MSDS
EN
**** MATERIAL SAFETY DATA SHEET ****
3-Aminobenzotrifluoride
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: 3-Aminobenzotrifluoride
Catalog Numbers:
10319-0000, 10319-0050, 10319-1000, 10319-5000
Synonyms:
3-(Trifluoromethyl)aniline
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 98-16-8 |3-Aminobenzotrifluoride | 99+% | 202-643-4 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: T+
Risk Phrases: 21/22 26 33 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Very toxic by
inhalation. Danger of cumulative effects. Irritating to eyes,
respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). May cause burning sensations, coughing,
wheezing, laryngitis, shortness of breath and headache.
Inhalation:
May be fatal if inhaled. May cause cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood). Causes respiratory
tract irritation. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Prolonged exposure may produce a narcotic effect. Prolonged or
repeated exposure may cause nausea, dizziness, and headache. There is
a danger of cumulative effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
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Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Combustible
liquid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Do
not store in direct sunlight. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: light yellow
Odor: stench
pH: 2.7 (5 g/l aq.sol.)
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Vapor Pressure: 26.7mbar @85 deg C
Viscosity: Not available.
Boiling Point: 187 - 193 deg C @760mmHg
Freezing/Melting Point: 5 - 6 deg C
Autoignition Temperature: > 600 deg C (> 1,112.00 deg F)
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 5 g/l (20鈥)
Specific Gravity/Density: 1.303
Molecular Formula: C7H6F3N
Molecular Weight: 161.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Light sensitive.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-16-8: XU9180000
LD50/LC50:
CAS# 98-16-8: Draize test, rabbit, eye: 100 uL Moderate; Inhalation,
mouse: LC50 = 690 mg/m3/2H; Inhalation, rat: LC50 = 440 mg/m3/4H;
Oral, mouse: LD50 = 220 mg/kg; Oral, rabbit: LD50 = 615 mg/kg; Oral,
rat: LD50 = 480 mg/kg; Skin, rabbit: LD50 = 1330 mg/kg.
Not available.
Carcinogenicity:
3-Aminobenzotrifluoride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: EC50: 6.6 mg/l; 48 h;Bacteria: EC50: >1400 mg/l; ; OESO
209log POW = 2.39Biodegradation: 74% (28d - OESO 302 B)
Other
Avoid entering into waters or underground water. Do not empty into
drains.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
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Packing Group: I
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 26 Very toxic by inhalation.
R 33 Danger of cumulative effects.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 98-16-8: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 98-16-8 is listed on Canada's NDSL List.
CAS# 98-16-8 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 98-16-8: OEL-RUSSIA:STEL 0.5 mg/m3
US FEDERAL
TSCA
CAS# 98-16-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/16/1996 Revision #3 Date: 5/25/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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