Johnson Matthey
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
209040 1.00 EC Current 22.05.2001
1. PRODUCT AND COMPANY IDENTIFICATION
209040
Product Code
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
2. COMPOSITION/INFORMATION ON THE COMPONENTS
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
Product Formal Name
Rhodium Compound
Product Chemical Family
13938-94-8
CAS Number
3. HAZARD IDENTIFICATION
There is no toxicological data available for this compound. By analogy with
Main Hazards
similar or related compounds it is thought to be Toxic by inhalation, in contact
with skin and if swallowed.
Dust will cause conjunctival irritation.
Health Effects - Eyes
Skin absorption may be a significant route for exposure. Effects will be similar
Health Effects - Skin
to those resulting from ingestion.
Swallowing may have the following effects:- severe gastrointestinal irritation.
Health Effects - Ingestion
diarrhoea. nausea. vomiting.
Exposure to dust may have the following effects:- systemic effects similar to
Health Effects - Inhalation
those resulting from ingestion.
4. FIRST AID MEASURES
First Aid - Eyes Immediately flood the eye with plenty of water for at least 15 minutes, holding
the eye open. Obtain medical attention urgently.
Immediately wash skin thoroughly with soap and water. Remove
First Aid - Skin
contaminated clothing as washing proceeds. Obtain medical attention.
First Aid - Ingestion Wash out mouth with water. Do not induce vomiting. Seek medical attention
Remove from exposure. Keep warm and at rest. If there is difficulty in
First Aid - Inhalation
breathing, give oxygen. Obtain medical attention urgently.
5. FIRE FIGHTING MEASURES
Not readily combustible. Select extinguishing agent appropriate to other
Extinguishing Media
materials involved.
The residue, ash or char left after a fire may have catalytic properties and
Special Hazards of Product
may promote the re-ignition of flammable materials and vapours.
Wear self contained breathing apparatus.
Protective Equipment for Fire-
Fighting
6. ACCIDENTAL RELEASE MEASURES
Wear appropriate protective clothing. Wear respiratory protection.
Personal Precautions
Try to prevent the material from entering drains or water courses.
Environmental Precautions
Transfer into suitable containers for recovery or disposal.
Spillages
7. HANDLING AND STORAGE
\ Page 1
Johnson Matthey
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
209040 1.00 EC Current 22.05.2001
7. HANDLING AND STORAGE (continued)
Use only under conditions of good local ventilation. Avoid inhaling dust. Avoid
Handling
contact with eyes, skin and clothing. Good industrial hygiene practices should
be observed.
Storage area should be: cool. dry. well ventilated. out of direct sunlight. Store
Storage
in original containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
UK EH40: OES 0.001mg/m鲁 8h TWA. Rhodium, soluble salts (as Rh)
Occupational Exposure Standards
UK EH40: OES 0.1mg/m鲁 8h TWA. Rhodium metal fume and dust
The specific respirator selected must be based on the airborne concentration
Respiratory Protection
found in the workplace and must not exceed the working limits of the
respirator.
Suitable gloves
Hand Protection
Suitable eye protection
Eye Protection
9. PHYSICAL AND CHEMICAL PROPERTIES
Crystals.
Physical State
Yellow.
Colour
Decomposes , at 170, before melting.
Melting Point (掳C)
Insoluble.
Solubility in Water (kg/m3)
10. STABILITY AND REACTIVITY
Stability Air stable No known reactive hazards.
Oxidising agents. Strong acids.
Materials to Avoid
oxides of carbon. toxic fumes.
Hazardous Decomposition Products
11. TOXICOLOGICAL INFORMATION
There is no toxicological data available for this material but, by analogy with
Acute Toxicity
similar compounds it should be regarded as being toxic by all routes of
exposure.
No known reports of skin sensitisation.
Skin Sensitisation
12. ECOLOGICAL INFORMATION
No specific information is available, but this material is not thought to present
Ecotoxicity
an ecological hazard.
13. DISPOSAL
Return accumulated waste material to a precious metal refinery for metal
Product Disposal
recovery, or dispose of in accordance with local and national regulations.
14. TRANSPORT INFORMATION
UN Number 2811
Toxic solid, organic, n.o.s.
UN Proper Shipping Name
6.1
UN Class
II
UN Packaging Group
15. REGULATORY INFORMATION
\ Page 2
Johnson Matthey
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
209040 1.00 EC Current 22.05.2001
15. REGULATORY INFORMATION (continued)
Toxic
Labelling Information
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R phrases
S36 Wear suitable protective clothing.
S phrases
S45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
2377128
EINECS Number
16. OTHER INFORMATION
22 May 2001
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
\ Page 3
Johnson Matthey
Rh-40 Carbonylchloro bis(triphenylphosphine) Rhodium (I)
209040 1.00 EC Current 22.05.2001
16. OTHER INFORMATION (continued)
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 307 1919, Fax:- 01 307
1920
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
\ Page 4
|