TECH LINE COATINGS, INC.
26844 ADAMS AVE. MURRIETA, CA 92562 USA
Phone 951-304-0498
Fax 951-461-9658
www.techlinecoatings.com
MATERIAL SAFETY DATA SHEET
SECTION I
COMMON NAME(S): MCSsf,
CHEMICAL NAME (S) AND SYNONYM (S): METALLIC CERAMIC COATING
CHEMICAL FAMILY: Not Applicable
FORMULA: Complex Mixture
EMERGENCY PHONE: (Chemtrec) 1-800-424-9300
INFORMATION PHONE: 951-304-0498
DATE PREPARED: 8/13/2003 (update)
SECTION II
HAZARDOUS INGREDIENTS CAS# CONCENTRATIONS
PHOSPHATE/CHROMATE SOLUTION 92203-02-6 >15%
(Less than 3.% of total weight is CrO3)
ACGIH TLV: 1mg/M3
1,2 - Propanediol 57-55-6 <1%
ACGIH TLV: 50 ppm
1-Methoxy-2propanol 107-98-2 <1%
ACGIH TLV 100 ppm
OSHA PEL: 100 ppm
1-Methoxy-2propanol acetete 108-65-6 <1%
ACGIH TLV 100 ppm
Stainless Steel Flake: Composition and ingredients as follows; <10%
Ingredient 0%
CAS # ACHIG OSHA ECC ECC ECC
TLV-TWA PEL-TWA Symbols R-phase S-phase
Iron 7439-89-6 66-71 N/A N/A
Chromium 7440-47-3 16-18 0.5 mg/m3 1 mg/m3 Ti,Xi 25,36/37/ 24/25
38, 43
Nickel 7440-47-0 10-14 1 mg.m3 1 mg.m3 Carc.Cat1 45.10,25, 53,22,24
F,T,Xi 42/43
Molybdenum 7439-98-7 2-3 10 mg/m3 10 mg/m3
Manganese 7439-96-5 0-2 5 mg/m3 5 mg/m3 T, Xi 25, 24/25
36/37/38
Silicon 7440-21-3 <1 10 mg/m3 10:5 mg/m3 F 10
Fatty Acid 57-11-4 <1 N/A N/A Xi 38 28/37
Note: "Total dust" and "Respirable Fraction" OSHA PEL values are listed for Silicon
NOTE: The National Toxicology program lists chromium and certain chromium compounds to be carcinogenic.
Pigment Black 26 68186-94-97 >5%
(Manganese Ferrite Black Spinel)
ACGIH: .20mg/m3 TWA (2)
OSHA: 5.00mg/m3 Ceiling (as Mn)
3.00 mg/m3 STEL (1)
1.00 mg/m3 TWA (1)
This pigment contains the following potential hazardous ingredients, which have been chemically reacted at a high termperature and are homogeneously and ionically
interdiffused to form an essentially insoluble pigment crystal with a crystalline matrix of spinel. Its composition may include a modifier. This means that they are not
present in the form of a simple physical mixture.
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MAGANESE OXIDE a component of Pigment Black 26
(1) Maganese fume (as Mn)
(2) Maganese, elemental and inorganic compounds (as Mn)
Crystalline silica (quartz) 14808-60-7 >25%
OSHA PEL: 10mg/m3
ACGIH TLV: 0.1mg/m3
SECTION III
PHYSICAL CHARACTERISTICS____________________________________
BOILING POINT: N/A
VAPOR DENSITY (AIR = 1) : <1
% VOLATILE VOLUME: 59.7%
APPEARANCE AND ODOR: GOLD/ BROWN WITH NO ODOR
SOLUBILITY IN WATER: APPRECIABLE
VOC'S: 0
SHIPPING: not regulated
SECTION IV
FIRE AND EXPLOSION HAZARD DATA_____________________________
FLASH POINT: NONE
EXTINGUISHING MEDIA: USE SAND OR CARBON DIOXIDE
SPECIAL FIRE FIGHTING PROCEDURES: n/a
UNUSUAL FIRE AND EXPLOSION HAZARDS: N/A
SECTION V
REACTIVITY DATA
STABILITY: STABLE
INCOMPATIBILITY (MATERIALS TO AVOID) : CONTACT WITH OXIDIZING AGENTS, ALKALIS OR STRONG REDUCING AGENTS
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
SECTION VI
HEALTH HAZARD DATA__________________________________________________
ROUTES OF ENTRY:
INHALATION? YES
SKIN? YES
INGESTION? YES
CARCINOGENICITY:
NTP, OSHA? CHROMIUM AND CERTAIN CHROMIUM COMPOUNDS ARE LISTED. Crystalline silica is listed as a probable human carcinogen.
The following information is for crystalline silica in its dry form, not as blended.
HEALTH HAZARDS: Crystalline silica does not cause burns or severe skin or eye irritation. A single exposure will not result in serious adverse health effects.
Crystalline silica is not an environmental hazard.
Potential health effects:
INHALATION: Exposure to Crystalline silica can cause silicosis, a fibrous scarring of the lungs. Silicosis may be a progressive; it may lead to disability and death.
There is evidence that exposure to respirable crystalline silica or the the disease silicosis is associated with the increased incidence of scleroderma, an immune system
disorder manifested by a fibrosis (scarring) of the lungs, skin and other internal organs. Individuals with siliocosis are predisposed to develop tuberculosis, There are
several studies that suggest that respirable crystalline silica or the disease silicosis is associated with the increased incidence of kidney lesions.
NOTE: When crystalline silica is heated to more than 850C/1560f it can change to a form known as trydimite. The PEL for trymidite is 1/2 that of crystalline silica.
HEALTH HAZARDS: CHROMIUM AND CERTAIN CHROMIUM COMPOUNDS
EYES: CAUSES SEVERE IRRITATION
SKIN: CAUSES MILD SKIN IRRITATION, DRYING OF SKIN
INHALATION: MAY CAUSE DRYING OF NASAL AND RESPIRATORY TISSUE
INGESTION: HARMFUL IF SWALLOWED, CAUSING VOMITING, NAUSEA, DIARRHEA
HEALTH HAZARDS: Black Pigment 26 On the basis of animal studies this material would be expected to be ono irritating to the eyes and skin and to be essentially
non toxic by ingestion. Mechanical irritation to the material can occur to the eyes and skin. To date no adverse health effects to exposure to this material has been
reported among workers using this pigment.
EMERGENCY AND FIRST AID:
EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER, CALL A PHYSICIAN
SKIN: WASH WITH WATER. REMOVE CONTAMINATED CLOTHING
INHALATION: REMOVE INDIVIDUAL TO FRESH AIR. ADMINISTER OXYGEN IF
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BREATHING IS DIFFICULT. CALL A PHYSICIAN
INGESTION: GIVE LARGE AMOUNTS OF WATER FOLLOWED BY MILK OF MAGNESIA. CALL A PHYSICIAN IMMEDIATELY
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: RESPIRATORY, DERMAL AILMENTS
SECTION VII
SPILL OR LEAK PROCEDURES___________________________________
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CLEAN SPILL WITH ABSORBENT MATERIAL. NEUTRALIZE WITH
SODIUM BICARBONATE. DO NOT USE STRONG ALKALIS. FLUSH AREA WITH WATER
WASTE DISPOSAL METHOD: MATERIAL MAY BE BAKED AT CURE TEMPERATURE THEN DISCARDED AS SOLID WASTE, OR FILTER TO
REMOVE SOLIDS AND DISCARD AS SOLID WASTE. TREAT REMAINING LIQUID WITH SODIUM METABISULFITE, THEN PRECIPITATE
TRIVALENT CHROMIUM BY NEUTRALIZING WITH ALKALI, SUCH AS LIME. DISPOSAL SHOULD BE MADE IN ACCORD WITH FEDERAL, STATE
AND LOCAL REGULATIONS.
SECTION VIII
SPECIAL PROTECTION / CONTROL MEASURES:____________________
RESPIRATORY PROTECTION: #9910 RESPIRATOR MANUFACTURED BY 3M OR EQUIVALENT
VENTILATION:
LOCAL EXHAUST: USE TO MAINTAIN BELOW TWA LIMITS
MECHINICAL: USE NON-SPARKING EQUIPMENT
PROTECTIVE GLOVES: RUBBER ACID PROOF
EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS OR GOGGLES
OTHER PROTECTIVE EQUIPMENT: WEAR PROTECTIVE CLOTHING, ACID PROOF
WORK / HYGIENIC PRACTICES: WASH THOROUGHLY AFTER HANDLING PRODUCT AND BEFORE EATING, DRINKING OR SMOKING
SECTION IX
SPECIAL PRECAUTIONS___________________________________________
HANDLING AND STORAGE: STORE IN AREAS THAT WILL NOT COME INCONTACT WITH STRONG ALKALIS OR OXIDIZING AGENTS.
NOTE: Since this compound contains aluminum powder, a clean spray area and duct system is important. It is hazardous to allow an accumulation of dried
material to occur since this dried material in the form of duct could be ignited by sparks or other means and possibly cause a dust explosion as with any finely
divided powdered material.
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THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, REPRESENTATION, INDUCEMENT OR LICENSE OF ANY KIND, EXCEPT THAT
IT IS ACCURATE TO THE BEST OF TECH LINE COATINGS, INC., KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY TECH LINE
COATINGS, INC. TO BE ACCURATE, AND TECH LINE COATINGS, INC., DOES NOT ASSUME ANY LEGAL RESPONSIBILITY FOR USE OR
RELIANCE UPON SAME. BEFORE USING ANY CHEMICAL, READ ITS LABEL, INSTRUCTIONS AND MATERIAL SAFETY DATA SHEET.
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