Johnson Matthey
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II) dichloromethane ad
179107 1.00 EC Current 07.06.2001
1. PRODUCT AND COMPANY IDENTIFICATION
179107
Product Code
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II)
Trade Name
dichloromethane adduct
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
(C鈥橦鈥?) PC鈥楬 FeC鈥楬 P(C鈥橦鈥?) PdCl
Composition
2. COMPOSITION/INFORMATION ON THE COMPONENTS
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II)
Product Formal Name
dichloromethane adduct
Palladium Compound
Product Chemical Family
72287-26-4
CAS Number
3. HAZARD IDENTIFICATION
Harmful by inhalation and if swallowed. Caution, substance not yet fully
Main Hazards
tested
Dust may cause slight transient irritation.
Health Effects - Eyes
Material may cause slight irritation on prolonged or repeated contact.
Health Effects - Skin
Swallowing may have the following effects:- nausea. vomiting.
Health Effects - Ingestion
Exposure to dust may have the following effects:- diarrhoea. nausea. irritation
Health Effects - Inhalation
of nose, throat and respiratory tract.
4. FIRST AID MEASURES
Wash out eye with plenty of water. Get medical attention if symptoms persist.
First Aid - Eyes
Wash skin with soap and water.
First Aid - Skin
Rinse mouth with water Give milk or water to drink Seek medical attention if
First Aid - Ingestion
symptoms persist
Rinse nose and mouth with clean water. Remove from exposure and allow to
First Aid - Inhalation
rest in fresh air. Seek medical attention if symptoms persist
5. FIRE FIGHTING MEASURES
This material is not flammable, but if involved in a fire will decompose
Extinguishing Media
producing toxic fumes. Use any extinguishing agent suitable for the
surrounding fire.
The residue, ash or char left after a fire may have catalytic properties and
Special Hazards of Product
may promote the re-ignition of flammable materials and vapours.
Wear full protective clothing and self-contained breathing apparatus.
Protective Equipment for Fire-
Fighting
6. ACCIDENTAL RELEASE MEASURES
Wear appropriate protective clothing. Wear respiratory protection.
Personal Precautions
Environmental Precautions Try to prevent the material from entering drains or water courses.
Collect in a suitable container for re-use, recycling or disposal
Spillages
\ Page 1
Johnson Matthey
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II) dichloromethane ad
179107 1.00 EC Current 07.06.2001
7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Do not eat, drink,
Handling
smoke or apply cosmetics whilst using this material. Avoid direct contact.
Storage area should be: cool. dry. well ventilated. Store in original containers.
Storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards None assigned.
Suitable gloves
Hand Protection
Suitable eye protection
Eye Protection
9. PHYSICAL AND CHEMICAL PROPERTIES
Powder.
Physical State
orange/red
Colour
280 - 282
Melting Point (掳C)
Not flammable
Flash Point (PMCC) (掳C)
Insoluble.
Solubility in Water (kg/m3)
Not classified as explosive.
Explosive Properties
Not classifed as oxidizing
Oxidising Properties
10. STABILITY AND REACTIVITY
No known reactive hazards. Air sensitive
Stability
Hazardous Decomposition Products Combustion will generate: oxides of carbon. oxides of phosphorus.
11. TOXICOLOGICAL INFORMATION
By analogy with similar compounds this material is expected to be harmful by
Acute Toxicity
inhalation and ingestion.
Data for a closely related material suggest that this product may cause
Irritancy - Eyes
irritation of the eye.
Data available for a related material suggests that this product is unlikely to
Irritancy - Skin
be irritating to the skin.
Caution - substance not fully tested.
Additional Data
12. ECOLOGICAL INFORMATION
No specific information is available, but this material is not thought to present
Ecotoxicity
an ecological hazard.
13. DISPOSAL
Return accumulated waste material to a precious metal refinery for metal
Product Disposal
recovery, or dispose of in accordance with local and national regulations.
14. TRANSPORT INFORMATION
UN Number Not restricted for transport.
15. REGULATORY INFORMATION
Harmful
Labelling Information
\ Page 2
Johnson Matthey
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II) dichloromethane ad
179107 1.00 EC Current 07.06.2001
15. REGULATORY INFORMATION (continued)
R20/22 Harmful by inhalation and if swallowed.
R phrases
S22 Do not breathe dust.
S phrases
S24/25 Avoid contact with skin and eyes.
CAUTION - SUBSTANCE NOT YET FULLY TESTED.
Additional Information
16. OTHER INFORMATION
7 June 2001
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed.
Reference Sources
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
\ Page 3
Johnson Matthey
PD-107 Dichloro bis (diphenylphosphino)ferrocene Palladium(II) dichloromethane ad
179107 1.00 EC Current 07.06.2001
16. OTHER INFORMATION (continued)
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 307 1919, Fax:- 01 307
1920
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
\ Page 4
|