MATERIAL SAFETY DATA SHEET
PRODUCT NAME: LANASET RED 2B
MSDS CODE : C0801351AE
VERSION : 4
UPDATED : December 2002
Not classified as hazardous according to criteria of NOHSC Australia
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn:
CHEMICAL SAFETY OFFICER
or
EMERGENCY RESPONSE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: LANASET RED 2B
Other name(s)..: MIXTURE OF AZO AND AZO METAL COMPLEX DYES
Correct Shipping name: ENVIRONMENTALLY HAZ. SUBS, SOLID, N.O.S
UN Number . . . . . : 3077
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (EXC. SEA) group . . : III
HAZCHEM Code . . . . : NONE LISTED
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
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Appearance. . . . . . : RED GRANULES; NO ODOUR
Boiling/Melting point : NOT AVAILABLE
Vapour pressure . . . : NOT APPLICABLE
Density . . . . . . . : 470 kg/m3 (g/cc @ 20 deg.C)
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : ' SEE BELOW' (g/L @ 20 deg.C)
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pH : 6.5-7.5 G/L
SOLUBILITY IN WATER : 20 g/l at 30oC
SOLUBILITY IN WATER : 60 g/l at 90oC
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Chemical Entity CAS No. Proportion
CHROMATE COMPLEX 72017-66-4 30-40 %
NON-HAZARDOUS COMPONENTS To 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral,Rat LD50) >2000 mg/kg
Eye . . . : NON-IRRITANT OECD 405 RABBIT
Skin . . : NON-IRRITANT - EC 83 OECD 404 RABBIT
Inhaled . : NOT YET AVAILABLE, BUT MAY CAUSE RESPIRATORY
SENSITIZATION (CHRONIC EFFECT) - SEE "HEALTH
EFFECTS" BELOW.
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THIS PRODUCT CONTAINS A REACTIVE DYE COMPONENT. CASES OF RESPIRATORY
SENSITISATION HAVE BEEN OBSERVED WITH REACTIVE DYES AND CARE SHOULD BE
TAKEN TO AVOID INHALATION. INHALATION SENSITISATION MAY PRODUCE
WHEEZING, SHORTNESS OF BREATH AND ASTHMA.
THE TOXICOLOGICAL TESTS WERE CARRIED OUT ON THE COMPONENTS.
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Swallowed : WASH OUT MOUTH WITH WATER, DRINK PLENTY OF WATER
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING.
Inhaled . : REMOVE PATIENT TO FRESH AIR, REST. IF SYMPTOMS OF
ASTHMA OR BREATHING DIFFICULTIES OCCUR, SEEK
MEDICAL ATTENTION. ASSIST BREATHING (OXY-VIVA
EQUIP) UNTIL HELP ARRIVES.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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TWA : 10 mg/m3 NUISANCE DUST (CIA - UK)
AVOID EXPOSURE BY USE OF VENTILATION AND/OR PERSONAL PROTECTION.
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE LPL OF EXPOSURE IS ATTAINED. ANY STATE REGULATIONS ON
SPEED AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND GLASSES ARE RECOMMENDED TO
BE WORN WHEN HANDLING THIS PRODUCT.
PARTICULATE FILTER CLASS P1 (DUST MASK) IS REQUIRED TO BE WORN WHEN
POSITIVE LOCAL VENTILATION IN OPERATION, OTHERWISE THE FOLLOWING
AS1716 RESPIRATORY PROTECTION MUST BE WORN.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : KEEP CONTAINERS CLOSED
Storage . . . . . . : STORE IN A WELL VENTILATED AREA.
UN Number . . . . . : 3077
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 (EXC. SEA) group . . : III
HAZCHEM Code . . . . : NONE LISTED
IATA Class . . . . . : 9
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE. DAMPEN
DOWN FIRST SCOOP UP THEN WASH DOWN FINAL RESIDUE WITH DETERGENT AND
WATER.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS. - LAND FILL: NO.
SECURE LAND FILL: YES INCINERATION: YES HIGH
TEMPERATURE INCINERATION: SUITABLE. CONTAMINATED, EMPTY
CONTAINERS MUST BE DISPOSED OF AS CHEMICAL WASTE. ** NOTE ** : IF IN
DOUBT CONTACT CIBA SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
VAPOURS OF CARBON, NITROGEN, SULFUR OXIDES AND SOME HYDROGEN
CHLORIDE POSSIBLE IN A FIRE, SELF CONTAINED BREATHING APPARATUS MUST
BE WORN IN CASE OF FIRE.
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 48 mg02/g
COD . . . . . . . . . . . . : 1007 mg02/g
TOC . . . . . . . . . . . . : NOT AVAILABLE
Fish toxicity . . . . . . . : SPECIES : ZEBRA FISH - 96HR, OECD 203
LC50 : 1.2 mg/l
DAPHNIA TOXICITY
EC50 > 30 48 Hr OECD 202
Toxicity to Bacteria . . . : > 281 mg/l 3 Hr OECD 209
OECD Biological degredation : 30-40%, DOC ANALYSIS - OECD 302B
Organo-halogen content. . . : 1.8% CHLORO
Heavy-metal content . . . . : 1% CHROMIUM AS CrIII ORGANO-METAL COMP
Phosphorous content . . . . : N/AP %
NITROGEN CONTENT: 7.3 %
Toxic to aquatic organisms if run directly to surface waters.
Behaviour in treatment plants: No inhibition. No nitrification
inhibition known.
Partially eliminated by adsorption on effluent treatment sludge.
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EEC classification/labelling: *N* DANGEROUS FOR THE ENVIRONMENT
R-phrase: R51/53: TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG
TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT
S-phrase: S61: AVOID RELEASE TO THE ENVIRONMENT. REFER TO
SPECIAL INSTRUCTIONS/SDS
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: NAMLIST1 Date: 01 December 02
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