1,10-PHENANTHROLINE/ FERROUS SULPHATE
MATERIAL SAFETY DATA SHEET COMPLEX
PRODUCT CODE NUMBER(S): 5488-6, 5489-6
PRODUCT IDENTIFICATION FIRE AND EXPLOSION DATA
Chemical Name and Synonyms: 1,10-Phenanthrolin/ fer- Flammability: Not combustible; will not burn.
rous sulphate complex; Ferroin Extinguishing Media: Use an extinguisher appropriate to
Chemical Family: Oxidation reduction indicator the surrounding material that is burning. Fight fire from up-
wind, from a safe distance. Firefighters must wear
Chemical Formula: C12H8N2 + FeSO4 in H2O
protective equipment and clothing sufficient to prevent inha-
Product Use: Laboratory reagent
lation of dust or fumes, and contact with skin and eyes.
Manufacturer鈥檚 Name and Address: Flash Point (Method Used): Not applicable
Caledon Laboratories Ltd.
Autoignition Temperature: Not applicable
40 Armstrong Avenue
Upper Flammable Limit (% by volume): Not applicable
Georgetown, Ontario L7G 4R9
Lower Flammable Limit (% by volume): Not applicable
Telephone No: (905) 877-0101
Hazardous Combustion Products: COx, SOx, nitrogen
Fax No: (905) 877-6666
compounds (minute quantities)
Emergency Telephone No: CANUTEC (613) 996-6666 Sensitivity to Impact: None idenitifed
Sensitivity to Static discharge: None identified
HAZARDOUS INGREDIENTS OF MATERIALS
TOXICOLOGICAL PROPERTIES AND HEALTH DATA
Ingredients % TLV Units CAS No.
To the best of our knowledge, the physical, chemical and
o-Phenanthroline ~1 Not established 5144-89-8
toxicological properties of this substance have not yet been
3
Ferrous sulphate 0.4 1 mg/m 7782-63-0
thoroughly investigated.
(as Fe) (ACGIH)
Toxicological Data:
PHYSICAL DATA
LD50: (oral, rat) 132 mg/kg (C12H8N2); (oral, rat) 1,480
Physical State: Liquid mg/kg; (oral, mouse) 100 mg/kg (FeSO4)
Odour and Appearance: Orange-red liquid; odourless. LC50: Not available
Odour Threshold (ppm): Not applicable
Effects of Acute Exposure to Product:
Vapour Pressure (mm Hg): Not available
Vapour Density (Air = 1): Not available Inhaled: No human information available. May be harmful.
May cause slight irritation, coughing, shortness of breath.
Evaporation Rate: 0 (butyl acetate = 1)
High concentrations of 1,10-phenanthroline caused hyper-
Boiling Point (degrees C): ~100掳C
tension, tachycardia, and peripheral vasodilation in rabbits.
Melting Point (degrees C): ~0掳C
In contact with skin: No human or animal information
pH: Not available available. Based on studies with similar compounds,
Specific Gravity: ~1 1,10-phenanthroline may causeslight irritation. May stain
skin.
Coefficient of Water/Oil distribution: Not available
In contact with eyes: No human or animal information
SHIPPING DESCRIPTION available. Based on studies with similar compounds,
1,10-phenanthroline may cause slight irritation.
UN: Not regulated Ingested: 1,10-phenanthroline is toxic. May cause gastro-
T.D.G. Class: Not regulated intestinal irritation, nausea, vomiting.
Pkg. Group: Not regulated
Effects of Chronic Exposure to Product:
REACTIVITY DATA Repeated exposure to toxic material may cause general de-
terioration of health by accumulation in one or more organs.
Chemical Stability: Stable
Carcinogenicity: No evidence of carcinogenicity.
Incompatibility with other substances: May react vigor-
Teratogenicity: No information available
ously or violently with strong oxidizers, strong acids.
Reactivity: Avoid extreme heat, incompatible materials, Reproductive Effects: Reproductive references cited for
generation of mist. phenanthroline (RTECS No. SF8437000)
Hazardous Decomposition Products: COx, SOx, nitrogen Mutagenicity: Mutation reference cited for
compounds (minute quantities) phenanthroline(RTECS)
Synergistic Products: No information available
1,10-PHENANTHROLINE FERROUS SULPHATE
MSDS COMPLEX
CODE: 5488-6, 5489-6
PREVENTIVE MEASURES Proposed WHMIS Designation: D1B, D2B
(i,10-phenanthrloine)
Engineering Controls: Local exhaust ventilation recom-
mended Prepared by: Caledon Laboratories Ltd. (905) 877-0101
Respiratory Protection: Dust/mist mask. For high or un- Caledon Laboratories Ltd. believes the information contained
known concentrations, as in fire or spill conditions,
herein is reliable and accurate. Caledon makes no warranty
positive-pressure, full face-piece self-contained breathing
with respect thereto and expressly disclaims all liability for reli-
apparatus.
ance thereon. Such information is solely for your consider-
Eye Protection: Chemical safety glasses
ation, investigation, and verification.
Skin Protection: Rubber or plastic gloves. Plastic apron,
and sleeves sufficient to limit contact.
Other Personal Protective Equipment: Safety shower
and eye-wash fountain in work area.
Leak and Spill Procedure: Cleanup personnel must be
thoroguhly trained in the handling of hazardous materials,
and must wear protective equipment and clothing sufficient
to prevent inhalation of mist, and contact with skin and eyes.
Cover with inert absorbent and place in suitable containers
for reclamation or disposal. Wash the site thorroughly with
water and detergent.
Waste Disposal: Follow all federal, provincial and local
regulations for disposal.
Handling Procedures and Equipment:
1,10-phenanthrloine is TOXIC, but is present in a very low
amount. Workers using this chemical must be thoroughly
trained in its hazards and its safe use, and must wear appro-
priate protective equipment and clothing. Use the smallest
amount possible for the purpose, in a designated area with
adequate ventilation. Avoid contact with skin and eyes.
Avoid inhalation. Wash thoroughly after handling.
Storage Requirements: Store in suitable, labelled contain-
ers, in a cool, dry, well-ventilated area, out of direct sunlight,
and away from incompatible materials. Keep containers
tightly closed. Protect from damage and inspect frequently
for signs of leaking.
FIRST AID MEASURES
Specific Measures:
Eyes: Flush eyes thoroughly with gently running water,
holding eyelids open while flushing, for five to ten (5-10)
minutes, or until no trace of chemical remains. Get medical
advice if irritation develops.
Skin: Remove contaminated clothing, including watches,
rings, belts, and shoes. Wash affected areas with soap and
running water. If irritation persists, obtain medical advice.
Inhalation: Move victim to fresh air. Give oxygen and get
medical attantion for any breathing difficulty.
Ingestion: If victim is alert and NOT convulsing, rinse
mouth, give several glasses of water to drink to dilute. If dis-
comfort occurs, or if a large amount has been ingested, get
medical attention.
REFERENCES USED
CCINFO disc: MSDS鈥檚, March 2001
Budavari: The Merck Index, 12th ed., 1997
Sax, Lewis: Hawley鈥檚 Condensed Chemical Dictionary, 11th
ed., 1987
Suppliers鈥? Material Safety Data Sheets
ADDITIONAL INFORMATION
Date Issued: July 22, 1991
Revision: October 2005
MSDS: 5488-6, 5489-6
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