MATERIAL SAFETY DATA SHEET
I PRODUCT IDENTIFICATION
Trade Name: Lithium Chloride Synonym: Lithium Salt
Chemical Family: Alkali Metals Formula: LiCl
Molecular Weight: 42.39 CAS #: 7447-41-8
II HAZARDOUS INGREDIENTS
Wt %: PEL/OSHA: TLV/ACGIH: TDLH/OSHA:
99-100 N/A N/A N/A
Extremely Hazardous Substances: No CERCLA Hazardous Substance: No
SARA 313 Toxic Chemicals: No TSCA Inventory: Yes
III PHYSICAL DATA
1355 oC 608 oC
Boiling Point: Melting Point:
Specific Gravity: 2.07 Volatiles: N/A
Evaporation Rate: N/A Solubility in H2O: Appreciable (>10%)
Appearance and Odor: White solid. Odorless. Physical State: Solid
IV FIRE AND EXPLOSION HAZARDS DATA
Flash Point (Method used): N/A Autoignition Temperature: N/A
Flammable Limits: Upper: N/A Lower: N/A
Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire Fighting Procedures: Wear self-contained breathing apparatus and full fire fighting protective clothing when fighting
significant-sized fires.
Unusual Fire & Explosion Hazard: None identified.
Toxic Gases Produced: Hydrogen chloride.
Explosion Data: This product is not an explosive.
Sensitivity to Mechanical Impact: N/A
Sensitivity to Static Discharge: N/A
V HEALTH HAZARD INFORMATION
Threshold Limit Value (TLV): Not Established STEL: Not Established PEL: Not Established
SARA/Title III Hazard Categories: Acute: Yes, Chronic: Yes, Flammability: No, Pressure: No, Reactivity: No
Toxicity of Components:
Oral Rat LD50 for Lithium Chloride: 526 mg/kg
Intraperitoneal Rat LD50 for Lithium Chloride: 514 mg/kg
Subcutaneous Rat LD50 for Lithium Chloride: 499 mg/kg
Intravenous Mouse LD50 for Lithium Chloride: 363 mg/kg
Carcinogenicity: NTP: No, IARC: No, ZList: No, OSHA Reg: No
Reproductive Effects: Tests on laboratory animals indicate material may be teratogenic.
Effects of Overexposure:
Inhalation: Irritation of upper respiratory tract, irritation of mucous membranes Skin Contact: Irritation
Eye Contact: Irritation Skin Absorption: None identified
Ingestion: Gastrointestinal irritation, nausea, vomiting, diarrhea
Chronic Effects: Kidney damage, central nervous system depression
Target Organs: GI tract, central nervous system, kidneys
Medical Conditions Generally Aggravated by Exposure: None identified
Primary Routes of Entry: Inhalation, ingestion, skin contact, eye contact
EMERGENCY AND FIRST AIDE PROCEDURES:
INGESTION: CALL A PHYSICIAN IMMEDIATELY. If swallowed, if conscious, give large amounts of water. Induce vomiting.
INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Prompt action is essential.
SKIN: In case of contact, flush skin with water.
EYES: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.
VI REACTIVITY DATA
Stability: Stable
Incompatibility: Strong acids, bromine trifluoride and trichloride
Conditions of Reactivity: Moisture
Hazardous Decomposition Products: Hydrogen chloride
Hazardous Polymerization: Will not occur.
VII SPILL OR LEAK PROCEDURES
Steps to Be Taken in Case Material Is Released or Spilled: Wear self-contained breathing apparatus and full protective clothing.
With clean shovel, carefully place material into clean, dry container and cover; remove from area. Flush spill area with water.
Waste Disposal Method: Dispose of in accordance with Local, State and Federal Waste Disposal Regulations.
VIII SPECIAL PROTECTION INFORMATION
Respiratory Protection: No special requirement, where adequate ventilation conditions exist. If airborne concentration is high, use
an appropriate respirator or dust mask.
Ventilation: Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.
Eye/skin Protection: Safety goggles, uniform, rubber gloves are recommended.
Others: Quick-drench eyewash and safety shower.
IX SPECIAL PRECAUTIONS
Handling and Storage: Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.
Transportation Data:
DOMESTIC (DOT):
DOT Proper Shipping Name: Chemicals, n.o.s. (non-regulated)
FOREIGN (IMO):
IMO Proper Shipping Name: Chemicals, n.o.s. (non-regulated)
U.S. Customs Harmonization Number: 28273900002
AIR (ICAO):
Proper Shipping Name: Chemicals, n.o.s. (non-regulated)
U.S. Customs Harmonization Number: 28273900002
Issued By: S. Dierks
Dated: May 1993
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