Material Safety Data Sheet
Revision Date: 02/07/2005 Issue date: 02/07/2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: 24CC 312 WIP Item No. : 7003326
Product type: Anaerobic Adhesive Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Hydroxyalkyl methacrylate 30-60 None None 1 ppm TWA; 3 ppm STEL
27813-02-1
Polyurethane methacrylate resin 30-60 None None None
Unknown
Polyurethane methacrylate resin 10-30 None None None
Unknown
Acrylic acid 5-10 2 ppm TWA 10 ppm TWA; 30 mg/m鲁 1 ppm TWA (skin); 3 ppm
79-10-7 (skin) STEL (skin)
1 ppm (6 mg/m3) Skin (WEEL)
Cumene hydroperoxide 1-5 None None
80-15-9
Polyglycol dimethacrylate 1-5 None None None
109-16-0
Methacrylic acid 1-5 20 ppm TWA None None
79-41-4
gamma- 1-5 None None None
Methacryloxypropyltrimethoxysilane
2530-85-0
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 2*
Color: Clear Amber FLAMMABILITY: 1
Odor: Sharp PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION.
MAY BE HARMFUL IF SWALLOWED OR INHALED.
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects
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Inhalation: Vapors and mist irritate the respiratory tract and nasal passages.
Skin contact: May cause allergic skin reaction. Irritating to skin.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: May be harmful if swallowed.
Existing conditions aggravated by Eye, skin, and respiratory disorders. Acrylic acid: Respiratory disorders. Lung disease.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding
eyelids open all the time. Get medical attention.
Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93潞C (200潞F) Tagliabue closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: None
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Irritating organic vapors.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container until
disposal.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after
handling. Use only with adequate ventilation.
Storage: For safe storage, store at or below 38掳C (100掳F). Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene
gloves.
Eye/face protection: Safety goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Clear Amber
Odor: Sharp
Vapor pressure: Less than 10 mm Hg at 27潞C (80潞F)
pH: Not applicable
Boiling point/range: Greater than 149潞C (300潞F)
Melting point/range: Not available
Specific gravity: 1.08
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: 49%; 529 grams/liter (EPA Method 24)
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Phenols. Irritating organic vapors.
Incompatability: Strong oxidizers. Strong reducing agents. Amines. Strong acids. Heavy metals. Peroxides. Free radical
initiators.
Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10).
11. TOXICOLOGICAL INFORMATION
Product toxicity data: Acute LD50 (oral) :Greater than 10000 mg/kg(rat). Acute LD50 (dermal) :Greater than 5000 mg/kg
(rabbit).
Carcinogen Status
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Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Hydroxyalkyl methacrylate No No No
27813-02-1
Polyurethane methacrylate resin No No No
Unknown
Polyurethane methacrylate resin No No No
Unknown
Acrylic acid No No No
79-10-7
Cumene hydroperoxide No No No
80-15-9
Polyglycol dimethacrylate No No No
109-16-0
Methacrylic acid No No No
79-41-4
gamma- No No No
Methacryloxypropyltrimethoxysilane
2530-85-0
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Hydroxyalkyl methacrylate Allergen, Irritant
27813-02-1
Polyurethane methacrylate resin Allergen, Irritant
Unknown
Polyurethane methacrylate resin Allergen, Irritant
Unknown
Acrylic acid Allergen, Corrosive, Irritant, Kidney, Liver
79-10-7
Cumene hydroperoxide Allergen, Central nervous system, Corrosive, Irritant, Mutagen
80-15-9
Polyglycol dimethacrylate Allergen, Irritant
109-16-0
Methacrylic acid Allergen, Corrosive, Irritant
79-41-4
gamma- Allergen, Irritant
Methacryloxypropyltrimethoxysilane
2530-85-0
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Unrestricted
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Unrestricted
Hazard class or division: None
Identification number: None
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Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Unrestricted
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: 4-Methoxyphenol (150-76-5).
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Acrylic acid
(CAS# 79-10-7). Cumene hydroperoxide (CAS# 80-15-9).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.
Canada Regulatory Information
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic
Substances List or the Non-Domestic Substances List. Those components must be tracked by all
Canadian Importers of Record as required by the Canadian Environmental Protection Agency. They
may be imported into Canada in limited quantities. Please contact Loctite Health & Regulatory Affairs
Department for details.
WHMIS hazard class: D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: Expanded chemical information in Section 2 and
related sections.
Prepared by: Kyra Kozak Woods, Health and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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