Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 1/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name PROSARO EC250 4X5L BOT ELL
Product code (UVP) 05676428
Usage fungicide
Company Bayer CropScience AG
Alfred-Nobel-Stra脽e 50
40789 Monheim
Germany
Telephone +49(0)2173-38-3373
Telefax +49(0)2173-38-7394
Responsible Department Material and Transport Safety Management
+49(0)2173-38-3409/4566
Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC)
Prothioconazole 125 g/l, Tebuconazole 125 /g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Prothioconazole 178928-70-6 N R51/53 12,70
Tebuconazole 107534-96-3 Xn, N R22, R51/53, 12,70
R63
N,N-Dimethyldecan amide 14433-76-2 Xn R22, R38, 59,50
238-405-1 R41
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Irritating to skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risk of harm to the unborn child.
4. FIRST AID MEASURES
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways).
Remove contaminated clothing immediately and dispose of safely.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 2/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center
immediately.
Skin contact
Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400,
subsequently rinse with water.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical
attention if irritation develops and persists.
Ingestion
Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.
Notes to Physician
Treatment
Treat symptomatically.
Gastric lavage is not normally required. If a significant amount (more than a mouthful) has been
ingested, administer activated charcoal and sodium sulphate.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray
carbon dioxide (CO2)
foam
sand
Specific hazards during fire fighting
hydrogen chloride (HCl)
nitrogen oxides (NOx)
hydrogen cyanide (hydrocyanic acid)
carbon monoxide (CO)
sulphur dioxide (SO2)
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid contact with spilled product or contaminated surfaces.
Wear personal protective equipment. Unprotected persons must be kept away.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 3/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Storage
Requirements for storage areas and containers
Store in a place accessible by authorized persons only.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Store in original container.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage temperature -10 - 40 掳C
Suitable materials
Coextruded containers with an internal barrier layer made of ethylene vinyl alcohol copolymer
(EVOH)
Coextruded containers with an internal barrier layer made of polyamide (PA).
** Containers of 20 l and above: HDPE (high density polyethylene). **
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Safety glasses with side-shields
Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands before breaks and at the end of workday.
Remove soiled and/or soaked clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).
Protective measures
If product is handled while not enclosed, and if contact may occur:
complete suit protecting against chemicals
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 4/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid, clear to slightly turbid
Colour tan
Odour aromatic
Safety data
pH 5-7
Flash point > 148 掳C
DIN EN ISO 2719 (2003-09)
Density ca. 0,98 g/cm鲁 at 20 掳C
Water solubility emulsifiable
Viscosity, dynamic 49,9 mPa.s at 20 掳C
Surface tension ca. 29,1 mN/m at 20 掳C
10. STABILITY AND REACTIVITY
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 2.500 mg/kg
Acute Inhalation Toxicity LC50 (rat) > 5,153 mg/l
Exposure time: 4 h
Acute Dermal Toxicity LD50 (rat) > 4.000 mg/kg
Skin Irritation Irritating to skin. (rabbit)
Eye Irritation No eye irritation. (rabbit)
Sensitization Non-sensitizing. (guinea pig)
OECD Test Guideline 406
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 3,94 mg/l
Exposure time: 96 h
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 5/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 8,8 mg/l
Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 9,5 mg/l
Growth rate Exposure time: 72 h
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(TEBUCONAZOLE, PROTHIOCONAZOLE SOLUTION)
IMDG
UN-No 3082
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(TEBUCONAZOLE, PROTHIOCONAZOLE SOLUTION )
IATA
UN-No 3082
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(TEBUCONAZOLE, PROTHIOCONAZOLE SOLUTION )
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
1999/45/EC as amended.
Classification:
Labelling according to EC Directives
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROSARO EC250 4X5L BOT ELL 6/6
Version 1 / EU Revision Date: 04.08.2006
102000007908 Print Date: 20.09.2007
Hazardous components which must be listed on the label:
鈥? Prothioconazole
鈥? Tebuconazole
鈥? N,N-Dimethyldecan amide
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R63 Possible risk of harm to the unborn child.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S36/37 Wear suitable protective clothing and gloves.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R63 Possible risk of harm to the unborn child.
The information given in this Data Sheet has been included in accordance with the guidelines
established by EC Directive 1991/155/EC as amended. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The
required information complies with current EEC legislation. Addressees are requested to observe
any additional national requirements.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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