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MSDS Material Safety Data Sheet
CAS

29964-62-3

File Name: jmcatalysts_com---755.asp
                           SAFETY DATA SHEET
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
179205 1.00 EC New

1. PRODUCT AND COMPANY IDENTIFICATION
179205
Product Code
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number

2. COMPOSITION/INFORMATION ON THE COMPONENTS
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
Product Formal Name
.Not Specified
Product Chemical Family
29964-62-3
CAS Number

3. HAZARD IDENTIFICATION
There is no toxicological data available for this material but, by analogy with
similar compounds, it is classified as being harmful by ingestion and by
inhalation and as being a possible eye irritant.
This material is not included in the EINECS inventory and, therefore, the
phrase"Caution, substance not yet fully tested" is allocated to the label. 聽

4. FIRST AID MEASURES
Overexposure to this material may produce the following symptoms -
First Aid
Inhalation - Irritation of the respiratory tract with coughing.
Ingestion - Nausea and vomiting
Eye contact - Redness and irritation.
Skin contact - Possible irritation if contact is prolonged or repeated 聽 聽

Remove from exposure and allow to rest in fresh air. Seek medical advice if
First Aid - Inhalation
symptoms persist.
Rinse mouth with clean water, give milk or water to drink. Seek medical
First Aid - Ingestion
advice if symptoms persist.
Irrigate with clean water or isotonic saline for 5 minutes. Seek medical advice
First Aid - Eyes
if symptoms persist. 聽
Remove contaminated clothes and wash skin with soap and water. 聽
First Aid - Skin

5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽

6. ACCIDENTAL RELEASE MEASURES
Wearing personal protective equipment (see section 8), collect up the spillage
and store in a suitable, sealed container. Wash the site of the spillage with
large volumes of water. Do not allow the wash water to enter natural
watercourses. 聽

7. HANDLING AND STORAGE


MSDS_ALL Page 1
SAFETY DATA SHEET
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
179205 1.00 EC New

7. HANDLING AND STORAGE (continued)
Good industrial hygiene practices should be observed. Use only under
Handling (JM)
conditions of a good level of ventilation. Avoid contact with skin and eyes. Do
not eat, drink, smoke or apply cosmetics whilst handling this material. 聽
Keep in a secure store. 聽
Storage (JM)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No Occupational Exposure Standards have been established for this material.
Users are advised to minimise exposure. If necessary, appropriate filter- type
mask, chemically resistant gloves and suitable eye protection should be worn.


9. PHYSICAL AND CHEMICAL PROPERTIES
Crystals.
Physical State
pale yellow/white
Colour
Decomposes before melting.
Melting Point (掳C)
>1
Density (kg/m3)
280 (approx.)
Decomposition Temp. (掳C)

10. STABILITY AND REACTIVITY
This material is supplied in a stable condition. No specific reactive hazards
are known to Johnson Matthey. As a precious metal catalyst, this material
may promote the oxidiation and ignition of flammable gases and liquids.
Contact with strong oxidizing agents should be avoided, as should exposure
to moisture.

11. TOXICOLOGICAL INFORMATION
There is no toxicological data available for this material but, by analogy with
similar compounds, it should be regarded as being harmful by ingestion or by
inhalation.

12. ECOLOGICAL INFORMATION
There is no data available for this preparation or its components. In the
abscence of such data this material should be regarded as being potentially
enviromentally hazardous.

13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽

14. TRANSPORT INFORMATION
Not restricted.


15. REGULATORY INFORMATION
Harmful
Labelling Information

R20/22 Harmful by inhalation and if swallowed.
R phrases
S24/25 Avoid contact with skin and eyes.
S phrases



MSDS_ALL Page 2
SAFETY DATA SHEET
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
179205 1.00 EC New

15. REGULATORY INFORMATION (continued)
CAUTION - SUBSTANCE NOT YET FULLY TESTED.
Additional Information

16. OTHER INFORMATION
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02



MSDS_ALL Page 3
SAFETY DATA SHEET
PD-105 DICHLORO-1,4-BIS(DIPHP.) BUTANE PALLADIUM (II)
179205 1.00 EC New

16. OTHER INFORMATION (continued)
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 307 1919, Fax:- 01 307
1920

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12




MSDS_ALL Page 4

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