MSDS: LANASET BLACK B Page 1 of 4
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: LANASET BLACK B
MSDS CODE : C0801746AO
VERSION :6
UPDATED : April 2002
Hazardous according to criteria of Worksafe Australia
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn: Attention:
CHEMICAL SAFTEY OFFICER
or
EMERGENCY RESPONCE SERVICES
Print:
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IDENTIFICATION
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PRODUCT NAME ..: LANASET BLACK B
Other name(s)..: MIXTURE OF AZO AND AZO METAL COMPLEX DYES
Correct Shipping name: ENVIRONMENTALLY HAZARDOUS SOILD, N.O.S
UN Number . . . . . : 3077
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (IATA ONLY) group . . : III
HAZCHEM Code . . . . : CONTAIN SPILL
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
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Appearance. . . . . . : BLACK POWDER WITH NO ODOUR.
Boiling/Melting point : NOT APPLICABLE
Vapour pressure . . . : NOT APPLICABLE
Density . . . . . . . : 0.69 (g/cc @ 20 deg.C)
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : 80 g/l at 30 oC (g/L @ 20 deg.C)
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SOLUBILITY IN WATER : 80 g/l at 90 oC
pH value : 7.5 - 8.5 in water at 1 g/l
OXIDISING PROPERTIES : NONE
THERMAL DECOMPOSITION : > 200 oC
IGNITION TEMPERATURE : 420 oC
COLOUR INDEX : ACID BLACK 172
HAZARD CODE : ** Xi ** IRRITANT
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Chemical Entity CAS No. Proportion
C.I. ACID BLACK 172 57693-14-8 30 - 40 %
DISODIUM [1-[(2-HYDROXY-3,5-DINITROPHENY 70236-55-4 5 - 10 %
L)AZO]-2-NAPHTHOLATO(2-)][3-HYDROXY-4-[(
2-HYDROXY-1-NAPHTHYL)AZO]-7-NITRONAPHTHA
LENE-1-SULPHONATO(3)]CHROMATE(2-)
OBSERVE "EXPOSURE LIMITS"
NON HAZARDOUS COMPONENTS TO 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral, Rat LD50) > 5000 mg/kg
Eye . . . : NON-IRRITANT - EC 83 RABBIT
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Skin . . : NON-IRRITANT - EC 83 RABBIT
SKIN SENSITISATION: SENSITIZING OECD 406 GUINEA
PIG.
Inhaled . : NOT YET AVAILABLE - SEE "HEALTH EFFECTS - CHRONIC"
BELOW.
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SENSITIZATION: EXPOSURE OF SKIN TO A SENSITIZING AGENT TENDS TO RESULT
IN RESPONSES SUCH AS HIVES OR EXZEMA. INHALATION MAY PRODUCE WHEEZING,
SHORTNESS OF BREATH, ASTHMA, REQUIRING IMMEDIATE MEDICAL ATTENTION.
CASES OF RESPIRATORY SENSITIZATION HAVE BEEN OBSERVED WITH SOME DYES
AND CARE SHOULD BE TAKEN TO AVOID INHALATION.
SHOULD AN INDIVIDUAL BECOME SENSITIZED A DOCTOR SHOULD BE CONSULTED
AND ALL CONTACT WITH THIS DYE MUST CEASE IMMEDIATELY.
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Swallowed : WASH OUT MOUTH WITH WATER. DRINK PLENTY OF WATER.
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING, DO
NOT RE-USE UNTIL LAUNDERED. SEEK MEDICAL
ATTENTION.
Inhaled . : REMOVE PATIENT TO FRESH AIR AND REST. IF YOU FEEL
UNWELL OR IF EXPOSURE PROLONGED, SEEK MEDICAL
ATTENTION.
First aid facility: DELUGE SAFETY SHOWER SHOULD BE LOCATED NEAR WORK
AREA.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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TWA : 0.1 mg/m3 C.I ACID BLACK 172 (C.I.A - U.K)
AVOID EXCEEDING EXPOSURE LIMITS BY USE OF VENTILATION AND/OR PERSONAL
PROTECTION
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
AVOID DUST FORMATION
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE EXPOSURE LIMITS ARE MET. STATE REGULATIONS ON SPEED
AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
HAZARDOUS POWDERS: THE USE OF LOCAL EXHAUST EXTRACTION DEVICE IN
ADDITION TO ROOM VENTILATION IS REQUIRED WITH THIS PRODUCT. LOCAL
EXHAUST EXTRACTION CAN BE A SLOT OR HOOD LOCATED AT DISPENSING POINT
OR A DOWNDRAUGHT WEIGHING BOOTH WITH HEPA AIR CLEANER.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND SAFETY GLASSES/FACE SHIELD
MUST BE WORN WHEN USING THIS PRODUCT.
PARTICULATE FILTER CLASS P1 (DUST MASK) IS REQUIRED TO BE WORN WHEN
POSITIVE LOCAL VENTILATION IN OPERATION, OTHERWISE THE FOLLOWING
AS1716 RESPIRATORY PROTECTION MUST BE WORN:
HALF FACE MASK: "YES" CANNISTER TYPE: NOT APPLICABLE
CARTRIDGE CLASS: "CLASS P2" FOR POWDERS, AND "CLASS A2" FOR LIQUIDS.
PRE FILTER: RECOMMENDED. FULL FACE MASK: "SUITABLE". AIR
SUPPLIED: "YES, AIR-LINE". COMBINATION ORGANIC VAPOUR PARTICULATE
TYPE A2-P2 CARTRIDGE. (MEDIUM CAPACITY/EFFICIENCY FILTER IS SUITABLE.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION. KEEP CONTAINERS CLOSED.
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UN Number . . . . . : 3077
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (IATA ONLY) group . . : III
HAZCHEM Code . . . . : CONTAIN SPILL
IATA Class . . . . . : 9 12C
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: CONTAIN SPILL
** KEEP AWAY UNPROTECTED PERSONS **
** ENSURE GOOD LOCAL EXHAUST AND VENTILATION IN WORK AREAS WHERE DUST
FORMATION IS POSSIBLE **
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE -
'DAMPEN DOWN FIRST', 'AVOID CREATING DUST', SCOOP UP AND PLACE INTO
MARKED CONTAINERS FOR DISPOSAL AS CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS. - LAND FILL: NO.
SECURE LAND FILL: NO INCINERATION: YES HIGH TEMPERATURE INCINERATION:
SUITABLE. CONTAMINATED, EMPTY CONTAINERS MUST BE DISPOSED OF AS
CHEMICAL WASTE. ** NOTE ** : IF IN DOUBT CONTACT CIBA SPECIALTY
CHEMICALS TELEPHONE NUMBER ON PAGE 1.
** KEEP AWAY UNPROTECTED PERSONS **
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
THERMAL DECOMPOSITION OR BURNING MAY RELEASE OXIDES OF CARBON,
NITROGEN AND SULFUR. TOXIC GASES/VAPOURS ARE ALSO POSSIBLE. IN CASE OF
FIRE, SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT
MUST BE WORN.
** KEEP AWAY UNPROTECTED PERSONS **
DO NOT RELEASE CHEMICALLY CONTAMINATED WATER INTO DRAINS, SOIL OR
SURFACE WATER. SUFFICIENT MEASURES MUST BE TAKEN TO RETAIN THE WATER
FOR EXTINGUISHING. DISPOSE OF CONTAMINATED WATER AND SOIL ACCORDING TO
LOCAL REGULATIONS.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 0 mgO2/g
COD . . . . . . . . . . . . : 950 mgO2/g
TOC . . . . . . . . . . . . : 33.5 %
Fish toxicity . . . . . . . : SPECIES : RAINBOW TROUT
LC0 : 2 mg/l
LC50 : 6 mg/l, 48 hr, OECD 203
Toxicity to Bacteria . . . : BST : > 300 mg/l
OECD Biological degredation : 30 - 40%, DOC ANALYSIS, OECD 302B
Organo-halogen content. . . : 0.1 % CHLORO
Heavy-metal content . . . . : 3.2% Cr (AS CrIII ORGANO-METAL COMPLEX)
BIOELIMINATION SUMMARY: PARTIALLY ELIMINATED BY ADSORPTION ON EFFLUENT
TREATMENT SLUDGE. PLEASE NOTE THAT THE CHROMIUM PRESENT IN THIS DYE IS
COORDININATELY BONDED AND IS NOT PRESENT AS A FREE METAL.
NITROGEN CONTENT: 7.6 %
TESTED MATERIAL: STANDARDISED PRODUCT.
VERY TOXIC TO AQUATIC LIFE. PREVENT DISCHARGE OF PRODUCT TO NATURAL
WATERWAYS, SEWER, DRAINS AND GROUND SOIL. CONTAIN SPILLS AND ANY
RESIDUES AND DISPOSE OF AS SHOWN ABOVE. BEHAVIOUR IN TREATMENT PLANTS:
NO INHIBITION. NO NITRIFICATION INHIBITION KNOWN.
"THE CLASS 9 CLASSIFICATION OF THIS PRODUCT APPLIES IN THE EC AND
REFERENCE SHOULD BE MADE TO THE LATEST ISSUE OF THE 'ARTDG' (OR
RELEVANT DG CODE) FOR LOCAL CLASSIFICATION. IF IN DOUBT, CONTACT CIBA
SPECIALTY CHEMICALS".
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EEC classification/labelling: ** Xi ** IRRITANT
R-phrase: R43: MAY CAUSE SENSITISATION BY SKIN CONTACT.
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S-phrase: S22: DO NOT BREATHE DUST:
S24: AVOID CONTACT WITH SKIN;
S37: WEAR SUITABLE GLOVES.
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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REVISIONS IN THIS VERSION
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- Name
- Physical properties
- Other properties
- Ingredients
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0412 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: DEANGGU1 Date: 20 April 02
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