ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
RIDOXYL 240EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
RIDOXYL庐240EC
Product Name:
Chemical Class: Phenylamide: acylalanine
Use: Ridoxyl 240 EC is used to control diseases caused by air- and soil-borne
Peronosporales on a wide range of crops.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
Metalaxyl-M Technical
CAS No. 70630-17-0
Chemical Name: methyl N-
24.91 CH3
(methoxyacetyl)-N-(2,6-xylyl)-D- O
(240 12 g/L)
alaninate; methyl (R)-2-{[(2,6- CH3O CH
C
CO2CH3
CH2 N
dimethylphenyl) methoxyacetyl]
amino}propionate (IUPAC) CH3 CH3
EC hazard (Xn; R22, R41)
Blend of anionic and nonionic
6.94
Surfactants
Organic Solvent 68.16
Ridoxyl庐 240 EC / Fungicide
MSDS: 1/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
Symptoms of Acute Exposure
May cause eye irritation
Hazardous Decomposition Products:
Can decompose at high temperature forming toxic gases
Unusual fire, Explosion and Reactivity Hazards:
During a fire, irritating and possibly toxic gases may be generated by thermal
decomposition or combustion.
4. FIRST AID MEASURES
Have the product container, label or Material Safety Data Sheet with you when
you calling a Poison control center or doctor, or going for treatment.
Ingestion:
If swallowed, call a Poison control center or a Doctor immediately for
treatment advice. Have the person sip a glass of water if able to swallow.
Do not induce vomiting unless to do so by a Poison Control center or
Doctor. Do not give anything by mouth to an unconscious person.
Eye:
If in eyes, Hold eye open and rinse slowly and gently with water for 15 鈥?
20 minutes. Remove contact lenses, if present, after 5 minutes, then
continue rinsing eye. Call a poison control center or doctor for treatment
advice.
Skin:
Wash affected area with plenty of soap and water for 15 鈥? 20 minutes.
Remove contaminated clothing. Launder contaminated clothing
separately. Get medical attention.
Inhalation:
Move person to fresh air. If person is not breathing give artificial
respiration, preferably mouth to mouth if possible. Call a Poison control
center or doctor for further treatment advice.
Note to Physician:
There is no specific antidote if this product is ingested. Treat symptomatically.
Medical conditions likely to be aggravated by Exposure:
None known
Ridoxyl庐 240 EC / Fungicide
MSDS: 2/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
5. FIRE FIGHTING MEASURES
Fire and Explosion:
Flash point : >40 C
Flammable Limits (% in Air): Not Available
Auto ignition Temperature: Not Available
Flammability: Combustible Liquid
Unusual Fire, Explosion and Reactivity Hazards:
During a fire, irritating and possibly toxic gases may be generated by thermal
decomposition or combustion.
In case of Fire:
Use dry, chemical, foam or CO2 extinguishing media. Wear full protective
clothing and self-contained breathing apparatus. Evacuate nonessential
personnel from the area to prevent human exposure to fire, smoke, fumes or
products of combustion. Prevent use of contaminated buildings, area and
equipment until decontaminated. Water runoff can cause environmental
damage. If water is used to fight fire, dike and collect runoff.
6. ACCIDENTAL RELEASE MEASURES
In Case of Spills or Leak:
Control the spill at its source. Contain the spill to prevent from spreading or
contaminating soil or from entering sewage and drainage systems or any body
of water. Clean up spills immediately, observing precautions in protective
equipment section. Cover entire spill with absorbing material and place into
compatible disposal container. Scrub area with hard water detergent (e.g.
commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid
with additional absorbent and place into compatible disposal container. Once all
material is cleaned up and placed in a disposal container, seal container and
arrange for disposition.
7. HANDLING AND STORAGE
Store the product in a well-ventilated, secure area out of reach of children and
domestic animals. Do not use or store near heat or open flame. Do not store
food, beverages, tobacco or feed in storage area. Prevent eating, drinking,
smoking and cosmetic application in areas where there is a potential exposure
to the product. Wash thoroughly with soap and water after handling.
Ridoxyl庐 240 EC / Fungicide
MSDS: 3/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
The following Recommendations for Exposure Controls/ Personal Protection are
intended for the manufacture, formulation, packaging and use of this product.
For commercial applications and or on farm applications consult the product label.
Ingestion:
Prevent eating, drinking, tobacco usage and cosmetic application in
areas where there is a potential for exposure to the material. Wash
thoroughly with soap and water after handling.
Eye Contact:
Where eye contact is likely use chemical splash goggles. Facilities
storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.
Skin Contact:
Where contact is likely, wear chemical resistant (such as nitrile or butyl)
gloves, coveralls, socks and chemical-resistant headgear.
Inhalation:
Use process enclosures, local exhaust ventilation or other engineering
controls to keep airborne levels below exposure limits. A NIOSH-certified
combination air-purifying respirator with an N, P or R 95 or HE class filter
and an organic vapor cartridge may be permissible under certain
circumstances where air borne concentrations are expected to exceed
exposure limits. Protection provided by air-purifying respirators is limited.
Use a pressure demand atmosphere supplying respirator if thre is any
potential for uncontrolled release, exposure levels are not known, or
under any other circumstances where air-purifying respirators may not
provide adequate protection.
Engineering Control Statements:
When handlers use closed systems, enclosed cabs, or aircraft in a manner that
meets the requirements listed in the Worker Protection Standards (WPS) for
agricultural Pesticides [40 CFR 170.240 d(d)(4-6)], the handler requirements
may be reduced or modified as specified in the WPS.
Ridoxyl庐 240 EC / Fungicide
MSDS: 4/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
9. PHYSICAL AND CHEMICAL PROPERTIES
Assay: Metalaxyl - M 240 12 g/L
Appearance: Clear Yellow Liquid free of visible impurities.
Odour: Sweet Wax
Density: 0.9392 鈥? 1.0592 Kg/L
Flash Point: >40掳C
Water contents: <5.0 g/Kg
Acidity as H2SO4: <5.0 g/Kg
10. STABILITY AND REACTIVITY
Stability: Stable under normal use and storage conditions.
Condition to avoid: None known.
Materials to avoid: None known.
Hazardous Decomposition products:
Can decompose at high temperatures forming toxic gases..
11. TOXICOLOGICAL INFORMATION
Toxicology Data:
Formulation:
Ingestion: Slightly Toxic
Acute Oral LD50 (rat): 2,300 mg/kg body weight
Dermal: Slightly Toxic
Acute Dermal LD50 (rabbit) : >4,000 mg/Kg body weight
Inhalation: Practically Non Toxic
Acute Inhalation (4 h rat): >5.0 mg/l air.
Eye Irritation: Moderately Irritating (Rabbit)
Skin Irritation: Slightly irritating (Rabbit)
Skin Sensitization: Not a Sensitizer (Guinea Pig)
Chronic/Sub chronic Toxicity Studies:
Metalaxyl-M: Liver effects at high dose levels.
Ridoxyl庐 240 EC / Fungicide
MSDS: 5/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
12. ECOLOGICAL INFORMATION
Summary of Effects:
Metalaxyl-M: Practically non-toxic to aquatic organisms and wildlife.
Eco-Acute Toxicity: (Technical)
Bees: LC50/ EC50. > 25 碌g/bee
Invertebrates (Water Flea): LC50/EC50. > 113 ppm
Fish (Trout): LC50/EC50. > 121 ppm
Birds (8-d dietary鈥揵obwhite quail):LC50/EC50. 5,620 ppm
Environmental Fate:
Metalaxyl-M:
No data available for the formulation. The information presented here is
for the active ingredient. A through review of environmental information is
not possible in this document.
Does not bioaccumulate: No persistent in soil or water. moderate
mobility in soil. Mixes / sinks (after 24 h).
Environmental Hazards;
For terrestrial uses, do not apply directly to water, or to areas where surface
water is present, or to intertidal areas below the mean high water mark. Apply
only as specified on this label. Do not apply when whether conditions favor drift
from treated areas. Do not contaminate water when disposing of equipment
wash water or rinsate.
This chemical is known to leach through soil into groundwater under certain
conditions as a result of agricultural use. Use of this chemical in areas where
soils are permeable, particularly where the water table is shallow, may result in
ground water contamination.
Ridoxyl庐 240 EC / Fungicide
MSDS: 6/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers. Dispose of product
containers, waste containers and residues according to local health and
environmental regulations.
Characteristic Waste: Not applicable
Listed Waste: Not applicable
14. TRANSPORT INFORMATION
UN. No: UN 2902
Proper Shipping name: Pesticide, liquid, toxic, N.O.S (Metalaxyl-M)
Class: 6.1
T6
Classification Code:
Packing group: III
6.1
Subsidiary Risks:
61
Special provisions:
LQ19
Limited quantities:
Packing instructions P001 IBC03 LP01
Packaging:
R001
Special packing provisions -
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks: Special Provisions TP2 TP28
Tank Code L4BH
ADR Tank: Special Provision TU15 TE1 TE15 TE19
Vehicle for tank carriage AT
Transport Category 2
Special provision carriage: Packages -
Bulk -
Loading, unloading & CV13 CV28
Handling
Operation S9
Hazard Identification 60
Ridoxyl庐 240 EC / Fungicide
MSDS: 7/8
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
15. REGULATORY INFORMATION.
EPCRA SARA Title III Classification
Section 311/312 hazard Classes:
Acute Health hazard
Chronic Health Hazard
Fire Hazard
Section 313 Toxic Chemicals: Not Applicable.
CERCLA/ SARA 302 Reportable Quantity (RQ): None
RCRA Hazardous Waste Classification (40 CFR 261) Not Applicable
TSCA Status: Exempt from TSCA, Subject to FIFRA
16. OTHER INFORMATION
Ridoxyl庐 240EC should be transported its original labeled, tightly closed
container. Store the material in a well-ventilated, secure area out of reach of
children and domestic animals. Do not store food, beverages or tobacco
products in the storage area. Prevent eating, drinking, tobacco use, and
cosmetic application in areas where there is a potential for exposure to the
material. Wash thoroughly with soap and water after handling.
Buyer assumes all responsibility for safety and use not in accordance with the
product label instructions.
Ridoxyl庐 240 EC / Fungicide
MSDS: 8/8
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