Johnson Matthey
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
179101 3.00 EC Current 15.09.2000
1. PRODUCT AND COMPANY IDENTIFICATION
179101
Product Code
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Tetrakis(TPP)Palladium(0), Pd(P(C鈥橦鈥?) )
Composition
1
JM Version Number
05/01/95
Date of First Issue
2. COMPOSITION/INFORMATION ON THE COMPONENTS
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
Product Formal Name
.Not Specified
Product Chemical Family
14221-01-3
CAS Number
3. HAZARD IDENTIFICATION
This material is sensitive to air, heat and light. Animal tests indicate that it is
not irritating to the skin or eyes.
It is classified as being harmful by ingestion and inhalation on the basis of the
production of triphenylphosphine oxide upon decomposition.
4. FIRST AID MEASURES
Over-exposure to this material may produce the following symptoms -
First Aid
Inhalation : irritation of the respiratory system with coughing. Ingestion :
abdominal pain and vomiting. 聽 聽 聽 聽 聽
remove from exposure and allow to rest in fresh air, if symptoms persist seek
First Aid - Inhalation
medical attention. 聽
First Aid - Ingestion rinse mouth with clean water and give clean water or milk to drink. Seek
medical advice. 聽
rinse with clean water or isotonic saline solution for 5 minutes, seek medical
First Aid - Eyes
advice if symptoms persist. 聽
First Aid - Skin wash skin with soap and water.
5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽
6. ACCIDENTAL RELEASE MEASURES
Collect up spillage and store, under an inert atmosphere, in a suitable
container.
7. HANDLING AND STORAGE
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Johnson Matthey
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
179101 3.00 EC Current 15.09.2000
7. HANDLING AND STORAGE (continued)
Good industrial hygiene practices should be observed. Chemical resistant
Handling (JM)
gloves and eye protection should be worn. Do not eat, drink, smoke or apply
cosmetics whilst using this material. This material should only be handled by
authorised personnel who are fully aware of its properties. It is supplied
packed under Argon and should, preferably, only be handled in an inert
atmosphere or under vacuum. 聽 聽
Store under kerosine, in a cool, dry area away from incompatible materials
Storage (JM)
such as liquid hydrocarbons and oxidising agents. Protect from water and
physical damage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No Occupational Exposure Standards have been established for this material.
Users are advised to minimise exposure. If necessary, appropriate filter- type
mask, chemically resistant gloves and suitable eye protection should be worn.
聽
9. PHYSICAL AND CHEMICAL PROPERTIES
Yellow/green solid.
Appearance
No odour.
Odour
not applicable
pH
not applicable.
Boiling Range/Point
Decomposes.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
no data.
Density
Water - insoluble. Insoluble in diethyl ether.
Solubility in Water
Slightly soluble in dichloromethane, acetone, methanol, ethyl acetate.
Soluble in ethanol, chloroform, toluene.
Fat - no data. 聽 聽
no data.
Partition Coefficient
10. STABILITY AND REACTIVITY
This material will decompose upon exposure to air, light or heat. No specific
reactive hazards are known to Johnson Matthey.
11. TOXICOLOGICAL INFORMATION
This material is classified as being harmful by ingestion and inhalation on the
basis of the toxicity of a decomposition product - triphenylphosphine oxide (
LD50 oral mouse - 1380mg/kg).
Animal tests indicate that the material is not irritating to the eyes or skin.
聽
12. ECOLOGICAL INFORMATION
This material is not thought to present a severe ecological hazard, however,
in the absence of definative data it should be regarded as a potential hazard.
Do not allow this material to enter natural watercourses. 聽
13. DISPOSAL
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Johnson Matthey
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
179101 3.00 EC Current 15.09.2000
13. DISPOSAL (continued)
The final disposal of this material should be in accordance with all local and
national regulations. Alternatively, it may, by prior arrangement, be returned
to Johnson Matthey for final disposal. 聽
14. TRANSPORT INFORMATION
Not restricted.
15. REGULATORY INFORMATION
Harmful
Labelling Information
R20/22 Harmful by inhalation and if swallowed.
R phrases
S22 Do not breathe dust.
S phrases
S24/25 Avoid contact with skin and eyes.
2380869
EINECS Number
Xn - Harmful
EC Annex I Classification
16. OTHER INFORMATION
30 July 1999
MSDS first issued
15 September 2000
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
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Johnson Matthey
TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)
179101 3.00 EC Current 15.09.2000
16. OTHER INFORMATION (continued)
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
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