MATERIAL SAFETY DATA SHEET POLYETHYLENE GLYCOL 8000
PRODUCT CODE NUMBER(S): 5770-5
PRODUCT IDENTIFICATION FIRE AND EXPLOSION DATA
Chemical Name and Synonyms: Polyethylene glycol Flammability: May be combustible if strongly heated. As
8000; Alkapol-peg; Carbowax with most organic compounds, fine dust dispersed in air in
the presence of an ignition source is a potential dust explo-
Chemical Family: Glycols
sion hazard.
Chemical Formula: C4H10NO3
Extinguishing Media: Use extinguishing media appropri-
Product Use: Laboratory reagent ate to the surrounding fire. Water in flooding amounts can
Manufacturer鈥檚 Name and Address: be used to cool containers, prevent dust formation, flush
Caledon Laboratories Ltd. chemcial away from fire. Firefighters should wear protective
equipment and clothing sufficient to prevent inhalation of
40 Armstrong Avenue
dust or fumes and contact with skin and eyes.
Georgetown, Ontario L7G 4R9
Flash Point (Method Used): >232掳C
Telephone No: (905) 877-0101
Autoignition Temperature: Not applicable
Fax No: (905) 877-6666
Upper Flammable Limit (% by volume): Not applicable
Emergency Telephone No: CANUTEC (613) 996-6666
Lower Flammable Limit (% by volume): Not applicable
HAZARDOUS INGREDIENTS OF MATERIALS Hazardous Combustion Products: Under fire condi-
tions,may form flammable/explosive mixtures in air.
Ingredients % TLV Units CAS No. Sensitivity to Impact: None identified
Sensitivity to Static discharge: Under certain conditions,
Polyethylene glycol 99 Not established 25322-68-3
dust/air mixtures can probably explode if in contact with an
PHYSICAL DATA electrostatic spark or other ignition source.
TOXICOLOGICAL PROPERTIES AND HEALTH DATA
Physical State: Solid
Odour and Appearance: White powder, colourless, vis-
Toxicological Data:
cous liquid abaove ~54掳C, slight sweet odour
Odour Threshold (ppm): Not available To the best of our knowledge, the physical, chemical and
Vapour Pressure (mm Hg): Not available toxicological properties of this substance have not yet been
thoroughly investigated.
Vapour Density (Air = 1): Not available
LD50: (oral, rat) >40,000 mg/kg; (dermal, rabbit) >20,000
Evaporation Rate: Not available
mg/kg
Boiling Point (degrees C): Decomposes at elevated tem-
LC50: Not available
peratures
Melting Point (degrees C): Not available
Effects of Acute Exposure to Product:
pH: 5.5 to 7.0 (5%, aqueous, 20掳C)
Inhaled: Not expected to be a hazard at room temperature.
Specific Gravity: 1.2 @ 25掳C
If heated, may be irritating to upper respiratory tract. Single
Coefficient of Water/Oil distribution: Not available
exposure in not expected to be harmful.
In contact with skin: Not expected to be irritating to intact
SHIPPING DESCRIPTION skin. Some evidence of absorption through broken skin.
UN: Not regulated In contact with eyes: May cause mild mechanical irritation.
T.D.G. Class: Not regulated Ingested: Single dose toxicity very low; not expected to be
an ingestion hazard under normal workplace conditions.
Pkg. Group: Not regulated
REACTIVITY DATA Effects of Chronic Exposure to Product:
Some recent studies have indicated evidence of absorption
Chemical Stability: Stable under normal conditions of use
of polyethylene glycol at toxic levels in burn patients. The
and storage. Decomposes or oxidizes at elevated tempera-
use of topical applications containing this substance may not
tures.
be appropriate in burn patients or those with impaired lidney
Incompatibility with other substances: May react vio-
function.
lently, with increased risk of fire and explosion, with strong
oxidizers or acids. Carcinogenicity: Long termanimal studies show no evi-
dence of carcinogenicity.
Reactivity: Avoid excessive heat, ignition sources, incom-
patible materials, generation of dust or mist. Teratogenicity: No information available
Hazardous Decomposition Products: CO, CO2 Reproductive Effects: No information available
Mutagenicity: No information available
MSDS POLYETHYLENE GLYCOL 8000
CODE: 5770-5
REFERENCES USED
Synergistic Products: None known
CCINFO disc: MSDS鈥檚, October 2005
PREVENTIVE MEASURES
Suppliers鈥? Material Safety Data Sheets
Engineering Controls: Local exhaust ventilation recom-
mended. ADDITIONAL INFORMATION
Respiratory Protection: Dust mask. NIOSH/MSHA ap-
.
Date Issued: May 30, 1995
proved half-face dust/mist respirator for dusty conditions.
For high or unknown concentrations, as in fire or spill condi- Revision: October 2005
tions, full face-piece, positive-pressure, self-contained MSDS: 5770-5
breathing apparatus.
Proposed Whmis Designation: Not a controlled product.
Eye Protection: Chemical safety glasses. Do not wear Not required to be updated every three years (WHMIS
contact lenses when working with chemicals. 1992, B-40, Section 29,2)
Skin Protection: Wear protective gloves and protective
clothing sufficient to prevent contact. Prepared by: Caledon Laboratories Ltd. (905) 877-0101
Other Personal Protective Equipment: Safety shower Caledon Laboratories Ltd. believes the information contained
and eye-wash fountain in work area.
herein is reliable and accurate. Caledon makes no warranty
Leak and Spill Procedure: If dust is present, eliminate with respect thereto and expressly disclaims all liability for reli-
sources of ignition. Wet if necessary to control dust.
ance thereon. Such information is solely for your consider-
Cleanup personnel should be trained in the handling of haz-
ation, investigation, and verification.
ardous chemicals and should wear protective equipment
and clothing sufficient to prevent inhalation of dust, mist or
fumes, and contact with skin and eyes. Prevent from enter-
ing sewers or waterways. Collect in a manner that does not
raise dust, transfer carefully into container, and arrange re-
moval by disposal company. Wash site of spillage
thoroughly with water and detergent.
Waste Disposal: Follow all federal, provincial and local
regulations for disposal.
Handling Procedures and Equipment: May be COMBUS-
TIBLE as DUST. Workers using this chemical must be
properly trained in its hazards and its safe use, and must
wear appropriate protective equipment and clothing. Avoid
generating dust. If there is dust, keep away from heat,
sparks, and all sources of ignition; avoid the accumulation of
static charge, use anti-sparking tools and ground and bond
equipment and containers. Use the smallest amount possi-
ble for the purpose, in a designated area with adequate
ventilation. Use good housekeeping to prevent accumula-
tions of dust. Avoid contact with skin and eyes. Avoid
inhalation. Wash thoroughly after handling.
Storage Requirements: Store in suitable, labelled contain-
ers, in a cool, dry, well-ventilated area, out of direct sunlight.
Keep containers tightly closed. Store away from incompati-
ble materials, and heat and ignition sources.
FIRST AID MEASURES
Specific Measures:
Eyes: Allow eyes to water naturally for a few minutes to
dislodge particle. Do not allow victim to rub eyes. Flush eyes
thoroughly with gently running water, holding eyelids open
while flushing, for five to ten (5-10) minutes, or until no trace
of chemical remains. Get medical advice if irritation devel-
ops.
Skin: Remove contaminated clothing. Brush or wipe off dry
material. Flush skin with plenty of running water until no evi-
dence of chemical remains. Get medical advice if irritation
develops.
Inhalation: Remove to fresh air. Give oxygen and get
medical attention for any breathing difficulty.
Ingestion: If victim is alert and NOT convulsing, rinse
mouth, give several glasses of water to drink to dilute. If dis-
comfort occurs, or if a large amount has been ingested, get
medical attention.
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