MATERIAL SAFETY DATA SHEET 1,10-PHENANTHROLINE HYDRATE
PRODUCT CODE NUMBER(S): 5490-5
PRODUCT IDENTIFICATION FIRE AND EXPLOSION DATA
Chemical Name and Synonyms: 1,10-Phenanthroline hy- Flammability: Can burn at elevated temperatures. As with
drate; o-Phenanthroline hydrate most organic compounds, fine dust dispersed in air, at suffi-
cient concentrations, and in the presence of an ignition
Chemical Family: Cyclic amine
source, can be an explosion hazard.
Chemical Formula: C12H8N2.H2O
Extinguishing Media: Use an extinguisher appropriate to
Product Use: Laboratory reagent the surrounding material that is burning. Fight fire from up-
Manufacturer鈥檚 Name and Address: wind, from a safe distance. Firefighters must wear
Caledon Laboratories Ltd. protective equipment and clothing sufficient to prevent inha-
lation of dust or fumes, and contact with skin and eyes.
40 Armstrong Avenue
Flash Point (Method Used): Not available
Georgetown, Ontario L7G 4R9
Autoignition Temperature: Not available
Telephone No: (905) 877-0101
Upper Flammable Limit (% by volume): Not available
Fax No: (905) 877-6666
Lower Flammable Limit (% by volume): Not available
Emergency Telephone No: CANUTEC (613) 996-6666
Hazardous Combustion Products: COx, NOx
HAZARDOUS INGREDIENTS OF MATERIALS Sensitivity to Impact: None idenitifed
Sensitivity to Static discharge: Fine dust dispersed in air
Ingredients % TLV Units CAS No.
in sufficient concentrations and, in the presence of an igni-
o-Phenanthroline tion source is a potential dust explosion hazard.
hydrate ~99 Not established 5144-89-8
TOXICOLOGICAL PROPERTIES AND HEALTH DATA
PHYSICAL DATA To the best of our knowledge, the physical, chemical and
toxicological properties of this substance have not yet been
Physical State: Solid
thoroughly investigated.
Odour and Appearance: White crystals or crystalline pow-
der, becoming cream coloured on storage; odourless.
Toxicological Data:
Odour Threshold (ppm): Not applicable
Vapour Pressure (mm Hg): Not available LD50: (oral, rat) 132 mg/kg
Vapour Density (Air = 1): Not available LC50: Not available
Evaporation Rate: 0 (butyl acetate = 1)
Effects of Acute Exposure to Product:
Boiling Point (degrees C): Not available
Melting Point (degrees C): 98掳C, loses water @ 117掳C Inhaled: No human information available. May be harmful.
May irritate, causing coughing, shortness of breath, chest
pH: Not available
pain. High concentrations caused hypertension, tachycardia,
Specific Gravity: 1.100 and peripheral vasodilation in rabbits.
Coefficient of Water/Oil distribution: Not available In contact with skin: No human or animal information
available. Based on studies with similar compounds, may
SHIPPING DESCRIPTION cause irritation, redness, itching. Will stain skin.
In contact with eyes: No humanor animal information
UN: Not regulated
available. Based on studies with similar compounds, may
T.D.G. Class: Not regulated cause irritation, with redness, tearing, pain.
Pkg. Group: Not regulated Ingested: Toxic. May cause gastrointestinal irritation, nau-
sea, vomiting.
REACTIVITY DATA
Effects of Chronic Exposure to Product:
Chemical Stability: Stable (darkens to tan or brown colour
on prolonged storage) Repeated exposure to toxic material may cause general de-
Incompatibility with other substances: May react vigor- terioration of health by accumulation in one or more organs.
ously, violently, or explosively with strong oxidizers, strong Carcinogenicity: No evidence of carcinogenicity.
acids.
Teratogenicity: No information available
Reactivity: Avoid ferrous contamination and metallic (fer-
Reproductive Effects: Reproductive references cited
rous) containers. Avoid excessive heat, incompatiable
(RTECS No. SF8437000))
materials, generation of dust.
Mutagenicity: Mutation reference cited (RTECS)
Hazardous Decomposition Products: COx, nitrogen com-
Synergistic Products: No information available
pounds
MSDS 1,10-PHENANTHROLINE HYDRATE
CODE: 5490-5
PREVENTIVE MEASURES REFERENCES USED
Engineering Controls: Local exhaust ventilation recom- Budavari: The Merck Index, 12th ed., 1997
mended Sax, Lewis: Hawley鈥檚 Condensed Chemical Dictionary, 11th
Respiratory Protection: Dust mask, fumehood. ed., 1987
NIOSH/MSHA approved respirator for dusty conditions. For
Suppliers鈥? Material Safety Data Sheets
high or unknown concentrations, as in fire or spill conditions,
positive-pressure, full face-piece self-contained breathing
ADDITIONAL INFORMATION
apparatus.
Eye Protection: Chemical safety goggle.s Date Issued: July 22, 1991
Skin Protection: Rubber or plastic gloves. Plastic apron, Revision: October 2005
and sleeves sufficient to prevent contact. MSDS: 5490-5
Other Personal Protective Equipment: Safety shower
Proposed WHMIS Designation: D1B, D2B
and eye-wash fountain in work area.
Leak and Spill Procedure: Ventilate area. Eliminate igni-
Prepared by: Caledon Laboratories Ltd. (905) 877-0101
tion sources. Cleanup personnel must be thoroughly trained
Caledon Laboratories Ltd. believes the information contained
in the handling of hazardous materials, and must wear pro-
herein is reliable and accurate. Caledon makes no warranty
tective equipment and clothing sufficient to prevent
with respect thereto and expressly disclaims all liability for reli-
inhalation of dust or fumes, and contact with skin and eyes.
Gather up in a manner that does not raise dust, and place ance thereon. Such information is solely for your consider-
in suitable containers for reclamation or disposal. Wash the ation, investigation, and verification.
site thorroughly with water and detergent.
Waste Disposal: Follow all federal, provincial and local
regulations for disposal.
Handling Procedures and Equipment: TOXIC, COM-
BUSTIBLE DUST. Workers using this chemical must be
properly trained in its hazards and its safe use, and must
wear appropriate protective equipment and clothing. Avoid
generating dust. If there is dust, keep away from heat,
sparks, and all sources of ignition; avoid the accumulation of
static charge, use anti-sparking tools and ground and bond
equipment and containers. Use the smallest amount possi-
ble for the purpose, in a designated area with adequate
ventilation. Use good housekeeping measures to prevent
accumulations of dust. Avoid contact with skin and eyes.
Avoid inhalation. Wash thoroughly after handling.
Storage Requirements: Store in suitable (non-metallic), la-
belled containers, in a cool, dry, well-ventilated area, out of
direct sunlight, and away from all ignition sources and in-
compatible materials. Keep container tightly closed. Protect
from damage,and inspect frequently for signs of leaking.
FIRST AID MEASURES
Specific Measures:
Eyes: Flush eyes thoroughly with gently running water,
holding eyelids open while flushing, for ten ti fifteen (10-15)
minutes, or until no trace of chemical remains. Take care
not to flush contaminated water into unaffected eye. Get
medical attention.
Skin: Remove contaminated clothing, including watches,
rings, belts, and shoes. Brush or wipe off dry material.
Flush skin with plenty of running water until no evidence of
chemical remains. If irritation develops get medical atten-
tion.
Inhalation: Move victim to fresh air. Give oxygen for
breathing difficulty. Obtain medical advice.
Ingestion: If victim is alert and NOT convulsing, rinse
mouth, give several glasses of water to drink to dilute and
induce vomiting under medical supervision. Have victim
lean forward with head down to avoid breathing in of
vomitus, rinse mouth and administer more water. Obtain
medical attention immediately.
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