Safety Data Sheet
E 142 GREEN S
Safety Data Sheet dated 21/6/2004, version 10
According to directive 91/155/EEC and the latest amendments
Printing date: 21/6/2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Trade name: E 142 GREEN S
Trade code: DED搂3A
CAS number: 3087-16-9
EINECS number: 221-409-2
Supplier:
NYMCO S.P.A.
Offices, Plant and Warehouse: Tradate (VA) Italy, via C. Magni, 1 Tel. +39-0331-
6871
Emergency telephone number of the company and/or of an authorised advisory centre:
NYMCO S.P.A. Telephone: +39 03316871
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterisation
Triarylmethane
Hazardous components within the meaning of EEC directive 67/548 and corresponding
classification:
100 % hydrogen [4-[4-(dimethylamino)-alfa-(2-hydroxy-3,6-disulphonato-1-naphthyl)
benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium, monosodium salt
CAS: 3087-16-9 EINECS: 221-409-2
Xi R36/37/38 (self assessment)
3. HAZARDS IDENTIFICATION
If brought into contact with the eyes,the product causes irritation that may last for over
24h,if inhaled,it causes irritation to the airways,and if brought into contact with the skin it
causes significant inflammation with erythema, scabs,and oedema
4. FIRST AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into
contact with the product must be rinsed immediately with plenty of running water and
possibly with soap.
Contact with eyes:
Wash immediately and thoroughly with running water, keeping eyelids raised, for at
least 10 minutes. Following this, protect the eyes with sterile gauze or a clean, dry,
handkerchief. OBTAIN A MEDICAL EXAMINATION.
Do not use eyewash or ointment of any kind (before obtaining an examination or
advice from an eye specialist).
Swallowing:
Induce vomit. GET IMMEDIATE MEDICAL ADVICE, showing the emergency card.
A suspension of activated charcoal in water, or liquid paraffin may be administered.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from the
contaminated premises to rest in a well ventilated area. OBTAIN MEDICAL
ATTENTION.
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Safety Data Sheet
E 142 GREEN S
5. FIRE-FIGHTING MEASURES
Recommended extinguishers:
Water, CO2, Foam, Chemical powders, according to the materials involved in the
fire.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes.
Protective equipment:
Use protection for the respiratory tract.
6. ACCIDENTAL RELEASE MEASURES
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
If the product has escaped into a water course, into the drainage system, or has
contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination. The product might,
where appropriate, be absorbed by inert material.
After the product has been recovered, rinse the area and materials involved with
water.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact and inhalation of the vapours. See, too, paragraph 8 below.
Do not eat or drink while working.
Storage conditions:
Store at room temperature away from heat sources
Instructions as regards storage premises:
Adequately ventilated premises.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or
handled.
Respiratory protection:
Use respiratory protection where ventilation is insufficient or exposure is prolonged,
e.g. CEN/FFP-2(S) or CEN/FFP-3(S).
Protection for hands:
Use protective gloves that provide comprehensive protection, e.g. P.V.C., neoprene
or rubber.
Eye protection:
Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1).
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber,
PVC or viton.
Exposure limit(s) (ACGIH):
hydrogen [4-[4-(dimethylamino)-alfa-(2-hydroxy-3,6-disulphonato-1-naphthyl)
benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium, monosodium salt
TLV-TWA: 4 mg/m3 TLV-STEL: 10 mg/m3
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Safety Data Sheet
E 142 GREEN S
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Green powder
Odour: odourless
pH: 6-8 (1 g/l a 20 掳C)
Solubility in water: soluble
10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
None in particular.
Hazardous decomposition products:
None
11. TOXICOLOGICAL INFORMATION
The concentration of each substance should be borne in mind in assessing the toxicological
effects deriving from the preparation.
Set out below is the toxicological information relating to the main substances in the
preparation.
the product does not contain toxicologically relevant substances.
Acute toxicity:
Oral LD50 (rat):>2000 mg/kg
12. ECOLOGICAL INFORMATION
Adopt sound working practices, so that the product is not released into the environment.
13. DISPOSAL CONSIDERATIONS
Recover if possible. In so doing, comply with the local and national regulations currently in
force.
14. TRANSPORT INFORMATION
Not a dangerous material under the amended E.E.C. Council Directives
15. REGULATORY INFORMATION
SDS in compliance with the following European Directives:
Directive 67/548/EEC - Directive 1999/45/EC (Classification and Labelling):
Symbols:
Xi Irritant
R Phrases:
R36/37/38 Irritating to eyes, respiratory system and skin.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36 Wear suitable protective clothing.
Contents:
hydrogen [4-[4-(dimethylamino)-alfa-(2-hydroxy-3,6-disulphonato-1-naphthyl)
benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium, monosodium salt
Where applicable, refer to the following regulatory provisions :
Ministerial circulars 46 e 61 (Aromatic amines).
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Safety Data Sheet
E 142 GREEN S
Law 136/83 (Biodegradability of detergents).
Presidential Decree D.P.R. 175/88 (Seveso Directive), Appendices II掳, III掳 e IV掳.
Presidential Decree D.P.R. 250/89 (Labelling of detergents).
Inventory information:
EEC EINECS:
All components of this product are included in the European Inventory of Existing
Chemical Substances (EINECS) in compliance with Council Directive 67/548/EEC
and its amendments.
US TSCA :
The components of this product appear in the TSCA list.
CANADA DSL:
The components of this product are included in the Canada Domestic Substances
List (DSL).
16. OTHER INFORMATION
Main bibliographic sources:
NIOSH - Registry of toxic effects of chemical substances (1983)
I.N.R.S. - Fiche Toxicologique
CESIO - Classification and labelling of anionic, nonionic surfactants (1990)
The information contained herein is based on our state of knowledge at the above-specified
date. It refers solely to the product indicated and constitutes no guarantee of particular
quality.
It is the duty of the user to ensure that this information is appropriate and complete with
respect to the specific use intended.
SECTIONS REVISED IN THIS EDITION:
Editor: NYMCO S.P.A. Product Safety.
This MSDS cancels and replaces any preceding release.
Text of R phrases referred to under heading 2:
R36/37/38 Irritating to eyes, respiratory system and skin.
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