ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
KLASH庐15EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
KLASH庐15EC
Product Name:
Pyrethroid Insecticide
Chemical Class:
KLASH庐15EC is an insecticide based on the synthetic-pyrethroid
Use:
Deltamethrin. It is a potent insecticide, effective by contact
and ingestion against a wide range of Public health insect
pests.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Quantity
Substance (g/L) Chemical structure
Deltamethrin technical 99% 15.2 Br
CAS No. 52918-63-5 (15 Pure) CN
C CH CH3 CO2
C O
Chemical Name: (S)-伪-cyano-3-phenoxybenzyl Br HH
H
(1R,3R)-3-(2,2-dibromovinyl)-2,2-
dimethylcyclopropanecarboxylate (IUPAC) CH3
60.00
Blend of ionic and non ionic emulsifiers
828.05
Solvents
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MSDS:
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
Signs of Poisoning:
Symptoms of acute exposure include severe headaches,
fatigue, nausea and anorexia. Severe cases of direct
contact cause blurred vision, tightness in chest and
convulsions.
Primary Routes of Entry:
Skin contact and absorption and vapor mist inhalation.
Effects of single over exposures:
Ingestion:
Accidental or deliberate ingestion could cause
neurological signs and symptoms such as ataxia and
convulsions.
Skin Absorption:
May be cause irritation and facial skin sensations.
Inhalation:
May be cause irritation to the respiratory system.
Eyes:
May be cause eye irritation.
4. FIRST AID MEASURES
Emergency and First aid Procedures
Ingestion:
Call a physician or poison control center. If breathing has
stopped apply atrificial respiration. Do not induce
vomiting. Do not give anything by mouth to an
unconscious person.
Skin:
Wash affected area with plenty of soap and water.
Remove contaminated clothing. Launder contaminated
clothing separately. Get medical attention.
Inhalation:
Remove victim to fresh air. If not breathing administer
artificial respiration. Avoid unprotected mouth to mouth
resuscitation. GET MEDICAL ATTENTION.
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MSDS:
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Eye:
Flush with clean water for 15 鈥? 20 minutes while holding
the eyelid open.
Note to Physician:
There is no specific antidote. Treat symptomatically. If
convulsions occur, diazepam (10 or 20 mg for an adult) should
be given slowly, intravenously or rectally and repeated if
necessary.
5. FIRE FIGHTING MEASURES
Fire and Explosion:
41.3 掳C
Flash point
Combustible
Flammable limits in air:
Not determined.
Auto ignition Temperature:
Not determined.
Extinguishing Media:
Use carbon dioxide or dry chemical for small fires and
water fog or foam (alcohol, polymer or ordinary) for large
fires. Cool containers from maximum distance.
Unusual fire and explosion hazards:
Noxious fumes may be emitted under fire conditions.
Special fire fighting procedures:
Fire fighters should use self contained breathing
apparatus and full turnout gear. Prevent runoff of fire
water. Avoid exposure to smoke. (Keep upwind).
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken if material is released or spilled:
Dike the area using absorbent materials such as sand or clay.
Recover and contain as much product as possible using
absorbent. Clean spill area using a solution of water and
detergent. Collect and contain wash water and all contaminated
absorbent for disposal. If spilled on the ground, the affected area
should be excavated to a depth of 1-2 inches. Prevent the
spilled product or washing from reaching public sewers or
waterways. Wear appropriate protective equipment during the
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MSDS:
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
cleanup. Ensure that tools and equipment are adequately
decontaminated.
Waste disposal method:
Dispose of in accordance with local regulations.
Container disposal:
Dispose of in an approved facility according to local regulations.
7. HANDLING AND STORAGE
Store the product in a well-ventilated, secure area out of reach
of children and domestic animals. Do not use or store near heat
or open flame. Do not store food or feed in storage area.
Prevent eating, drinking or smoking in areas where there is a
potential exposure to the product. Wash hands before eating,
drinking or smoking after using the product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective equipment should be used during the following procedures:
鈥? Manufacture, formulation or application of this product.
鈥? Repair and maintenance of contaminated equipment
鈥? Clear up of leaks and spills.
鈥? Any other activity that may result in hazardous exposures.
Respiratory Protection:
Use MSHA/NIOSH approved respirator for organic vapors. Use
positive pressure contained breathing apparatus where
emergency conditions or where exposure limits are exceeded.
Ventilation:
Exhaust appropriate for removal of vapors.
Protective clothing:
Chemical resistant gloves, coveralls, apron and foot coverings.
Eye Protection:
Safety goggles or face shield.
User safety recommendations:
Safety showers and eye wash should be easily accessible.
KLASH庐 15EC / INSECTICIDE 4/6
MSDS:
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Personnel Protection:
May irritate the eye and skin. Avoid contact with eyes and skin.
DO NOT inhale spray mist. When preparing spray and using the
prepared spray, wear cotton overalls buttoned to the neck and
wrist and washable hat, elbow-length PVC gloves and face
shied. After use and before eating drinking or smoking, wash
hands, arms and face thoroughly with soap and water. After
each day鈥檚 use, wash gloves, face shield and contaminated
clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Assay: "Deltamethrin" 15 卤 2.25 g/L
Appearance: Clear Light yellow to Yellow Liquid free of
visible impurities
Odour: Aromatic
Density: 0.8959(Kg/L)
Viscosity: 2.5-3.0 Cp (Brookfield, spindle 2@ 6 r.p.m
and 24掳C)
Flash Point: 41.5掳C
Acidity as H2SO4: 0.017% w/w
Water Contents: 0.16% w/w
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Condition to avoid: Excessive heat.
Materials to avoid: Strong oxidizers, acids, and alkalis.
Hazardous polymerization: will not occur
Emulsion Stability
Initial Emulsification Complete
Emulsion Stability (2 h) 1.0 ml Cream + 0.25 ml oil
Re-emulsification (24 h) Complete
Emulsion Stability (24.5 h) 1.0 ml Cream + 0.25 ml oil
Heat Stability (2 weeks @ 54掳C) Passed
Cold Stability Passed
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MSDS:
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
11. TOXICOLOGICAL INFORMATION
Toxicology Data:
Acute Oral LD50 (rat) 431 mg/kg
2.69 mg/m3
Acute Inhalation LC50 (4 h rat)
Eye Irritation (rabbit) May cause irreversible eye
damage
Dermal Irritation (rabbit) Irritating to skin, may cause
facial skin sensations
Carcinogenicity, Teratogenicity Mutagenicity:
Deltamethrin is not carcinogenic. It did not show any mutagenic
or chromosome damaging activity. It is also not teratogenic to
mice and rabbits.
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is toxic to bees, fish and other aquatic life.
13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers.
Dispose of product containers, waste containers and residues
according to local health and environmental regulations.
14. TRANSPORT INFORMATION
Proper Shipping Name Environmentally hazardous
substances, Pyrethyroid Pesticide,
Liquid, toxic (Deltamethrin)
UN number UN No 3351
Class 6.1
Packing Group III
Marine Pollutant Yes
15. REGULATORY INFORMATION.
Pest Control Product
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
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MSDS:
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