ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
PESTON 500EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
庐
Product Name: PESTON 500EC
Active Ingredient: Phenthoate
Chemical Class: Organophosphorus
Use: PESTON 500EC Used for the Control of Aphididae (aphids),
Coccidae & Diaspididae (scale insects),
Cicadellidae (leafhoppers), Fulgoridae (lantern
bugs), Pseudococcidae (mealybugs), Tingidae
(lace bugs), Pyrrhocoridae (cotton stainers, red
bugs) and Pentatomidae (shield bugs),
Thripidae (thrips), Aleyrodidae (whitefly),
Noctuidae (bollworms, stem borers), in citrus
fruit, pome fruit, olives, Japanese persimmons,
chestnuts, mulberries, cotton, cereals, maize,
rice, coffee, tea, sunflowers, sugar cane,
tobacco, vegetables, cucurbits, and
ornamentals, at 40-75 g/hl, 500-1000 g/ha. Also
used for mosquito control (adults and larvae).
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel.# (+966) 3 8121 406
PESTON庐 500EC / Insecticide 1/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
Phenthoate 91% Tech 52.73 S
(=500 g/L)
CAS No.2597-03-7
CHSP(OCH3)2
Chemical Name: S- -ethoxycarbonylbenzyl
O,O-dimethyl phosphorodithioate (IUPAC) CO2CH2CH3
Blend of anionic and nonionic emulsifiers 5.76
Aromatic Solvent 41.51
3. HAZARD IDENTIFICATION
ACUTE EFFECTS
Physical hazards:
None
Health hazards:
Inhalation: Vapor or spray mist may be harmful if inhaled.
Eye: None irritating to the eyes.
Skin: None irritating or sensitizing to skin
Ingestion: Harmful if swallowed.
4. FIRST AID MEASURES
First Aid:
In the case of the following Symptoms appearing during spray or
inadvertent swallowing, immediately take the first aid treatment and
call a physician immediately.
Symptoms of Poisoning
Nausea, headache, giddiness, vomiting, blurred vision, contraction
of pupils and diarrhea
Ingestion:
If ingestion is suspected, call a physician or poison control center. If
medical assistance cannot be given immediately, induce vomiting
and get to a hospital. To induce vomiting, administer 1 or 2 glasses
of water and stick finger down throat. Repeat until vomits are clear.
And inject 1 to 2 mg of atropine subcutaneous. Or, if available,
administer syrup of ipecac (1/2 oz. Or 15 ml). If vomiting does not
occur within 10-20 minutes, administer a second does of ipecac. Do
PESTON庐 500EC / Insecticide 2/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
not attempt to give anything by mouth to an unconscious or
convulsing person.
Eye:
Irrigate for 15 minutes with copious quantities of water with eyelids
held open. If irritation persists, seek medical attention immediately.
Skin:
Remove contaminated clothing. Flush skin with running water for a
minimum of 20 minutes. If swelling, redness, blistering or irritation
occurs seek medical attention immediately.
Inhalation:
If a person is overcome by excessive exposure to aerosols or
vapors of this material, remove to fresh air or uncontaminated area.
If not breathing, give artificial respiration, preferably mouth to
mouth. Get medical attention as soon as possible.
Advice to doctor:
If ingestion has occurred less than 2 hours earlier, carry out careful
gastric lavage; use endotracheal cuff if available, to prevent
aspiration. Observe patient for respiratory difficulty from aspiration
pneumonitis. Give artificial resuscitation and appropriate
chemotherapy if respiration is depressed. Symptomatic treatment
and supportive therapy as indicated.
5. FIRE FIGHTING MEASURES
Extinguishing Media:
For small fires, use foam, carbon dioxide or dry powder
extinguishant. For large fires, use foam or water-fog, avoid use of
water jet. Contain run-off water with for example, temporary earth
barriers.
Fire and Explosion Hazards:
Flash point: >40掳C
Combustible liquid: Keep fire exposed containers cool by spraying
with water.
Fire Fighting Instructions:
Evacuate area and fight fire upwind from a safe distance to avoid
hazardous vapors and decomposition products. Fire exposed
containers can build up pressure and should be kept cool with
water spray if possible. Explosive vapor could form from ruptured
containers. Dike and collect water used to fight fire to prevent
PESTON庐 500EC / Insecticide 3/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
environment damage due to run off. Foam or dry chemical fire
extinguishing systems are preferred to prevent environmental
damage from excessive water run off.
Self - contained breathing apparatus with full face-piece.
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent
(vermiculite). Prevent from entering drains, waterway or sewers.
Collect in sealed open top containers for disposal. Generously
cover the contaminated areas with common, household detergent
brush in a small amount of water, work the detergent into the
remaining spilled material forming slurry. Collect slurry in sealed
open top container for disposal. This material is water pollutant and
should be prevented from drainage systems and bodies of water.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer
container for recycling/reconditioning, or puncture top, sides and
bottom and dispose of in landfill in accordance with local
regulations. On-site disposal of concentrate is not acceptable.
Waste disposal should be carried out by industrial incineration or
burial at a site approved by local authorities.
7. HANDLING AND STORAGE
Keep out of reach of Children:
Use only in a well-ventilated area. Do not reuse empty containers.
Keep the container closed when not in use. Keep away from food,
feed and drinking water. Keep in a well-ventilated, dry place away
from heat and other sources of ignition. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls:
Natural ventilation only required when handling the concentrate. A
local exhaust should be used in confined areas to keep the level of
solvent within acceptable limits.
PESTON庐 500EC / Insecticide 4/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Personnel Protection:
Eye protection: Safety glasses or goggles.
Clothing: Long sleeved shirt and long pants, shoes plus
socks.
Gloves: Chemical resistant gloves.
Respirator: All pesticide handlers must wear a respiratory
protection device when working.
Preparation of solution
The proper dosages for spray should be confirmed before spray.
Put on rubber gloves and a respirator so as not to contact Peston
500EC directly.
User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using tobacco
or using the toilet. Remove clothing immediately if pesticide gets
inside. Then wash throughly and put on clean clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, Light yellow liquid free of visible
impurities.
pH 6.5 鈥? 8.5
Acidity (g/Kg) as H2SO4 <1.0
Flash point > 40 C
Water content Not applicable
Solubility in water: Soluble.
10. STABILITY AND REACTIVITY
Stable in water, air and from light.
Stability:
Incompatibility:
Peston 500EC is chemically compatible with all most insecticides,
fungicides and acaricides except alkaline ones such as Bordeaux
mixture and lime sulfur. Physically however Peston 500EC may be
immiscible due to the type of emulsifiers, diluents and carriers
Therefore, on the occasion of making the mixture for the first time, it
is recommended that small scale test be carried out in order to sees
compatibility and phytotoxicity
PESTON庐 500EC / Insecticide 5/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Hazardous Polymerization: Will not occur
Condition to avoid :
Keep away from heat. Keep away from sources of ignition, No
smoking.
Hazardous Decomposition Products:
Thermal decomposition products are toxic and may include
hydrocarbons ammonia, organic and acid halides, oxide of carbon,
nitrogen and sulfur.
11. TOXICOLOGICAL INFORMATION
LD50 oral for rat the product >600 mg/Kg.
Technical Phenthoate:
LD50 oral for male rat for technical grade material used in the
product (Phenthoate) is: 270 mg/Kg.
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is very toxic to aquatic organisms.
Do not apply this product or allow it to drift to blooming crops or
weeds if bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Methods:
Do not contaminate ponds, waterways or ditches with chemical or
used containers. Dispose of in facility permitted for hazardous
waste.
Container Disposal:
Empty container retains product residue. Triple rinse empty
containers, return rinse water to dilution mixture, and dispose of
dilution mixture as a hazardous waste if it cannot be disposed of by
use according to label instructions. Do not reuse container. Offer if
for recycling or reconditioning, or puncture and dispose of in
properly permitted landfill.
PESTON庐 500EC / Insecticide 6/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
14. TRANSPORT INFORMATION
Proper Shipping Name: Organophosphorus pesticide, liquid, toxic,
flammable, flash point 鈮?23掳C (Phenthoate)
UN. No: UN 3017
Hazard Class: 6.1
TF2
Classification Code:
Packing group: III
Subsidiary Risks: 6.1 + 3
61
Special provisions:
LQ19
Limited quantities:
Packing instructions P001, IBC03,
Packaging:
R001
Special packing provisions
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks Special Provisions TP2 TP28
Tank Code L4BH
ADR Tank Special Provision TU15 TE1 TE15
TE19
Vehicle for tank carriage FL
Transport Category 2
Special provision Packages -
carriage Bulk -
Loading, unloading & Handling CV13 CV28
Operation S2 S9
Hazard Identification 63
15. REGULATORY INFORMATION.
Organophosphorus Insecticide for agricultural use
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
PESTON庐 500EC / Insecticide 7/8
MSDS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
PESTON庐 500EC / Insecticide 8/8
MSDS
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