Johnson Matthey
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
179111 3.00 EC Current 15.09.2000
1. PRODUCT AND COMPANY IDENTIFICATION
179111
Product Code
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Palladium(II)Acetate trimer, [Pd(CH COO) ]
Composition
2
JM Version Number
14/02/96
Date of First Issue
2. COMPOSITION/INFORMATION ON THE COMPONENTS
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
Product Formal Name
.Not Specified
Product Chemical Family
53189-26-7
CAS Number
3. HAZARD IDENTIFICATION
This compound is a severe eye irritant and a moderate skin irritant, and is
also expected to irritate the respiratory tract if inhaled as a dust. It is of low
acute toxicity. There is no evidence that palladium compounds present an
allergy problem, similar to that observed with corresponding platinum
compounds. 聽
4. FIRST AID MEASURES
Over-exposure to this material may produce the following symptoms -
First Aid
Inhalation : irritation of the respiratory system with coughing. Ingestion :
abdominal pain and vomiting. Eye contact : severe pain, blurred vision and
possible blindness. 聽 聽 聽 聽
First Aid - Inhalation remove from exposure and allow to rest in fresh air, if symptoms persist seek
medical attention. 聽
rinse mouth with clean water and give clean water or milk to drink. Seek
First Aid - Ingestion
medical advice.
First Aid - Eyes rinse with clean water or isotonic saline solution for 15 minutes, seek medical
attention urgently. 聽 聽
wash skin with soap and water.
First Aid - Skin
5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽
6. ACCIDENTAL RELEASE MEASURES
Wearing gloves and eye protection, sweep up the spillage and store in
sealed, plastic containers, ready for disposal. Wash the area with water. 聽 聽
7. HANDLING AND STORAGE
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Johnson Matthey
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
179111 3.00 EC Current 15.09.2000
7. HANDLING AND STORAGE (continued)
If the process is dusty or if fume is created, local exhaust extraction should be
Handling (JM)
used and protective clothing, including gloves and eye protection, should be
worn. There are no special requirements if used under ordinary conditions
and with adequate ventilation. 聽
Store in a cool, dry area away from incompatible materials, such as liquid
Storage (JM)
halogenated hydrocarbons and oxidising agents. Protect from physical
damage. Powder and other active forms should be kept in tightly sealed
containers under nitrogen.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No Occupational Exposure Standards have been established for this material.
Users are advised to minimise exposure. If necessary, appropriate filter- type
mask, chemically resistant gloves and suitable eye protection should be worn.
聽
9. PHYSICAL AND CHEMICAL PROPERTIES
orange-brown needles.
Appearance
No odour.
Odour
not applicable
pH
not applicable.
Boiling Range/Point
decomposes in the range 194-205掳C.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
no data.
Density
Water - insoluble.
Solubility in Water
Fat - no data. Fairly soluble in ethanol. Soluble in chloroform, methylene
dichloride, acetone, acetonitrile and di-ethyl ether. 聽 聽 聽
no data.
Partition Coefficient
10. STABILITY AND REACTIVITY
Users should note that, whilst this material is not impact or friction sensitive,
calorimetric studies indicate that decomposition is accompanied by an
extremely high exotherm. The temperature of this material should not be
allowed to exceed 175掳C.
Palladium(II)acetate trimer is soluble with decomposition in hydrochloric acid
and aqueous potassium iodide solutions. It is insoluble in solutions of sodium
chloride, sodium nitrate or sodium acetate. When warmed with alcohols, it
decomposes.
Palladium/acetic acid compounds have been reported as causing explosions
when used for the synthesis of poly(phenylacetylene). 聽
11. TOXICOLOGICAL INFORMATION
LD50 (oral-rat): >5000 mg/kg.
skin-rabbit: slight irritant.
eye-rabbit: severe irritant/corrosive.
12. ECOLOGICAL INFORMATION
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Johnson Matthey
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
179111 3.00 EC Current 15.09.2000
12. ECOLOGICAL INFORMATION (continued)
No specific information is available, but this material is not thought to present
an ecological hazard. 聽
13. DISPOSAL
Accumulated wastes and residues should be returned to a refinery for metal
recovery or disposed of in accordance with local and national regulations. 聽
14. TRANSPORT INFORMATION
Not restricted.
15. REGULATORY INFORMATION
Irritant
Labelling Information
R38 Irritating to skin.
R phrases
R41 Risk of serious damage to eyes.
S22 Do not breathe dust.
S phrases
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
2584249
EINECS Number
Xi - Irritant
EC Annex I Classification
16. OTHER INFORMATION
30 July 1999
MSDS first issued
15 September 2000
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
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Johnson Matthey
PD-111 HEXAKIS(ACETATO)TRIPALLADIUM(II)
179111 3.00 EC Current 15.09.2000
16. OTHER INFORMATION (continued)
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
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