0624569 - LYOPRINT RG Page 1 of 4
Ciba Specialty Chemicals
Product-Ident-No. 0624569
SAFETY DATA SHEET (2001/58/EC)
Replaces Edition 4.000 from 03.02.1999
Edition 5 from 23.07.2002
TRADE NAME
LYOPRINT RG
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation
Sodium salt of nitrobenzene sulfonic acid
Chemical description
Use of the substance/preparation
Textile chemical
Company/undertaking identification
Ciba Specialty Chemicals CH-4002 Basle
Product responsibility
Product Safety & Registration CA, Basel; Fax ++41 6163 6 51 69
Responsible department
Ciba Specialty Chemicals Ltd.
Supplier
CH-4002 Basel
0041 61 696 5151
Emergency telephone
2. COMPOSITION / INFORMATION ON INGREDIENTS
Information on ingredients Content CAS-No. Symbol R-Phrases
- Sodium 3-nitrobenzenesulfonate >90 % 127-68-4 Xi 36-43
EC No.: 204-857-3
3. HAZARDS IDENTIFICATION
Irritating to eyes
May cause sensitisation by skin contact
4. FIRST-AID MEASURES
Move to fresh air. Seek medical attention if you feel unwell or if exposure
Inhalation
prolonged.
Remove contaminated clothing. Wash affected skin with soap and plenty of
Skin contact
water.
Rinse immediately with plenty of water for at least 10 minutes. Seek
Eye contact
medical attention.
Wash out mouth with water. Drink plenty of water.
Ingestion
Symptomatic treatment
Advice for the doctor
5. FIRE-FIGHTING MEASURES
Waterspray, foam, powder, carbon dioxide.
Fire extinguishing agents
No restrictions.
Restrictions
Dust explosion hazard.
Fire/explosion hazard
Carbon, nitrogen and sulfur oxides
Main combustion gas
Self contained breathing apparatus.
Personal protection
6. ACCIDENTAL RELEASE MEASURES
Goggles, gloves, respiratory protection.
Personal protection
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No special precautions
Environmental precautions
Damp down. Avoid dust. Scoop into marked containers for disposal as
Spillage procedure
chemical waste. Flush residues away with water.
7. HANDLING AND STORAGE
Handling
Avoid ingestion, inhalation, skin and eye contact. Handle in accordance
Occupational hygiene
with good industrial hygiene practice and any legal requirements.
Storage
Take precautionary measures against electrostatic discharge.
Fire precautions
Avoid build up of dust.
Store in a cool, dry area with adequate ventilation
Storage facilities
No special precautions.
Segregation
Keep containers closed.
Storage conditions
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure limit values
None. Ensure adequate ventilation
Components with occupational
exposure limits
Exposure Controls
Occupational exposure controls
Goggles, gloves, respiratory protection.
General Personal Protection
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Powder
Form
Yellow
Colour
None
Odour
Important health safety and environmental information
7-8 2 g/l
pH
-- 掳C
Boiling point
> 100 掳C DIN EN 22719 (DIN
Flash point
51758)
None
Oxidising properties
-- mbar
Vapour pressure
0.45 g/ml 20 掳C
Density
ca. 200 g/l at 20 掳C
Solubility in water
-2.61
Partition coefficient
-- mPa.s
Viscosity-
Other information
ca. 350 掳C
Melting point
> 350 掳C
Thermal decomposition
380 掳C DIN 51794
Ignition temperature
--
Explosion limits (Vol%) Lower
--
Upper
10. STABILITY AND REACTIVITY
None.
Conditions to avoid
None
Materials to avoid
Hazardous decomposition products None under normal storage conditions
11. TOXICOLOGICAL INFORMATION
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Acute toxicity
> 5000 mg/kg
- LD50 oral
Primary irritation
Non-irritant OECD 404
(Skin)
Irritant OECD 405
(Eye)
Sensitizing OECD 406
Skin sensitisation
Inhalation of dust may cause irritation of the respiratory tract
Adverse effects in man
Additional information
12. ECOLOGICAL INFORMATION
Ecotoxicity
Bacterial toxicity
> 300 mg/l
BST
500 mg/l 96 hour Golden orfe
Fish toxicity LC0
> 500 mg/l
LC50
Not toxic or harmful to aquatic organisms
Summary
Persistance and degradability
>90%, COD Analysis, OECD 302B
Bioelimination
Eliminated by adsorption on effluent treatment sludge
Summary
No inhibition. No nitrification inhibition known
Behaviour in treatment plants
Additional Ecology Data
< 10 mgO2/g
BOD5
990 mgO2/g
COD
6.2 %
Nitrogen content
--
Phosphorus content
-- %
Organohalogen content
Metal content under the ETAD recommended limits
Metal content
Standardised product
Tested material
Additional information
13. DISPOSAL CONSIDERATIONS
Incineration, landfill. Observe local regulations.
Product disposal
Contaminated, empty containers must be disposed of as chemical waste.
Contaminated packaging
14. TRANSPORT INFORMATION
KEEP AWAY FROM FOODSTUFFS
Transport road and rail
FREE
UN Number ADR/RID
Correct technical name ADR/RID
ADR/RID Class
Packing Group
Transport air
FREE
UN Number ICAO
Proper shipping name
ICAO Class
Packing Group
Transport sea
FREE
UN Number IMO
Proper shipping name
IMDG Class
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Packing Group
15. REGULATORY INFORMATION
CLASSIFICATION AND LABELLING
Xi - Irritant
Symbol and classification
R36:Irritating to eyes
R-Phrases
R43:May cause sensitisation by skin contact
S24 : Avoid contact with skin
S-Phrases
S26 : In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice
S37 : Wear suitable gloves
3-Nitrobenzene sulphuric acid, Sodium salt
Contains
83/467
EU Guideline
16. OTHER INFORMATION
List of relevant R-phrases (Section 2)
R36 : Irritating to eyes
R43 : May cause sensitisation by skin contact
Recommended restrictions on use
Ciba textile, paper and leather dyes and chemicals are technical grade and unless otherwise stated or agreed are
recommended only for industrial use in applications involving the pretreatment dyeing or finishing of textiles,
paper or leather. Other intended uses including their use in consumer products governed by specific legislation or
standards should be referred to the manufacturer. The data contained in the SDS apply only to Ciba Specialty
Chemicals products sold under the stated trade names. Technical information in support will be provided by Ciba
Specialty Chemicals at the request of competent authorities.
member of ETAD
This Safety Data Sheet has been updated in accordance with EU Directives
MSDS Changes
2001/58/EC (The Safety Data Sheet Directive) and 1999/45/EC (The
Preparations Directive)
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