INCO庐
INCOMAG庐 Alloy 5
Hazardous Ingredients
Hazardous Calculated
INCO PEL1 鈥搈g/m3 TLV2 鈥搈g/m3
C.A.S. No
Ingredients Composition
Nickel (Ni) 63 7440-02-0 1 1.5*
Magnesium
16 7439-95-4 n.av. n.av.
Material (Mg)
*as inhalable fraction
Physical and Chemical Data
Safety Grey, odorless, metallic, conical pig in two weights: 3 lb. and 12 lb. (1.4 kg and 5.4 kg).
Specific Sol. In H20
Ingredient Mol. Wt. m.p.掳C b.p.掳C
Gravity g/100ml
Data Ni 58.71 8.9 1453 2732 0
Mg 24.312 1.74 651 1107 0
Physical Hazards
Sheet Fire or Explosion Hazard
As supplied this product does not present a fire or explosion hazard. However, magnesium vapor
liberated in the use of this product (eg. production of ductile iron) in contact with air at elevated
temperatures can result in a violent explosion.
Also, finely-divided magnesium produced in the use of this product in contact with air at
temperatures near the melting point of magnesium will ignite and burn with a white flame.
Magnesium fires should be smothered with dry graphite or other suitable dry powders. (Consult
National Fire Protection Association (NFPA) standards to determine suitable extinguishing media
applicable to user operations.) Do not use foam, carbon tetrachloride, or carbon dioxide. Use of
water can produce hydrogen gas and result in an explosion. Avoid direct viewing of magnesium
fires to prevent eye injury.
In magnesium fire conditions, protect eyes and skin against flying particles.
A build-up of finely-divided magnesium from the use of this product should be prevented. If clean-up
is necessary, see Spill, Leak and Disposal Procedure.
Health Hazards
Nickel
LD50 ORAL RAT >9000 mg/kg
Inhalation: The National Toxicology Program has listed nickel as reasonably
anticipated to be a carcinogen based on the production of
injection-site tumours. The International Agency for Research on
Cancer (IARC) found there was inadequate evidence that metallic
nickel is carcinogenic to humans but since there was sufficient
evidence that it is carcinogenic to animals, IARC concluded that
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metallic nickel is possibly carcinogenic to humans.
Epidemiological studies of workers exposed to nickel powder and
to dust and fume generated in the production of nickel alloys and
of stainless steel have not indicated the presence of a significant
respiratory cancer hazard.
The inhalation of nickel powder has not resulted in an increased
incidence of malignant lung tumours in rodents.
INCO Repeated intratracheal instillation of nickel powder produced an
increased incidence of malignant lung tumours in rats. Repeated
intratracheal instillation of nickel powder did not produce an
increased incidence of malignant lung tumours in hamsters when
Material administered at the maximum tolerated dose. Single intratracheal
instillations of nickel powder in hamsters at doses near the LD50
produced an increased incidence of fibro sarcomas,
mesotheliomas and rhabdomyosarcomas.
Safety Inhalation of nickel powder at concentrations 15 times the PEL
irritated the respiratory tract in rodents.
In 1997, the ACGIH categorized elemental nickel as: A5 "Not
Data Suspected as a Human Carcinogen."
Skin Contact: Prolonged and intimate contact with metallic nickel may cause
irritation to the skin and nickel sensitivity, which may result in
Sheet allergic skin rashes.
One case has been reported of asthma induced by external
exposure to a nickel-containing skin clip and by skin contact with
nickel.
Wounds: Nickel metal powder has caused tumours at the site of injection in
rodents. However, studies do not suggest a significant risk for
humans from nickel-containing prostheses.
Ingestion: The U.S. National Institute for Occupational Safety and Health
(NIOSH) concluded there is no evidence that nickel and its
inorganic compounds are carcinogenic when ingested. The U.S.
Food and Drug Administration has affirmed that nickel is generally
recognized as safe (GRAS) as a direct human food ingredient.
Pre-existing
Conditions: Prolonged and intimate skin contact can cause an allergic skin
rash in previously sensitized individuals.
Magnesium
Wounds: Magnesium powder and magnesium alloy have caused necrotic
gaseous tumours at the site of subcutaneous injection in
experimental animals. No similar experiences have been reported
in humans.
Open skin abrasions and wounds exposed to magnesium metal
may be difficult to heal.
Ingestion: The lowest lethal dose of magnesium (LDLo) is 230 mg/kg in dogs.
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Precautions for safe storage, handling and use
If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne nickel
and magnesium oxide below the PELs4. If ventilation alone cannot so control exposure, use
NIOSH-approved respirators selected according to OSHA 29 CFR 1910.134. Maintain airborne
nickel levels as low as possible.
Avoid repeated skin contact. Wear suitable gloves. Wash skin thoroughly after handling. Launder
clothing and gloves as needed.
INCO Do not store near acids. This product can react vigorously with acids to liberate hydrogen gas,
which can form explosive mixtures in air.
Under special conditions nickel can react with carbon monoxide in reducing atmospheres to form
Material nickel carbonyl, Ni(CO)4, a toxic gas.
Spill, leak and disposal procedure
Pick up product and replace in original container. Nickel-containing waste is normally collected to
Safety recover nickel values. Should waste disposal be deemed necessary, follow EPA and local
regulations.
If clean-up of finely-divided magnesium arising from the use of this product is required, use
Data non-sparking tools to prevent ignition. Do not vacuum. Carefully sweep up and store in tightly
closed metal or fibre containers. Protect containers against physical damage. Store in a detached
fire resistive building, protected from moisture and away from reactive substances such as chlorine,
bromine, iodine, acids and all possible sources of ignition.
Sheet Emergency and first aid procedures
If exposure to nickel carbonyl is suspected, seek medical attention immediately. For skin rashes,
seek medical attention. Cleanse wounds thoroughly to remove any particles.
SARA Section 313 Supplier Notification
This product contains the following chemical(s) subject to the reporting requirements of Section 313
of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372:
Nickel
Refer to the Hazardous Ingredients section of this MSDS for the appropriate CAS numbers and
percent by weight.
INTERNATIONAL NICKEL INC.
Park 80 West, Plaza Two
Saddle Brook, NJ 07663
(201) 368-4800
Chemtrec 24 Emergency No. : 1-800-424-9300
Note:
Inco believes that the information in this Material Safety Data Sheet is accurate. However,
Inco makes no express or implied warranty as to the accuracy of such information and
expressly disclaims any liability resulting from reliance on such information.
Footnotes:
庐 Trademark of the Inco family of companies.
1 OSHA Permissible Exposure Limit
2 Threshold Limit Value of the American Conference of Governmental Industrial Hygienists.
3 Describes possible health hazards of the product supplied. If user operations change it to
other chemical forms, whether as end products, intermediates or fugitive emissions, the
possible health hazards of such forms must be determined by the user.
The PEL for magnesium oxide is 10 mg/m3. The TLV is 10 mg/m3. Exposure to
4
magnesium oxide fume can result in metal fume fever.
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