % (21 掳C)

Boiling point/ range 100 掳C

Ignition temperature > 600 掳C

Density ca. 1.205 g/cm鲁 at 20 掳C

Viscosity, kinematic 2.52 mm2/s at 40 掳C



10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.

Materials to avoid None.

Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Corrodes metals in the presence of water or moisture.
Risk of ethylene emission in case of increasing pH.
Stable under normal conditions.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 5/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 2,000 mg/kg

Acute Dermal Toxicity LD50 (rat) > 2,000 mg/kg

Skin Irritation Slight irritant effect - does not require labelling. (rabbit)

Eye Irritation In view of its pH being less than 1, the formulation is considered to
be severely irritant to the eyes.



12. ECOLOGICAL INFORMATION

Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) > 100 mg/l
Exposure time: 96 h

Toxicity to daphnia (Water flea (Daphnia magna)) > 721 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient.

Toxicity to algae EC50 (Scenedesmus subspicatus) 56 mg/l
Exposure time: 72 h



13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances


14. TRANSPORT INFORMATION

ADR/RID/ADNR
UN-No 3265
Labels 8
Packaging group III
Hazard no. 80
Description of the goods UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 6/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

(ETHEPHON SOLUTION)

IMDG
UN-No 3265
Class 8
Packaging group III
EmS F-A , S-B
Description of the goods CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(ETHEPHON SOLUTION )

IATA
UN-No 3265
Class 8
Packaging group III
Description of the goods CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(ETHEPHON SOLUTION )

UK 'Carriage' Regulations
UN-No 3265
Labels 8
Packaging group III
Hazard no. 80
Emergency action code 2X
Description of the goods UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(ETHEPHON SOLUTION)


15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Hazard warning labelling compulsory
Hazardous components which must be listed on the label:
鈥? Ethephon
Symbol(s)
Xi Irritant
R-phrase(s)
R41 Risk of serious damage to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S39 Wear eye/face protection.
S57 Use appropriate container to avoid environmental contamination.
CLASSIFICATION ACCORDING TO SPECIFIC UK REGULATIONS:
The labelling information below is that which has been approved under 'The Control of Pesticides
Regulations 1986' and/or 'Part III of the Food and Environment Protection Act 1985' and/or 'Plant
Protection Product Regulations 1999' and any subsequent amendments and may differ from that
indicated by any toxicological and/or other testing otherwise indicated in this 'Safety Data Sheet'.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


CERONE 7/7
Version 2 / GB Revision Date: 21.04.2006
102000001937 Print Date: 14.07.2008

Symbol(s)
Xi Irritant
R-phrase(s)
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S37 Wear suitable gloves.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)


16. OTHER INFORMATION

Further information
Text of R phrases mentioned in Section 2:
R20/21 Harmful by inhalation and in contact with skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R36/38 Irritating to eyes and skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.

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